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91.
The calcium salt of mono(hydroxyethoxyethyl)phthalate [Ca(HEEP)2] was synthesized by the reaction of diethylene glycol, phthalic anhydride, and calcium acetate. Calcium‐containing poly(urethane ether)s (PUEs) were synthesized by the reaction of hexamethylene diisocyanate (HMDI) or tolylene 2,4‐diisocyanate (TDI) with a mixture of Ca(HEEP)2 and poly(ethylene glycol) (PEG300 or PEG400) with di‐n‐butyltin dilaurate as a catalyst. A series of calcium‐containing PUEs of different compositions were synthesized with Ca(HEEP)2/PEG300 (or PEG400)/diisocyanate (HMDI or TDI) molar ratios of 2:2:4, 3:1:4, and 1:3:4 so that the coating properties of the PUEs could be studied. Blank PUEs without calcium‐containing ionic diols were also prepared by the reaction of PEG300 or PEG400 with HMDI or TDI. The PUEs were well characterized by Fourier transform infrared, 1H and 13C NMR, solid‐state cross‐polarity/magic‐angle‐spinning 13C NMR, viscosity, solubility, and X‐ray diffraction studies. The thermal properties of the polymers were also studied with thermogravimetric analysis and differential scanning calorimetry. The PUEs were applied as top coats on acrylic‐coated leather, and their physicomechanical properties were also studied. The coating properties of PUEs, such as the tensile strength, elongation at break, tear strength, water vapor permeability, flexing endurance, cold crack resistance, abrasion resistance, color fastness, and adhesive strength, were better than the standard values. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2865–2878, 2003  相似文献   
92.
A method for suppressing self-modulation in backward-wave tubes is proposed. Additional delay is introduced into the feedback circuit, owing to which the output signal amplitude affects the electron beam current that enters into the interaction space. Numerical simulations demonstrate that the operating current in the single-frequency oscillation mode may be increased roughly twofold.  相似文献   
93.
The luminescence and scintillation properties of poly(methyl methacrylate) containing 1,1,3-trimethyl-3-phenylindan were studied.  相似文献   
94.
A new parallel storm surge model, the Parallel Environmental Model (PEM), is developed and tested by comparisons with analytic solutions. The PEM is a 2‐D vertically averaged, wetting and drying numerical model and can be operated in explicit, semi‐implicit and fully implicit modes. In the implicit mode, the propagation, Coriolis and bottom friction terms can all be treated implicitly. The advection and diffusion terms are solved with a parallel Eulerian–Lagrangian scheme developed for this study. The model is developed specifically for use on parallel computer systems and will function accordingly in either explicit of implicit modes. Storm boundary conditions are based on a simple exponential decay of pressure from the centre of a storm. The simulated flooding caused by a major Category 5 hurricane making landfall in the Indian River Lagoon, Florida is then presented as an example application of the PEM. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
95.
The structural change in the depth direction of a polyimide (UPILEX‐S) film treated in alkaline solution, which was a representative surface treatment used to form a seed layer for plating and to improve the adhesive strength, was analyzed by means of micro Fourier transform infrared attenuated total reflection (FTIR‐ATR) line analysis with gradient shaving preparation. The polyimide film was treated with KOH. The imide ring opened through the alkaline treatment, and the amide structure and carboxylic acid salt were formed. The attainment depth of this structural change was almost proportional to the treatment time, and it reached about 8 μm after a 30‐min treatment. The degree of structural change through the alkaline treatment was almost constant after it reached a considerably degraded stage, and the chemically changed region penetrated into the inner part of the film from the surface. An intermediate layer before the final degraded stage appeared in the treated layer, and its thickness increased with the treatment time. The region that was changed chemically by the alkaline treatment progressed to the inner part simultaneously and continuously as the treatment time increased. The combined use of gradient shaving preparation and micro FTIR‐ATR line analysis was found to be extremely effective for the depth profiling of organic materials. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2071–2078, 2003  相似文献   
96.
An arbitrary operator-valued function from the generalized Shur class is realized as the transfer function of a minimal optimal and minimal *-optimal dissipative scattering system with the Pontryagin state space. These results generalize Arov's results for the case of the Hilbert state space. Bibliography: 11 titles.  相似文献   
97.
98.
The ZnS:Cu,Al,Au (P22G) phosphor powder was bombarded by an electron beam in an O2 ambient, Ar ambient and other mixture of gases. These gases consisted of mixtures of O2 and COx, and O2, COx and Ar gas. Auger electron spectroscopy (AES) was used to monitor changes in the surface composition of the P22G phosphor during electron bombardment. When the P22G phosphor powder was exposed to the electron beam in a water-rich O2 ambient, a chemically limited ZnO layer was formed on the surface. The electron beam degradation of the P22G phosphor powder was also performed in a dry O2 ambient and a layer of ZnSO4 was formed on the surface. The ZnSO4 formation decayed exponentially with time and it is postulated that this was due to the diffusion of the charge reactants through the ZnSO4 film to the reaction interfaces. The P22G phosphor exposed to the electron beam in an Ar ambient and to the other gas mixtures degraded at a lower rate than in the case of the O2 ambient. This suggests that Ar and COx may suppress the degradation of the P22G phosphor powder.  相似文献   
99.
Since a comprehensive survey published in 1999 [1] much work was done in standardizing measuring methods to characterize the surface geometry of dispersed and/or porous solids and to certify reference materials. The present paper is an extension of a short communication [2]. It gives a survey on existing standards and reports on new drafts and proposals.  相似文献   
100.
The study deals with estimating the reliability of classification algorithms. The present article (the first of three) examines the statistical methods used for point estimation of the reliability of classifiers in the frequency approach. The estimation results are applicable to the small-sample case, which is of considerable importance in practice.  相似文献   
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