Studies of the kinetics of the reduction of chromate by glutathione and related thiols

The reduction of chromate by glutathione, its mono- and diethyl esters, -cysteine, 2-mercapto-propionic acid and mercapto-succinic acid has been studied. The empirical rate law k_obs = ab[Thiol]²/(1 + b[Thiol]) is obeyed by all of these thiols, at neutral pH. No evidence could be obtained for a first-order pathway in glutathione under these conditions. These observations are used to comment on the stability of intermediates potentially important in explaining chromate toxicity.     

3rd International Conference on Trace Element Speciation in Biomedical,Nutritional and Environmental Sciences

3rd International Conference on Trace Element Speciation in Biomedical, Nutritional and Environmental Sciences     

On the existence of equilibrium states in local quantum field theory

It is shown that any local quantum field theory admits thermodynamical equilibrium states (KMS-states) for all positive temperatures provided it satisfies a nuclearity condition, proposed by Wichmann and one of the authors, which restricts the admissible number of local degrees of freedom.Dedicated to E. H. Wichmann on the occasion of his 60th birthday     

A comparison of some hierarchal agglomerative clustering algorithms for structure—property correlation

Six different hierarchal clustering algorithms were used to cluster eleven sets of compounds for which associated property data were available. The effectiveness of the clustering in each case was assessed by inspection of the resulting tree diagram representing the classification and by the utility of the classification for molecular property prediction. The best predictions were generally obtained by using the algorithm proposed by Ward while the widely-used nearest neighbour algorithm performed very badly. Unstandardised data gave better results than standardised data although the difference was less when structurally related, rather than structurally disparate, groups of compounds were tested.     

The prism algorithm for two-electron integrals

A new approach to the evaluation of two-electron repulsion integrals over contracted Gaussian basis functions is developed. The new scheme encompasses 20 distinct, but interrelated, paths from simple shell-quartet parameters to the target integrals, and, for any given integral class, the path requiring the fewest floating-point operations (FLOPS ) is that used. Both theoretical (FLOP counting) and practical (CPU timing) measures indicate that the method represents a substantial improvement over the HGP algorithm.     

Zur Kenntnis von Natrium-hexafluoromanganat(III)

Sodium hexafluoromanganate(III) has been synthesized by heating equimolecular quantities of Na₂MnF₅ and NaF in argon atmosphere. The compound is monoclinic witha=5.56 (1) Å,b=5.84 (1) Å,c=8.10 (2) Å, =90.7 (2) andZ=2. It is a high spin complex with _eff and the deformation of the octahedra is evident from its IR-spectra. Two enantiotropic transitions (at 562 and 653°C) and the melting point at 800°C have been observed.

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8. Mitt.: Mh. Chem.106, 483 (1975).     

Pyrolysis of homoadamant-3-ene

Pyrolysis of homoadamant-3-ene ($\text{5}$), generated from 1-adamantylcarbene ($\text{7}$), leads to the same three olefins ($\text{2}$, $\text{3}$, and $\text{4}$) that are produced from pyrolysis of 3-homoadamantyl acetate ($\text{1}$).