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91.
Perumal Elumalai Vladimir V. Plashnitsa Taro Ueda Masaharu Hasei Norio Miura 《Ionics》2007,13(6):387-393
The effect of thickness of oxide-sensing electrode (SE) on NO2 sensitivity of the planar sensor based on yttria-stabilized zirconia (YSZ) was examined at high temperatures. The sensitivity
of the sensor increased with decreasing thickness of SE, and the highest sensitivity was obtained by using the thinnest layer
of Cr2O3–SE (2.7 μm) at 700 °C. In the case of NiO–SE, the highest sensitivity was observed for the sensor using the 4 μm-thick SE
even at high temperature of 850 °C. Based on the results of the measurements for the complex impedances, the polarization
curves, and the gas-phase NO2 decomposition catalysis, it was confirmed that the catalytic activity to the gas-phase NO2 decomposition on the oxide–SE matrix played an important role in determining the NO2 sensitivity of the present sensors.
This artice was accidentally published twice. This is the second publication, please cite only the authoritative first one
which is available at . An additional erratum is available at .
An erratum to this article can be found at 相似文献
92.
We report the direct observation of the effects of quenched disorder on the critical behavior of partially frustrated amorphous FeMnZr alloys by the systematic analysis of high-precision ac susceptibility data and dc magnetization data. Interestingly, the analysis reveals that the presence of short-range quenched disorder does not alter the actual critical behavior. However, it does affect quantities such as the Curie temperature, the peak value of effective exponent gamma, width of the peak, and crossover temperatures. The observed temperature dependence of the effective critical exponent can be understood in terms of the field-theoretical renormalization group approach. Also, the present results would help in identifying the main source of the spread in the exponent values reported in the literature. 相似文献
93.
A convenient method for the conversion of electron rich benzylic hydrocarbons to carbonyl compounds is reported. 相似文献
94.
Progress in the research of artemisinin and its analogues as antimalarials: an update 总被引:3,自引:0,他引:3
Malaria is the number one infectious disease in the world today. Worldwide, over two million people die each year from malaria. This shocking reality is largely due to the emergence of drug resistant strains of Plasmodium falciparum. Artemisinin, a sesquiterpene lactone endoperoxide isolated from Artemesia annua has been shown to be a fast acting, safe and effective drug against multidrug-resistant and sensitive strains of P. falciparum. This article reports a survey of the literature dealing with artemisinin related antimalarial issues that have appeared from 1980s to the beginning of 2003. A broad range of medical and pharmaceutical disciplines is covered, including a brief introduction about discovery, phytochemical aspects, antimalarial mechanism of action, pharmacokinetics, and major drawbacks and various structural modifications made to overcome them. 相似文献
95.
In this paper we obtain a number of interesting results on the connection
that exists between the essential lower bound of an element in a von
Neumann algebra and its Fredholm properties. These connections lead to an
extension of a well-known perturbation theorem on Fredholm operators of
index zero. Finally we obtain for special cases necessary and sufficient conditions
for elements in the closure of the group of invertible elements to be
essentially topological divisor of zero 相似文献
96.
Electrical resistivity (ρ) of the amorphous (a-)Fe100−c
Zr
c
(c=8.5, 9.5 and 10) alloys has been measured in the temperature range 77 to 300 K, which embraces the second-order magnetic
phase transition at the Curie temperature point T
c. Analysis of the resistivity data particularly in the critical region reveals that these systems have a much wider range
of critical region compared to other crystalline ferromagnetic materials. The value of T
c and specific heat critical exponent, α has the same values as those determined from our earlier magnetic measurements. The value of α for all the present investigated alloys are in close agreement with the values predicted for three-dimensional (3D) Heisenberg
ferromagnet systems, which gives contradiction to the earlier results on similar alloys. It is observed from the analysis
that the presence of quenched disorder does not have any influence on critical behavior. 相似文献
97.
Nonlinear Dynamics - Analysis of electrostatic floating potential fluctuations associated with multiple anodic double layer revealed a complexity dynamic coexisting with chaotic behavior. These... 相似文献
98.
Conjugated polymers with carbazole,fluorene, and ethylene dioxythiophene in the main chain and a pendant cyano group: Synthesis,photophysical, and electrochemical studies 下载免费PDF全文
Vivek Anand Elumalai Ramachandran Raghavachari Dhamodharan 《Journal of polymer science. Part A, Polymer chemistry》2016,54(17):2774-2784
Six new conjugated polymers comprising of carbazole, fluorene, and ethylene dioxythiophene (EDOT) moieties along the backbone with a pendant cyano group attached to the ethylene moiety have been designed and synthesized via Sonogashira coupling polymerization reaction. Optical and electrochemical characterizations have shown that the energy band gaps lie within the range of 2.35–2.44 eV. Additionally, the presence of carbazole and EDOT makes these polymers better hole transporting materials, which is reflected from their low oxidation potential peaks (0.55–1.11 V) in cyclic voltammograms. Furthermore, the aggregation enhanced emission (AEE) phenomenon resulted in a 2.6‐fold increase in fluorescence intensity in a 90:10 THF/water mixture in comparison to pristine THF. The AEE properties were further verified by DLS (dynamic light scattering) experiment and SEM (scanning electron microscopy) studies. Polymers in solution as well as in polystyrene matrix emit in the green region (quantum yield in solution state Φf =41–43%) with CIE values (0.25–0.36, 0.52–0.57). Excellent thermal stability is observed for the new polymers. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2774–2784 相似文献
99.
Dongamanti Ashok Aamate Vikas Kumar Devulapally Mohan Gandhi Gundu Srinivas Balabadra Saikrishna Manga Vijjulatha Yogeeswari Perumal Sriram Dharmarajan Balasubramanian Sridhar 《Molecular diversity》2017,21(4):999-1010
Molecular Diversity - On the basis of reported antimycobacterial property of chroman-4-one pharmacophore, a series of chemically modified bis-spirochromanones were synthesized starting from... 相似文献
100.
A mixed potential type yttria-stabilized zirconia-based sensor using NiO sensing electrode and Pt reference electrode was fabricated, and its NO2 sensing characteristics were examined at various operating temperatures in the range of 700–950 °C. It was observed that the sensitivity to NO2 strongly depends on the operating temperature of the sensor; the sensitivity decreases with increasing operating temperature, while the response/recovery rates increase. To rationalize this temperature dependence of NO2 response, polarization curves and complex impedances of the sensor were measured in the base gas and in the sample gas (400 ppm NO2?+?base gas) at various operating temperatures. It turned out that the operating temperature had a strong influence on the rate of anodic reaction of oxygen; the increased rate of anodic reaction leads to lower NO2 sensitivity and quicker response/recovery at higher operating temperature. 相似文献