排序方式: 共有68条查询结果,搜索用时 46 毫秒
31.
N. G. Semaltianos S. Logothetidis W. Perrie S. Romani R. J. Potter M. Sharp P. French G. Dearden K. G. Watkins 《Applied Physics A: Materials Science & Processing》2009,94(3):641-647
Nanoparticles of the II–VI semiconductors CdTe, CdSe and ZnTe were synthesized by laser ablation (387 nm, 180 fs, 1 kHz, pulse
energy of 7 μJ (fluence of 2 J/cm2)) of the target materials in methanol, de-ionized water and acetone. The nanoparticles size distributions follow log-normal
functions with median diameters between about 6 and 11 nm for the several materials. The nanoparticles have the same crystalline
structure as that of the corresponding bulk material and under the present conditions of ablation are rich in the higher volatility
element of the two in the binary alloy and oxidized. Photoluminescence emission in the green-yellow (∼570 nm) was detected
from CdSe nanoparticles. 相似文献
32.
Elizabeth R. Bowkett James L. Maggs Jennifer A. Perrie Andrew V. Stachulski 《Tetrahedron》2007,63(32):7596-7605
Acyl glucuronides are key metabolites for many carboxylic acid-containing drugs, notably those of the non-steroidal anti-inflammatory class. In the processes of drug safety assessment and new drug development, it is essential that acyl glucuronides, if formed in vivo, should be made conveniently available for bioevaluation. We recently showed that selective acylation of allyl glucuronate is a promising method for the synthesis of these metabolites in good yield and with excellent β-anomeric selectivity. We now give fuller details of the allyl ester method and further report that benzyl glucuronate performs at least equally well in the acylation step, offering the advantage of very mild deprotection by catalytic transfer (or conventional) hydrogenation. Depending on the compatibility of other functional groups, as discussed below, this will be the method of choice for many acyl glucuronide syntheses. The value of the method is demonstrated in particular by the synthesis of several acyl glucuronides that are known metabolites of important drugs. 相似文献
33.
电感耦合等离子体原子发射光谱法测定钛酸钡纳米粉体中7种杂质元素 总被引:3,自引:0,他引:3
钛酸钡纳米粉体样品用盐酸溶解,在所得样品溶液中用电感耦合等离子体原子发射光谱法测定了以氧化物存在于样品中的7种杂质元素(包括镁、锶、钾、钠、铝、硅及铁),对测定的光谱条件进行了试验并优化达到上述各元素的测定上限为0.1%(质量分数).测得方法的检出限(3S/b)为(单位μg·L-1):2.0(铝),1.0(铁),20.0(钾),0.2(镁),4.0(钠),3.0(硅)及0.5(锶).应用此方法分析了两件实样,所得结果的相对标准偏差(n=6)小于等于2.0%,对其中4种杂质元素(镁、钾、钠和锶)同时用HG/T 3587-1999标准中的方法作分析校核,所得结果与此方法结果一致. 相似文献
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36.
N. G. Semaltianos S. Logothetidis W. Perrie S. Romani R. J. Potter S. P. Edwardson P. French M. Sharp G. Dearden K. G. Watkins 《Journal of nanoparticle research》2010,12(2):573-580
Silicon nanoparticles were generated by femtosecond laser [387 nm, 180 fs, 1 kHz, pulse energy = 3.5 μJ (fluence = 0.8 J/cm2)] ablation of silicon in deionized water. Nanoparticles with diameters from ~5 up to ~200 nm were observed to be formed in
the colloidal solution. Their size distribution follows log-normal function with statistical median diameter of ≈20 nm. Longer
ablation time leads to a narrowing of the nanoparticle size distribution due to the interaction of the ablating laser beam
with the produced nanoparticles. Raman spectroscopy measurements confirm that the nanoparticles exhibit phonon quantum confinement
effects and indicate that under the present conditions of ablation they are partially amorphous. 相似文献
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38.
To study the electromagnetic (EM) backscatter
characteristics of freak waves at moderate incidence angles, we
establish an EM backscattering model for freak waves in
(1+1)-dimensional deep water. The nonlinear interaction between
freak waves and Bragg short waves is considered to be the basic
hydrodynamic spectra modulation mechanism in the model. Numerical
results suggest that the EM backscattering intensities of freak
waves are less than those from the background sea surface at
moderate incidence angles. The normalised radar cross sections
(NRCSs) from freak waves are highly polarisation dependent, even at
low incidence angles, which is different from the situation for
normal sea waves; moreover, the NRCS of freak waves is more
polarisation dependent than the background sea surface. NRCS
discrepancies between freak waves and the background sea surface
with using horizontal transmitting horizomtal (HH) polarisation are
larger than those with using vertical transmitting vertical (VV)
polarisation, at moderate incident angles. NRCS discrepancies
between freak waves and background sea surface decreases with the
increase of incidence angle, in both HH and VV polarisation radars.
As an application, in the synthetic-aperture radar (SAR) imaging of
freak waves, we suggest that freak waves should have extremely low
backscatter NRCSs for the freak wave facet with the strongest slope.
Compared with the background sea surface, the freak waves should be
darker in HH polarisation echo images than in VV echo images, in SAR
images. Freak waves can be more easily detected from the background
sea surface in HH polarisation images than in VV polarisation
images. The possibility of detection of freak waves at low incidence
angles is much higher than at high incidence angles. 相似文献
39.
Refractive index modification of pure poly(methyl methacrylate) (PMMA) is investigated as a function of pulse duration using femtosecond lasers at 800 and 387 nm wavelength. It is observed that at 800 nm, the refractive index is modified more efficiently as the pulse duration decreases below 100 fs, whereas at 387 nm, efficient index modification is accomplished with longer, 180 fs pulses. Results suggest that three- and two-photon absorption is responsible for modification of pure PMMA at 800 nm and 387 nm, respectively. Repeated irradiation with short pulses of low laser fluence allows control of the photomodification via incubation, thus reducing bulk damage. 相似文献
40.
This paper presents and demonstrates a method for using magnetic resonance imaging to measure local pressure of a fluid saturating a porous medium. The method is tested both in a static system of packed silica gel and in saturated sintered glass cylinders experiencing fluid flow. The fluid used contains 3% gas in the form of 3-mum average diameter gas filled 1,2-distearoyl-sn-glycero-3-phosphocholine (C18:0, MW: 790.16) liposomes suspended in 5% glycerol and 0.5% Methyl cellulose with water. Preliminary studies at 2.35 T demonstrate relative magnetic resonance signal changes of 20% per bar in bulk fluid for an echo time T(E)=40 ms, and 6-10% in consolidated porous media for T(E)=10 ms, over the range 0.8-1.8 bar for a spatial resolution of 0.1 mm(3) and a temporal resolution of 30 s. The stability of this solution with relation to applied pressure and methods for improving sensitivity are discussed. 相似文献