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81.
Rosa Pereira Tommy Julianto Peh-Kim Ang Sharon Sheue-Nee Ling Carlos Mauricio Barbosa Kah-Hay Yuen Abu Bakar Abdul Majeed 《Chromatographia》2010,71(5-6):373-381
A sensitive and rapid routine LC method was validated for measuring cefotaxime incorporated in three different pH-sensitive nanoparticles. The drug was chromatographed on a C18 reversed-phase column; the mobile phase used was 0.05 M aqueous ammonium acetate, acetonitrile and tetrahydrofuran (87:11:2, v/v) adjusted to pH 5.5 with acetic acid. The flow rate was 1 mL min?1 and cefotaxime was quantified at 254 nm, with a sensitivity range of 0.005 AUFS. The validated method was specific, linear (R 2 ≥ 0.999), precise and accurate in a concentration range of 0.2–50.0 μg mL?1. The method was rapid, selective and suitable for evaluation of cefotaxime in pH-sensitive Eudragit nanoparticles. 相似文献
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M. Murugesan P. Selvam M. Sharon L. C. Gupta R. Pinto C. S. Gopinath S. Subramanian 《Applied Physics A: Materials Science & Processing》1997,64(2):177-179
Single phase Ba-free Sr-based YSr2Cu
3-x
M
x
O7+δ (M=Mo, W and Re) compounds have been stabilized by chemical doping. Superconductivity is observed for these phases in the
range 30–45 K. X-ray diffraction studies suggest a relatively small orthorhombicity compared to Ba-analogue. X-ray photoelectron
spectroscopic investigations reveal that the stabilizing cations are in the hexavalent state. The observation of the higher
oxidation state of M-ions accounts for the excess oxygen content in these phases which is in accordence with the diffraction
results.
Received: 10 June 1996 / Accepted: 20 September 1996 相似文献
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We consider a mixture of two immiscible oppositely charged molecules strongly adsorbed to an interface, with a neutral nonselective molecular background. We determine the coexistence between a high density ionic periodic phase and a dilute isotropic ionic phase. We use a strong segregation approach for the periodic phase and determine the one-loop free energy for the dilute phase. Lamellar and hexagonal patterns are calculated for different charge stoichiometries of the mixture. Molecular dynamics simulations exhibit the predicted phase behavior. The periodic length scale of the solid phase is found to scale as epsilon/(lB psi3/2), where psi is the effective charge density, lB is the Bjerrum length, and epsilon is the cohesive energy. 相似文献
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Daniel Sharon Daniel Hirshberg Michal Afri Aryeh A. Frimer Malachi Noked Doron Aurbach 《Journal of Solid State Electrochemistry》2017,21(7):1861-1878
During the last two decades, we have observed a dramatic increase in the electrification of many technologies. What has enabled this transition to take place was the commercialization of Li-ion batteries in the early nineties. Mobile technologies such as cellular phones, laptops, and medical devices make these batteries crucial for our contemporary lifestyle. Like any other electrochemical cell, the Li-ion batteries are restricted to the thermodynamic limitations of the materials. It might be that the energy density of the most advance Li-ion battery is still too low for demanding technologies such as a full electric vehicle. To really convince future customers to switch from the internal combustion engine, new batteries and chemistry need to be developed. Non-aqueous metal-oxygen batteries—such as lithium–oxygen, sodium–oxygen, magnesium–oxygen, and potassium–oxygen—offer high capacity and high operation voltages. Also, by using suitable polar aprotic solvents, the oxygen reduction process that occurs during discharge can be reversed by applying an external potential during the charge process. Thus, in theory, these batteries could be electrically recharged a number of times. However, there are many scientific and technical challenges that need to be addressed. The current review highlights recent scientific insights related to these promising batteries. Nevertheless, the reader will note that many conclusions are applicable in other kinds of batteries as well. 相似文献