Investigation of changes in catalyst for conversion by means of steam during use in an industrial reactor

A study was made of the changes in the active component of a commercial catalyst for methane reforming by means of steam, as a function of its duration of use and of its position in an industrial reactor. The samples for examination were taken after 3, 8, 9 and 20 months of catalyst use, and from seven different levels in the reformer tube, ranging from the top to the bottom.DTA, TG, IR spectroscopy, X-ray diffraction and surface area determination were used to follow the catalyst changes.

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Zusammenfassung Veränderungen der aktiven Komponente eines kommerziellen Katalysators zur Methanreformierung mittels Wasserdampf wurden in Abhängigkeit von der Betriebsdauer und der Lage im industriellen Reaktor untersucht. Proben für die Untersuchung wurden nach 3-, 8-, 9- und 20-monatiger Betriebsdauer aus 7 verschiedenen Höhen vom Boden bis zum Kopf des Reformer-Rohres entnommen. Veränderungen des Katalysators wurden mittels DTA, TG, IR-Spektroskopie, Röntgendiffraktometrie und Oberflächenmessungen verfolgt.

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, - , @2 . 3, 8, 9 20 -, -. , , , , , .

     

Ammonium nitrate changes during thermal analysis

A study was made of the difference occurring in ammonium nitrate during investigation by DTA and by DSC. The results show that the DTA of ammonium nitrate (p.a.) is accompanied by the crystal transformation IV III II I and melting. During DSC investigation of the same ammonium nitrate samples, the salt undergoes the transformations IV III and IV II in parallel; then follow the crystal transformations III II I and melting. The investigation conditions and the history of the samples do not essentially influence the crystal transformations during thermal analysis.

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Zusammenfassung Bei DTA und DSC von Ammoniumnitrat zu beobachtende Unterschiede wurden untersucht. Bei der DTA von p.a. Ammoniumnitrat verlaufen die Kristallumwandlungen IV III II I sowie der Schmelzvorgang. Während der DSC der gleichen Ammoniumnitratproben verlaufen die Übergänge IV III und IV II parallel, worauf die Kristallumwandlungen III II I und der Schmelzvorgang folgen. Die experimentellen Bedingungen und die Vorgeschichte der Proben hat keinen wesentlichen Einfluß auf die während der thermischen Analyse verlaufenden Kristallumwandlungen.

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. ( ..) IV III II I . , IV III IV II - , III II ar I . .

     

Author index

The thermal decomposition of N₂H₅Nd(SO₄)₂·H₂O has been studied by simultaneous TG and DSC and by isothermal weight change determination. The final product and the intermediate phases have been identified by chemical analysis, X-ray powder patterns and infrared spectroscopy. The solid phases in the decomposition sequence are: N₂H₅Nd(SO₄)₂· H₂O → N₂H₅Nd(SO₄)₂ → NH₄Nd(SO₄)₂ → Nd₂(SO₄)₃. The reactions overlap under dynamicconditions, isothermally, however, NH₄Nd(SO₄)₂ can be obtained by 200°C.     

Antioxidants and stabilizers: Part IC—Hydroperoxide deactivation by aliphatic sulfides. A model study

The hydroperoxide decomposing efficiencies of dioctadecylsulfide (I), dioctadecyldisulfide (IV) and dioctadecyl 3,3-thio-dipropionate (VII) have been compared at 75°C and 85°C. The formation of oxidation products from (I) and (IV) has been checked. Experimental evidence is given of the important rôle of the activation of the molecule of (IV) by the presence of two sulfidic sulfur atoms compared with the activation of the sulfur atom in (VII) by the alkoxycarbonyl group in the beta position. The explanation of the high efficiency of disulfide has been based on the formation of thiosulfinate—the key intermediate for the generation of peroxidolytic species—in the first reaction step.     

Enantiomers of sterically hindered n-aryl-4-pyridones: Chromatographic enrichment and thermal interconversion

N-Aryl-4-pyridones 1–6 were synthesized by condensation of the corresponding 4-pyrone with anilines. The enrichment of the enantiomers was achieved by liquid chromatography on triacctylcellulose, enantiomeric purities of(+)-1 and (+ )-2 being measured by ¹H-NMR in the presence of an optically active auxiliary. Barriers to partial rotation about the C-N bond in 1-4 were determined and compared with corresponding biphenyls.     

Photocatalytic Reduction of Nicotinamide Co-factor by Perylene Sensitized RhIII Complexes**

The ambitious goal of artificial photosynthesis is to develop active systems that mimic nature and use light to split water into hydrogen and oxygen. Intramolecular design concepts are particularly promising. Herein, we firstly present an intramolecular photocatalyst integrating a perylene-based light-harvesting moiety and a catalytic rhodium center ( Rh^IIIphenPer ). The excited-state dynamics were investigated by means of steady-state and time-resolved absorption and emission spectroscopy. The studies reveal that photoexcitation of Rh^IIIphenPer yields the formation of a charge-separated intermediate, namely Rh^IIphenPer ⋅ ⁺ , that results in a catalytically active species in the presence of protons.     

Reactivity of a N-Coordinated Germylene-Borane Complex: From Ge→B to Ge→Ga Coordination

Reactivity studies of the Ge^II→B complex L(Cl)Ge⋅BH₃ ( 1 ; L=2-Et₂NCH₂-4,6-tBu₂-C₆H₂) were performed to determine the effect on the Ge^II→B donation. N-coordinated compounds L(OtBu)Ge⋅BH₃ ( 2 ) and [LGe⋅BH₃]₂ ( 3 ) were prepared. The possible tuning of the Ge^II→B interaction was proved experimentally, yielding compounds 1-PPh₂-8-(LGe)-C₁₀H₆ ( 4 ) and L(Cl)Ge⋅GaCl₃ ( 5 ) without a Ge^II→B interaction. In 5 , an unprecedented Ge^II→Ga coordination was revealed. The experimental results were complemented by a theoretical study focusing on the bonding in 1 − 5 . The different strength of the Ge^II→E (E=B, Ga) donation was evaluated by using energy decomposition analysis. The basicity of different L(X)Ge groups through proton affinity is also assessed.     

Tuning the Structure and Properties of N-doped Positively Charged Polycyclic Aromatic Hydrocarbons

A detailed study of the geometry, aromatic character, electronic and magnetic properties for a series of positively charged N-doped polycyclic aromatic hydrocarbons (PAHs) was performed. Magnetic properties of the examined molecules were analyzed by means of the magnetically induced current density calculated using the diamagnetic-zero version of the continuous transformation of origin of current density (CTOCD-DZ) method. The comparative study of the local aromaticity of the studied molecules was performed using several different indices: energy effect (ef), harmonic oscillator model of aromaticity (HOMA) index, six centre delocalization index (SCI) and nucleus independent chemical shifts (NICS). The presence of N-atoms in the inner rings was found to cause a planarity distortion in the studied N-doped systems. The geometric changes and charged nature of the studied N-doped systems do not significantly influence the current density and the local aromaticity distribution in comparison with the corresponding parent benzenoid hydrocarbons. The present study demonstrates how quantum chemical calculations can be used for rational design of novel PAHs and for fine tuning of their properties.     

Screening of Synthetic Cathinones by Potentiometric Sensor Array and Chemometrics

This work demonstrates the analytical applicability of single ion-selective membranes (ISMs) and potentiometric sensor array to distinguish and detect cathinone derivatives. Potentiometric data from ISMs based on cation exchanger and varying content of calix[4]arene derivative were processed by principal component analysis (PCA). Such a combination of methods allowed discriminating various individual synthetic cathinones and their recognition from the mixture comprising primary amines (substituted amphetamines+aminoindane). Analytical parameters of ISM containing 1wt % of calix[4]arene derivative were sufficient to detect 1.0×10⁻⁴ mol.l⁻¹ 1-(4-fluorophenyl)-2-(ethylamino)butan-1-one and 2-(methylamino)-1-phenylbutan-1-one (buphedrone) in both model and saliva samples.     

Development of a Diamond Nanoparticles-based Nanosensor for Detection and Determination of Antiviral Drug Favipiravir

This study developed a nanosensor for the detection and determination of favipiravir, a presumed drug that has potential therapeutic efficacy in treating COVID-19 patients, from tablets and serum samples. This nanosensor was obtained by adding the optimum amount of diamond nanoparticles into carbon paste. For the determination of favipiravir adsorptive stripping differential pulse (AdSDPV) and adsorptive stripping square wave voltammetry (AdSSWV) were used. Limit of detection values were found as 4.83×10⁻⁹ M and 2.44×10⁻⁷ M for bulk and 5.18×10⁻⁸ M and 4.38×10⁻⁸ M for serum samples using AdSDPV and AdSSWV, respectively. Recovery studies made of the tablet and serum produced satisfactory results.