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131.
C. Gonilho Pereira R. Fangueiro S. Jalali M. Araujo P. Marques 《Mechanics of Composite Materials》2008,44(3):221-230
This paper reports on the development of braided reinforced composite rods as a substitute for the steel reinforcement in
concrete. The research work aims at understanding the mechanical behaviour of core-reinforced braided fabrics and braided
reinforced composite rods, namely concerning the influence of the braiding angle, the type of core reinforcement fibre, and
preloading and postloading conditions. The core-reinforced braided fabrics were made from polyester fibres for producing braided
structures, and E-glass, carbon, HT polyethylene, and sisal fibres were used for the core reinforcement. The braided reinforced
composite rods were obtained by impregnating the core-reinforced braided fabric with a vinyl ester resin. The preloading of
the core-reinforced braided fabrics and the postloading of the braided reinforced composite rods were performed in three and
two stages, respectively. The results of tensile tests carried out on different samples of core-reinforced braided fabrics
are presented and discussed. The tensile and bending properties of the braided reinforced composite rods have been evaluated,
and the results obtained are presented, discussed, and compared with those of conventional materials, such as steel.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 44, No. 4, pp. 327–338, May–June, 2008. 相似文献
132.
L. C. Mendes R. E. R. Abrigo V. D. Ramos P. S. C. Pereira 《Journal of Thermal Analysis and Calorimetry》2010,99(2):545-549
The influence of PC melt flow rate (MFR) on phase behavior, thermal and rheological properties of catalysed and non-catalysed
poly(ethylene terephthalate)/polycarbonate (PET/PC) (80/20 wt%) reactive blending were investigated. Two types of PC named
PC1 and PC2 with MFR 3.1 and 10.8 g/10 min, respectively, were used. Each PC and the catalyst showed significant influence
on calorimetric properties, thermal stability and WAXS patterns of the blends. Regarding to TG/DTG, the blends degraded in
two steps which were attributed to PET rich phase and PC one and permit to infer that a partially miscible blends were produced. 相似文献
133.
Lurdes M. Ciríaco Isabel M. da Silva Pereira Manuel R. Nunes Helena M. Mendonça Fernanda M. Costa 《Journal of Solid State Electrochemistry》2001,5(7-8):495-501
The effect of the partial substitution of tantalum by iron on the structural and electrical properties of the KTaO3 perovskite-type oxide powders has been studied. The powders were prepared by the standard ceramic method, and the respective
structural characterization performed by X-ray powder diffraction. From the synthesized oxide samples, iron-coated electrodes
were fabricated and tested as the anode for the oxygen evolution reaction in alkaline medium. An estimation of the electrode's
capacity has been calculated from the charging currents and the corresponding roughness factor evaluated. The electrocatalytic
activity/stability of the oxide electrodes in alkaline solutions has been analysed through the kinetic parameters.
Electronic Publication 相似文献
134.
The objective of the present research work was to develop a membrane with a high H2O/alcohol selectivity for pervaporation and for use in direct alcohol fuel cells. Sulfonated poly (ether ether ketone) (SPEEK) was coated with a thin continuous carbon molecular sieve (CMS) layer. The membranes obtained had 180- and 400-nm thick CMS layers that led to a clear reduction of alcohol crossover. The water/alcohol selectivity increased with the size of the alcohol molecules as follows: methanol < ethanol < n-propanol < iso-propanol. A water/n-propanol selectivity of up to 34,000 was obtained, confirming the molecular sieving effect. The system was tested in a direct methanol fuel cell using standard electrodes, and demonstrated a better performance than with plain membranes. In a later stage Pt was introduced in the CMS layer during the preparation of the membrane electrode assemblies, this had the advantage that the CMS layer not only acted as an alcohol barrier but also as a catalyst support. 相似文献
135.
We consider the harmonic and anharmonic chains of oscillators with self-consistent stochastic reservoirs and derive an integral
representation (à la Feynman-Kac) for the correlations, in particular, for the heat flow. For the harmonic chain, we give
a new proof that its thermal conductivity is finite in the steady state. Based on this integral representation for the correlations
and a perturbative analysis, the approach is quite general and can be extended to more intricate systems.
__________
Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 156, No. 1, pp. 138–146, July, 2008. 相似文献
136.
We study magnetic vortex-like excitations lying on a conic space background. Two types of them are obtained. Their energies appear to be linearly dependent on the conical aperture parameter, besides of being logarithmically divergent with the sample size. In addition, we realize a geometrical-like pinning of the vortex, say, it is energetically favorable for it to nucleate around the conical apex. We also study the problem of two vortices on the cone and obtain an interesting effect on such a geometry: excitations of the same charge, then repealing each other, may nucleate around the apex for suitable cone apertures. We also pay attention to the problem of the vortex pair and how its dissociation temperature depends upon conical geometry. 相似文献
137.
Time and temperature induced phase transformation in L‐isoleucine hydrochloride monohydrated crystal
Ricardo S. Ferreira Júnior Geanso M. Moura Andreia C. Pereira Paulo R. da Silva Ribeiro Luzeli M. da Silva Adenilson O. dos Santos 《Crystal Research and Technology》2016,51(12):738-741
Semi organic crystals have been intensively studied aiming applications in nonlinear optical (NLO). Such applicability requires crystals with both high quality and thermal stability, which make the full characterization of this material a topic issue. In this paper, single crystals of L‐isoleucine hydrochloride monohydrated (L‐Ile.H2O.HCl) was synthesized by slow evaporation technique and characterized by thermal analysis and X‐ray diffraction (XRD) measurements. XRD results at 298 K showed that the sample crystallize with the orthorhombic structure, and the lattice parameters obtained by Rietveld refinement were a = 5.873(3) Å, b = 24.814(4) Å, and c = 6.873(5) Å. Thermal analysis measurements shows four decomposition stages between 328 ‐480 K which were associated with loss of water by desolvation, loss crystallization water and decomposition of L‐Ile.HCl. XRD measurements as a function of temperature up to 428 K show an irreversible phase transformation. This transformation was obtained after 32 hours keeping the L‐Ile.HCl.H2O sample at 413 K. The analysis shows that phase transformation occurs due to water and chlorine losses without destroy the amino acid carbon chain and in the end of transformation only the precursor amino acid remains. L‐Ile.HCl.H2O present low thermal stability and the phase transformation is time and temperature dependent. 相似文献
138.
Ana R. Almeida Rui M.B. Carrilho Andreia F. Peixoto Artur R. Abreu Artur Silva Mariette M. Pereira 《Tetrahedron》2017,73(17):2389-2395
Different families of new amino compounds were efficiently synthesized, through optimized sequential processes, involving rhodium catalyzed hydroformylation as the key step. The selection of appropriate hydroformylation catalytic systems and reaction conditions allowed obtaining aldehydes derived from several n-alkyl olefins, cholest-4-ene and 3-vinyl-1H-indole, which were subsequently transformed, in one-pot, in to α-amino acids via hydroformylation/Strecker reaction, and in to tertiary amines via hydroaminomethylation, with excellent yields. 相似文献
139.
Johanna Méndez Arias Anelize de Oliveira Moraes Luiz Felipe Amarante Modesto Aline Machado de Castro Nei Pereira Jr 《Applied biochemistry and biotechnology》2017,181(2):593-603
Poly(ethylene glycol) (PEG 4000) and bovine serum albumin (BSA) were investigated with the purpose of evaluating their influence on enzymatic hydrolysis of sugarcane bagasse. Effects of these supplements were assayed for different enzymatic cocktails (Trichoderma harzianum and Penicillium funiculosum) that acted on lignocellulosic material submitted to different pretreatment methods with varying solid (25 and 100 g/L) and protein (7.5 and 20 mg/g cellulose) loadings. The highest levels of glucose release were achieved using partially delignified cellulignin as substrate, along with the T. harzianum cocktail: increases of 14 and 18 % for 25 g/L solid loadings and of 33 and 43 % for 100 g/L solid loadings were reached for BSA and PEG supplementation, respectively. Addition of these supplements could maintain hydrolysis yield even for higher solid loadings, but for higher enzymatic cocktail protein loadings, increases in glucose release were not observed. Results indicate that synergism might occur among these additives and cellulase and xylanases. The use of these supplements, besides depending on factors such as pretreatment method of sugarcane bagasse, enzymatic cocktails composition, and solid and protein loadings, may not always lead to positive effects on the hydrolysis of lignocellulosic material, making it necessary further statistical studies, according to process conditions. 相似文献
140.
Processes and products have by nature many quality characteristics that must be in some sense optimized simultaneously. With this aim, a method which can be used easily and efficiently by practitioners for optimizing multi‐response problems is proposed. Implementation steps and considerations, in addition to optimization measures to assess method's solutions and guide the analyst in finding an effective compromise solution, are also presented. Three classical examples from the literature are used to assess the performance of several prominent methods in the response surface methodology (RSM) framework and help practitioners make a better‐informed choice among them. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献