Effect of different downstream temperatures on the performance of a two-layer porous burner

The influence of considering different downstream temperatures on the performance of a two-layer porous burner is studied numerically. A 3D numerical model based on a unit cell was implemented to correctly predict the momentum, heat and mass transfer at the interface of the two layers. Two operating modes are simulated corresponding to the burner radiating to cold and hot environments. When the burner radiates to a hot environment, its radiative heat losses are lower and, as a consequence, the temperatures and pollutants emissions are higher. Additionally, the flame front moves upstream and stabilizes nearer the interface of the two layers.     

A new formalism for the dynamic modelling of cables

This article proposes a new formalism for the dynamic modelling of cables that can even be applied when they are submitted to cross flow of water or air. An important application is the case of umbilical cables used in remotely operated vehicles. The primary basis for the formulation is to assume that the continuous flexibility is represented by a discrete approach, consisting of rigid links connected by elastic joints, allowing movement in three dimensions. Each elastic joint allows three independent movements, called elevation, azimuth and torsion (twist). A significant contribution of the proposed formalism is the development of a compact equation that allows obtaining the Lagrangian of the system directly and automatically, regardless of the number of links chosen to form a chain of rigid bodies connected by flexible joints to represent the continuous flexibility of the cable. This formulation allows the construction of an algorithm for obtaining the equations of the dynamic model of flexible cables.     

Preparation and characterization of cobalt ferrite nanoparticles coated with fucan and oleic acid

Cobalt ferrite has attracted considerable attention in recent years due to its unique physical properties such as high Curie temperature, large magnetocrystalline anisotropy, moderate saturation magnetization, large magnetostrictive coefficient, excellent chemical stability and mechanical hardness. In this work we present the preparation, of fucan coated cobalt ferrite nanoparticles by a modified co-precipitation method and the study of their structural, microstructural and magnetic characteristics for their application as a solid support for enzymes immobilization and other biotechnology applications. Aqueous suspensions of magnetic particles were prepared by coprecipitation of Fe(III) and Co(II) in the presence of NaOH, acid oleic and fucan polymer. The X-ray diffraction indicates that the funtionalization does not degrade the core cobalt ferrite. The infrared (FTIR) bands, indicate the functional characteristics of the coating on the cobalt ferrite. Mössbauer spectra at room temperature indicate the presence of a broadened sextet plus a doublet which is typical of superparamagnetic relaxation. For the Co-ferrite uncoated and coated with fucan the doublets have areas of 36.1 % and 40.3 % respectively, indicating the presence of non-interacting particles and faster relaxation time. The Co-ferrite coated with oleic acid and oleic acid plus fucan have areas around 17.5 % and 17.1 % respectively which indicate a weak superparamagnetic relaxation due to a slow relaxation time. The magnetization measurements of the cobalt ferrite nanoparticles with and without coating confirm that they are superparamagnetic and this behavior is produced by the core nanoparticles rather than the coatings. The cobalt ferrite nanoparticles coated with oleic acid presented the highest magnetization than when coating with fucan.     

Ultrasound-promoted synthesis of 3-trichloromethyl-5-alkyl(aryl)-1,2,4-oxadiazoles

The alternative synthesis of 12 1,2,4-oxadiazoles using ultrasound irradiation from trichloroacetoamidoxime and acyl chlorides is reported. Seven of them are novel compounds. The 3-trichloromethyl-5alkyl(aryl)-1,2,4-oxadiazoles have been synthesised in better yields and shorter reaction times compared to the conventional method. This protocol can be applicable for preparation of 1,2,4-oxadiazoles containing aryl or alkyl groups attached at their C-5 side-chain.     

Ultrasound irradiation promoted efficient solvent-free lipase-catalyzed production of mono- and diacylglycerols from olive oil

This work reports the enzymatic production of mono- and diacylglycerols under the influence of ultrasound irradiation, in a solvent-free system, with and without the presence of surfactants at a constant temperature of 65°C, glycerol to oil molar ratio of 2:1 and a commercial immobilized lipase (Novozym 435) as catalyst. For this purpose, two operation modes were adopted: the use of a sonotrode (ultrasonic probe), without agitation, varying reaction time, irradiation amplitude (25-45% of the total power) and type of surfactant, and a mechanically stirred reactor (600 rpm) under ultrasound irradiation in a water bath, testing different surfactants. Results show that very satisfactory MAG and DAG yields, above 50 wt.%, can be obtained without the use of surfactant, at mild irradiation power supply (～130 W), with no important enzyme activity losses verified, in a relatively short reaction time (2h), and low enzyme content (7.5 wt.%). Also, reaction kinetic results show that contents of MAG+DAG as high as ～65 wt.% can be achieved at longer times (6h), indicating a promising route for producing MAG and DAG using ultrasound irradiation.     

Nash Equilibrium Seeking in Quadratic Noncooperative Games Under Two Delayed Information-Sharing Schemes

In this paper, we propose non-model-based strategies for locally stable convergence to Nash equilibrium in quadratic noncooperative games where acquisition of information (of two different types) incurs delays. Two sets of results are introduced: (a) one, which we call cooperative scenario, where each player employs the knowledge of the functional form of his payoff and knowledge of other players’ actions, but with delays; and (b) the second one, which we term the noncooperative scenario, where the players have access only to their own payoff values, again with delay. Both approaches are based on the extremum seeking perspective, which has previously been reported for real-time optimization problems by exploring sinusoidal excitation signals to estimate the Gradient (first derivative) and Hessian (second derivative) of unknown quadratic functions. In order to compensate distinct delays in the inputs of the players, we have employed predictor feedback. We apply a small-gain analysis as well as averaging theory in infinite dimensions, due to the infinite-dimensional state of the time delays, in order to obtain local convergence results for the unknown quadratic payoffs to a small neighborhood of the Nash equilibrium. We quantify the size of these residual sets and corroborate the theoretical results numerically on an example of a two-player game with delays.

     

Controlled adsorption of cytochrome c to nanostructured gold surfaces

Herein, we present a novel method based on the use of the symmetrical T4 bacteriophage capsid as a scaffold for preparing the gold-coated iron ternary core/shell nanostructure. Results showed that the thick gold shell was obtained to effectively protect Fe core from oxidation. Magnetic measurements showed that the nanocomposites were superparamagnetic at room temperature with a blocking temperature of about 35?K. At 3?K, its coercivity of 1142.86 Oe was larger than the existing experimental values. The magnetic property of Au/T4 was also tested, demonstrating the source of the magnetic sample arising from the Fe core only. The absorption spectrum of the Fe@Au/T4 complex was measured and compared with gold/virus. Different thickness gold shells were controlled in the synthesis by tuning the Au salt addition. On the basis of results and discussion, we further speculated the general growing mechanism of the template-supported Fe@Au process.     

Analysis of Pre-Columbian objetcs from Cupisnique, one of the oldest culture from Perú, using a portable X-ray fluorescence equipment

Cupisnique (2000–200 BC) is one of the first complex societies that developed in the Jetequepeque valley in the “Formative period.” It includes several settlements: Puémape on the coast, Limoncarro in middle valley, Montegrande and Tembladera in the upper valley, and Kuntur Wasi in San Pablo. Currently the valley comprises two provinces, Pacasmayo and Chepen in the La Libertad region, north of Lima. Consideration should be given to cupisniques as premetallurgical culture, and the only used metal was gold, which is present in the native state, on the soil surface or shallow, and attracted attention because of color, brightness, weight, ductility, and inalterability. We analyzed three Cupisnique metal objects belonging to the Larco Museum of Lima designated with No. 4 (pectoral), No. 7 (pendant), and No. 12 (bracelet), using a portable energy-dispersive X-ray fluorescence equipment. Mean value for the pectoral were Au (62 %), Ag (23 %), Cu (15 %); for the pendant, Au (81 %), Ag (16.5 %), Cu (2.5 %); and for the bracelet, Au (69.1 %), Ag (20 %), and Cu (10.9 %).