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71.
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Sem Raj Tamang Andreas J. Achazi Haley S. Rust Pramod Dhungana Pere Miró James D. Hoefelmeyer 《Tetrahedron》2019,75(16):2365-2370
The title compound was evaluated as catalyst for Suzuki coupling of aryl halides (X?=?I, Br) with phenylboronic acid at room temperature. The rates of the reactions increase with increasing Hammet sigma constant of m-substituents on the arylhalide. The presence of ortho groups on the arylhalides had the effect of lowering the reaction rates. Density functional theory study of the mechanism for the formation of a Pd(0) complex from the title molecule was performed. Reductive elimination of chloride and the η4-BCCC moiety was endergonic and ruled out as a likely pathway. Instead, conversion of the title molecule to phenyl({2-[mesityl(quinolin-8-yl-κN)boryl]-3,5-dimethylphenyl}methyl-κC)palladium(II) complex is thermodynamically favored and predicted to further react with the solvent and the Suzuki coupling reagents to undergo reductive elimination of diphenyl to form a reactive Pd(0) complex. 相似文献
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We characterize the exchange property for non-unital rings in terms of their local rings at elements,and we use this characterization to show that the exchange property is Morita invariant for idempotent rings.We also prove that every ring contains a greatest exchange idela(with respect to the inclusion). 相似文献
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77.
Jordi Farjas Núria Butchosa Pere Roura 《Journal of Thermal Analysis and Calorimetry》2010,102(2):615-625
In a recent article, we obtained an approximate solution for the evolution of a transformed fraction under isochronal conditions
for a large variety of single-step transformations. We verified that this solution is accurate and can, in many instances,
be used instead of the exact numerical solutions of the corresponding differential equations. In this article we want to examine
the possibilities offered by an analytical solution in the analysis of thermoanalytical curves. We will show that for single-step
transformations, our model predicts that under the proper time scaling the thermograms obtained at different heating rates
merge into a single curve. This ‘universal curve’ is exclusively related to the kinetic model. In addition, the universal
curve can be obtained from experimental thermograms by means of a simple transformation. In this way, the dependence of the
experimental curves on the rate constant and the kinetic model can easily be separated, making it possible to independently
determine the kinetic parameters and the kinetic model. In addition, one can easily check the validity of the kinetic analysis
as well as calculate a reliable statistical measure of the goodness of the single-step assumption. 相似文献
78.
A scheme to quantify the symmetry content of the electronic wave function and molecular orbitals for arbitrary molecules is developed within the formalism of Continuous Symmetry Measures (CSMs). After defining the symmetry operation expectation values (SOEVs) as the key quantity to gauge the symmetry content of molecular wavefunctions, we present the working equations to be implemented in order to carry out real calculations using standard quantum chemistry software. The potentialities of a symmetry analysis using this new method are shown by means of some illustrative examples such as the changes induced in the molecular orbitals of a diatomic molecule by an electronegativity perturbation, the breaking of orbital symmetry along the dissociation path of the H(2) molecule, the changes in the molecular orbitals upon a geometrical distortion of the benzene molecule, and the inversion symmetry content in the different spin states of the [Fe(CH(3))(4)](2-) complex. 相似文献
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Jose M. González-Domínguez Pere Castell Mohammed Naffakh Marián A. Gómez 《Polymer Degradation and Stability》2010,95(10):2065-2075
Novel nanocomposite materials were prepared by incorporating block copolymer-wrapped single-wall carbon nanotubes (SWCNTs) into a trifunctional epoxy resin. The work was focused on the study of the influence of the SWCNTs and the block copolymer based on ethylene oxide and propylene oxide, Pluronic F68, on the thermal and thermo-oxidative cleavage reactions of the resin. A nanocomposite sample containing 2 wt% Pluronic-wrapped SWCNTs was prepared and its behaviour compared with that of Pluronic/epoxy and SWCNT/epoxy composites. Their thermal performance in both oxidative and inert atmospheres was evaluated by different techniques including thermogravimetric analysis (TGA), mass spectrometry and infrared spectroscopy. A kinetic study of the TGA data in both atmospheres based on the Vyazovkin’s advanced isoconversional method showed differences in the activation energies. Infrared spectroscopy of residues extracted at various steps during dynamic heating indicated a common degradation mechanism for all samples, and improved thermo-oxidative performance in the nanocomposite containing Pluronic-wrapped SWCNTs. 相似文献