Features of the Quenching of the Triplet States of Water-Soluble Porphyrins by Molecular Oxygen

Using the methods of time-resolved absorption spectroscopy, we have investigated the features of quenching, by molecular oxygen, of the excited triplet states of water-soluble 5,10,15,20-tetrakis-(4-N-methylpyridyl)-porphyrin (H₂TMPyP) and 5,10,15,20-tetrakis-(4-sulfonatophenyl)-porphyrin (H₂TSPP) in water–ethanol solutions. It has been revealed that for both compounds the rate constant of quenching of the triplet states increases with increasing viscosity of the medium. Quenching of the excited triplet states of the dissociated (in water) and undissociated (in ethanol) forms of water-soluble porphyrins occurs with a different efficiency, and the rate constant of quenching the triplet states by molecular oxygen k _T thereby is higher for the dissociated form. It has been shown by means of mathematical modeling that the experimental results obtained can be described in terms of the change in the rate constants of intracomplex transitions in the porphyrin–oxygen collisional complex at varied solution viscosity and their difference for the dissociated and undissociated forms of water-soluble porphyrin.     

Krylov subspaces and the analytic grade

Typical behaviour of the solution of a linear system of equations obtained iteratively by Krylov methods can be characterized by three stages. Initially the residual diminishes steadily; this is followed by stagnation and finally rapid convergence near the algebraic grade. This study examines this behaviour in terms of the concepts of approximately invariant subspace and what we have called the analytic grade of a Krylov sequence. It is shown how the small Ritz values play a vital role in the convergence and how this knowledge helps in the construction of an effective preconditioner. Copyright © 2004 John Wiley & Sons, Ltd.     

Energetics of an adiabatically-loaded excited anharmonic oscillator

The dependence of the energy characteristics on an adiabatically slowly increasing external force is determined analytically for an anharmonic oscillator. The analytical results are confirmed by a numerical calculation. The nature of the force dependences of the energy characteristics are determined and discussed. Fiz. Tverd. Tela (St. Petersburg) 39, 153–157 (January 1997)     

Existence regions of regimes with anomalously high rates of plasma generation in grid plasma switch elements

Results are presented from a systematic investigation of the conditions under which anomalously high rates of plasma generation are observed in the anode region of a low-voltage Knudsen arc in grid plasma switch elements. The phenomenon develops over a wide range of currents and switched voltages under conditions for which the plasma density in the cathode-grid region is noticeably higher than the density in the anode region. and its onset is characterized by a pronounced pressure threshold of ∼2×10⁻² Torr. The results are analyzed from the standpoint of the possible mechanisms for anomalous plasma generation — collisional nonresonance diffusion of electrons in velocity space, leading to enrichment of the distribution function in fast particles, and the collapse of Langmuir waves in the gap at the high energies of the beam produced when the wires of the grid are bridged by the quenching pulse and and the current is blocked. Zh. Tekh. Fiz. 67, 15–21 (June 1997)     

Characteristics of nonlinear reflection of radiation associated with waverfront reversal by a surface

The dependence of the nonlinear reflection coefficient R of a mirror with a wavefront reversing surface on the intensity I of the reference wave is analyzed in terms of a phenomenological model of a medium having a nonlinear Fresnel reflection amplitude coefficient φ. Substantial differences are revealed for media having different signs of the nonlinearity coefficient β=(dφ/dI). It is shown that R is related to the magnitude D of the dynamic range of the wavefront reversing mirror by the expression RD=Q_s' where Q_s is a parameter which defines the “quality” of the nonlinear medium. Far-Eastern State Academy of Communications. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 68–70, August, 1997.     

Propagation of magnetostatic waves in unsaturated ferrite films with a strip domain structure

The propagation of surface and volume magnetostatic waves in unsaturated films of yttrium iron garnet is studied experimentally for the case when the wavelength greatly exceeds the domain width, while the domain width is comparable to the film thickness. The characteristics of these waves are examined for symmetric linear, asymmetric linear, and symmetric zigzag strip domain structures in the films. These characteristics cannot be explained by a theory based on averaging the magnetization over all the domains. Zh. éksp. Teor. Fiz. 111, 1016–1031 (March 1997)     

Resonance enhancement of diffuse scattering of x-rays in a waveguide heterostructure

The diffuse scattering of x rays in a four-layer waveguide-type heterostructure is investigated. The dynamic enhancement of diffuse scattering is detected experimentally in regions corresponding to the excitation of waveguide modes for both the incident and scattered waves. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 4, 219–223 (25 August 1997)     

High power CW solid-state multilaser system

A laser system containing four CW Nd:YAG double-rod lasers, transforming optics and a fibre with input-output optics has been designed and investigated. It is shown that reduction of the beam parameter product of the non-Gaussian beams in the image space of the lens has made it possible to collect the emission of four lasers to the same fibre. Independent laser operation has provided the output power control in the range of 10–900 W with a stable light spot size on the input end of the fibre.     

Investigation of acceptor centers in semiconductors with the diamond crystal structure by the μ − SR method

The residual polarization of negative muons in crystal silicon samples with phosphorus (P: 1.6×10¹³ cm⁻³) and antimony (Sb: 2×10¹⁸ cm⁻³) impurities is investigated. The measurements are made in a 1000 G magnetic field oriented in a direction transverse to the muon spin in the temperature range 4–300 K. The relaxation rate and shift of the precession frequency in the silicon sample with the phosphorus impurity are measured more accurately than previously. It is found that in antimony-doped silicon the acceptor center _μ A1 at temperatures below 30 K can be in both ionized and neutral states. The experimental data are interpreted on the basis of spin-lattice relaxation of the magnetic moment of an acceptor center, formation of acceptor-donor pairs, and recombination of charge carriers at the acceptor. Preliminary measurements showed a nonzero residual polarization of negative muons in germanium. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 1, 61–66 (10 July 1998)