High-frequency single-electron transport in a quasi-one-dimensional GaAs channel induced by surface acoustic waves

We report on an experimental investigation of the direct current induced by transmitting a surface acoustic wave (SAW) with frequency 2.7 GHz through a quasi-one-dimensional (1D) channel defined in a GaAs - AlGaAs heterostructure by a split gate, when the SAW wavelength was approximately equal to the channel length. At low SAW power levels the current reveals oscillatory behaviour as a function of the gate voltage with maxima between the plateaux of quantized 1D conductance. At high SAW power levels, an acoustoelectric current was observed at gate voltages beyond pinch-off. In this region the current displays a step-like behaviour as a function of the gate voltage (or of the SAW power) with the magnitude corresponding to the transfer of one electron per SAW cycle. We interpret this as due to trapping of electrons in the moving SAW-induced potential minima with the number of electrons in each minimum being controlled by the electron - electron interactions. As the number of electrons is reduced, the classical Coulomb charging energy becomes the Mott - Hubbard gap between two electrons and finally the system becomes a sliding Mott insulator with one electron in each well.     

Is the stereomutation of methane possible?

Large basis set ab initio calculations at correlated levels, including MP2, single reference, as well as multireference configuration interaction, carried out on the methane potential energy surface, have located and characterized a transition structure for stereomutation (one imaginary frequency). This structure is best described as a pyramidal complex between singlet methylene and a side-on hydrogen molecule with C_s symmetry. At the single reference CI level, it lies 105 kcal/mol above the methane T_d-ground state but is stable relative to dissociation into CH₂(¹A₁) and H₂ by 13 kcal/mol at 0 K (with harmonic zero point energy (ZPE) corrections for all structures). Dissociation of the transition state into triplet methylene and hydrogen also is endothermic (by 4 kcal/mol), but single bond rupture to give CH and H^. is 3 kcal/mol exothermic. Thus, it does not appear likely that methane can undergo stereomutation classically beneath the dissociation limit. Confirming earlier conclusions, side-on insertion of ¹A₁ CH₂ into H₂ in a perpendicular geometry occurs without activation energy. Planar (D_4h) methane (130.5 kcal/mol) has four imaginary frequencies. Two of these are degenerate and lead to equivalent planar C_2v structures with one three-center, two-electron bond and two two-electron bonds and two imaginary frequencies. The remaining imaginary frequencies of the D_4h form lead to tetrahedral (T_d) and pyramidal (C_4v) methane. The latter has three negative eigenvalues in the force-constant matrix; one of these leads to the T_d global minimum and the other to the C_s (parallel) stereomutation transition structure. Multireference CI calculations with a large atomic natural orbitals basis set produce similar results, with the electronic energy of the C_s stereomutation transition state 0.7 ± 0.5 kcal/mol higher than that of CH + H^. dissociation products, and a ZPE-corrected energy which is 5 ± 1 kcal/mol higher. Also considered are photochemical pathways for stereomutation and the possible effects of nuclear spin, inversion tunneling, and the parity-violating weak nuclear interaction on the possibility of an experimental detection of stereomutation in methane. © 1995 by John Wiley & Sons, Inc.     

Stereoselective cycloadditions of chiral acyl-nitroso compounds; selective reactions of ring-cleaved cycloadducts leading to a new approach to polyoxamic acid

Diesters obtained from diacids produced by oxidative ring cleavage of cycloadducts derived from acyl-nitroso compounds and cyclic 1,3-dienes undergo highly regioselective hydrolysis on reaction with lithium hydroperoxide, which allows for easy differentiation of the carboxyl groups leading to a new approach to polyoxamic acid.     

End-group evidence of zwitterionic species in the anionic polymerization of cyanoacrylates by Lewis bases

X-ray fluorescence (XRF) spectra of poly(butyl cyanoacrylate) initiated, in tetrahydrofuran, by triphenylphospine and terminated by SO₃, show the persistent presence of phosphorus and sulfur in the polymer, in near-equivalent proportions, with the sulfur content partially removable by anion-exchange. It is concluded that all chains have initial phosphonium groups, and, in abesence of any hydrolysis-formed H₂SO₄, are macrozwitterions with terminal  SO₃⁻. Acid-terminated chains should have proton-capped ends and initial phosphonium⁺ · HSO₄⁻ ion-pairs.     

Enhanced responsivity of non-steady-state photoinduced electromotive force sensors using asymmetric interdigitated contacts

The responsivity at a constant detection area of non-steady-state photoinduced electromotive force (photo-emf) detectors is improved by a factor equal to the number of contact pairs contained in asymmetric interdigitated surface contacts. The polar nature of photo-emf current generation requires contact asymmetry in which one increases the total signal by blocking the illumination between alternate contact pairs, in distinct contrast to the behavior of conventional interdigitated contacts fabricated upon isotropic photoconductors.