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131.
T. Yu. Gumerov A. F. Dobrynina R. A. Yusupov V. P. Barabanov 《Russian Journal of Applied Chemistry》2006,79(12):1935-1939
The behavior of real disperse systems with organic impurities was examined under conditions of destabilization by inorganic coagulants. A number of physicochemical methods of analysis and a simulation method were used to identify the character and type of the complexes formed and to calculate their stability constants. 相似文献
132.
Baoqiang Li Dechang Jia Yu Zhou Qiaoling Hu Wei Cai 《Journal of magnetism and magnetic materials》2006
Chitosan/magnetite nanocomposite was synthesized induced by magnetic field via in situ hybridization in ambient condition. Results of XRD patterns and TEM micrographs indicated that magnetite particles with 10–20 nm were dispersed in chitosan homogeneously. An interesting result is that magnetite nanoparticles were assembled to form chain-like structures under the influence of the external magnetic field, which mimics the magnetite chains inside of magnetotatic bacteria. The saturated magnetization (Ms) of nano-magnetite in chitosan was 50.54 emu/g, which is as high as 54% of bulk magnetite. The remanence (Mr) and coercivity (Hc) were 4 emu/g and14.8 Oe, respectively, which indicated that magnetite nanoparticles were superparamagnetic. The key of route is that a pre-precipitated chitosan hydrogel membrane, used as chemical reactor, which controlled the precipitation of chitosan precipitation and in situ transformation of magnetite from the precursor simultaneously in the magnetic field environment. 相似文献
133.
孟昭英院士是著名物理学家、我国电子学开拓者,在清华大学物理系历史上是积极倡导“理工会通”教育思想的杰出大师,曾为我国培养了许多高级科技人才,有的成了我国某学科学术带头人,有的是佩戴上“两弹、一星”国家勋章的科学家.孟昭英先生一生辉煌、半生坎坷,但是即使在蒙受奇冤的年代,仍然以国家和民族大业为重,不懈努力.改革开放后,更是老骥伏枥,惮精竭虑地为清华大学物理系的重振作出了卓越贡献.值此孟昭英先生诞辰100周年之际,挥泪命笔写下此文。 相似文献
134.
Yu. D. Perfiliev V. S. Rusakov L. A. Kulikov A. A. Kamnev K. Alkhatib 《Hyperfine Interactions》2006,167(1-3):881-885
To explain line broadening in emission Mössbauer spectra as compared to the corresponding absorber measurements, the model of trapped electrons has been proposed. Auger electrons (emitted, e.g. after electron capture by 57Co or after the converted isomeric transition of 119mSn), as well as secondary electrons, may be trapped in the proximity to the nucleogenic ion. Electrons captured by lattice traps at different distances from the daughter ion induce an asymmetric distribution of quadrupole splitting in the resulting emission spectra, as shown in a few examples. This model is supported by estimates of quadrupole splitting values which may be caused by such trapped electrons located at specified distances from the nucleogenic atom. 相似文献
135.
Inverse diffusion problems allow the diffusion coefficients to be determined from experimental concentration profiles. Solutions
of the inverse diffusion problem are unstable toward perturbations of the initial concentration profiles. By the example of
inverse diffusion problem solution for a model binary system it is demonstrated that the use of the production entropy to
minimize the discrepancy functional stabilizes the solution even for significant perturbations of the initial concentration
profile. The choice of the entropy production for the smoothing component of the discrepancy functional is physically adequate
to the formulated problem, and the entropy production can be used to solve inverse problems of heat and mass transfer.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 79–83, June, 2006. 相似文献
136.
N.D. Tho N. Chau S.C. Yu H.B. Lee N.D. The L.A. Tuan 《Journal of magnetism and magnetic materials》2006
Effect of annealing on the soft magnetic properties of Fe73.5Si13.5B9Nb3Au1 amorphous ribbon has been investigated by means of structure examination, magnetoimpedance ratio (MIR) and incremental permeability ratio (PR) spectra measured in the frequency range of 1–10 MHz at a fixed current of 10 mA X-ray diffraction analysis showed that the as-cast sample was amorphous and it became nanocrystalline under a proper heat treatment. When annealing amorphous alloy at 530 °C for 30, 60, 90 min, soft magnetic properties have been improved drastically. Among the samples investigated, the sample annealed at 530 °C for 90 min showed the softest magnetic behavior. The MIR and PR curves revealed the desirable changes in anisotropy field depending upon annealing. 相似文献
137.
Mössbauer investigations about iron atom redistribution in oxide films of zirconium alloys subjected to corrosion at 500°C in pure oxygen and water pair have been analysed. The alloys were also subjected to autoclave conditions at a pressure of 10.0 MPa and autoclave conditions at 350°C and at a pressure of 16.8 MPa, using distilled water and water with additives of lithium and fluorine. It is shown that, depending on the corrosion environment, various compounds of iron, such as α-Fe2O3, Fe3O4, and FeO, as solid solutions of iron in ZrO2 are formed in oxide films. 相似文献
138.
The electrodynamic properties of coaxial two-dimensional Bragg resonators with two-dimensional distributed feedback are analyzed. These resonators are made of coaxial waveguide sections with doubly periodic corrugation, which provides coupling and mutual scattering of four partial waves. Two of them propagate along the waveguide, while the other two propagate in the transverse (azimuthal) direction. It is shown that the high azimuthal index selectivity of two-dimensional Bragg resonators may be related to a qualitative difference in topology of the dispersion characteristics of azimuth-symmetric and asymmetric normal waves propagating in infinite waveguides of such a geometry. For the finite-length systems used as two-dimensional Bragg resonators, the eigenmode spectrum is found for two types of boundary conditions that correspond to the limiting cases of perfectly matched (open) systems and, conversely, of systems closed for the extraction of transverse electromagnetic fluxes. Perimeter-to-length ratios of the resonator at which the Q factor of the fundamental azimuth-symmetric mode is greater than those of the other modes are determined. The applicability domain of the geometrical approach, which was earlier applied to two-dimensional Bragg resonators, is discussed. 相似文献
139.
Based on solving the couple mode equation numerically, the characterization of the signal power on the gate power was analyzed. And the relationship of the tolerance of the grating period and the bulk temperature on the interaction length was analyzed. 相似文献
140.
Zhong‐Zhen Yu Mingshu Yang Qingxin Zhang Chungui Zhao Yiu‐Wing Mai 《Journal of Polymer Science.Polymer Physics》2003,41(11):1234-1243
Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with an alkyl ammonium surfactant pretreated montmorillonite (MMT). The thermal stability of the organic MMT powders was measured by thermogravimetric analysis. The decomposition of the surfactant on the MMT occurred from 200 to 500 °C. The low onset decomposition temperature of the organic MMT is one shortcoming when it is used to prepare polymer nanocomposites at high melt‐compounding temperatures. To provide greater property enhancement and better thermal stability of the polymer/MMT nanocomposites, it is necessary to develop MMT modified with more thermally stable surfactants. The dispersion and spatial distribution of the organic MMT layers in the nylon‐66 matrix were characterized by X‐ray diffraction. The organic MMT layers were exfoliated but not randomly dispersed in the nylon‐66 matrix. A model was proposed to describe the spatial distribution of the organic MMT layers in an injection‐molded rectangular bar of nylon‐66/organic MMT nanocomposites. Most organic MMT layers were oriented in the injection‐molding direction. Layers near the four surfaces of the bar were parallel to their corresponding surfaces; whereas those in the bulk differed from the near‐surface layers and rotated themselves about the injection‐molding direction. The influence of the spatial distribution of the organic MMT on crystallization of nylon‐66 was also investigated. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1234–1243, 2003 相似文献