长循环寿命结晶@非结晶金属硫化物复合电极材料的制备及其混合电容器性能

通过乙二醇诱导策略成功地设计和构建了结晶@非结晶NiCo₂S₄@MoS₂(v-NCS@MS)纳米结构,利用非结晶MoS₂壳层的柔性保护和带缺陷的内部核 NiCo₂S₄的高比容量,使 v-NCS@MS电极具有高比容量(1 A·g^-1时 1 034 mAh·g^-1)和出色的倍率性能。此外,以v-NCS@MS为正极、活性炭(AC)为负极组装的混合超级电容器在219 W·kg^-1的比功率下可获得111 Wh·kg^-1的高比能量,在不同电流密度下循环15 000次后容量保持率高达80.5%。     

低分子量溴代聚苯乙烯的制备及应用

用溶液法合成了一系列低分子量的聚苯乙烯，其溴化产物（Ｂｒ－ＰＳ）的溴含量和热稳定性与美国同类产品Ｐｙｒｏ－Ｃｈｅｋ ＬＭ相当，分别用作聚苯乙烯树脂的阻燃剂，极限氧指数测定结果表明，其阻燃性也达到了Ｐｙｒｏ－Ｃｈｅｋ ＬＭ的水平。     

Multi-wavelength fiber ring laser based on a chirped moire fiber grating and a semiconductor optical amplifier

A simple and cost-effective multi-wavelength fiber ring laser based on a chirped Moire fiber grating （CMFG） and a semiconductor optical amplifier （SOA） is proposed. Stable triple-wavelength lasing oscillations at room temperature are experimentally demonstrated. The measured optical signal-to-noise ratio （SNR） reaches the highest value of 50 dB and the power fluctuation of each wavelength is less than 0.2 dB within a 1-h period. To serve as a wavelength selective element, the CMFG possesses excellent comb-like filtering characteristics including stable wavelength interval and ultra-narrow passband, and its fabrication method is easy and flexible. The lasing oscillation shows a narrower bandwidth than SOA-based multi-wavelength fiber lasers utilizing some other kinds of wavelength selective components. Methods to optimize the laser performance are also discussed.     

SiO2交联剂交联MMA聚合制备PMMA/SiO2纳米复合材料

用SiO2交联剂(SiO2HPA)交联甲基丙烯酸甲酯(MMA)自由基聚合制备PMMA SiO2纳米复合材料。采用两步法将可聚合乙烯基单体以化学键的形式键接到SiO2表面合成SiO2交联剂,首先利用过量的甲苯2,4二异氰酸酯(TDI)对SiO2纳米粒子表面进行化学修饰合成出表面带有高反应活性NCO基团的功能化SiO2粒子(SiO2TDI),SiO2TDI与丙烯酸羟丙酯(HPA)反应合成SiO2交联剂。系统研究了MMA单体与SiO2交联剂投料比及聚合时间对聚合反应的影响。此外,利用红外光谱(FT IR)、DSC、TGA、可见光光谱仪等实验手段对纳米复合材料进行了表征分析。结果表明,纳米SiO2粒子在复合材料中起着物理交联点和化学交联点作用,复合材料玻璃化转变温度(Tg)明显地高于其纯PMMA的玻璃化转变温度,随着纳米SiO2粒子含量的增加,复合材料玻璃化温度升高,而透明度明显降低。     

稀土壳聚糖杂化材料的制备、表征及抑菌活性研究

在室温条件下,以天然高分子材料壳聚糖和稀土纳米氧化物为原料,用表面接枝法制备了两种RE2O3-TDI-壳聚糖(TDI=甲苯-2,4-二异氰酸酯,RE=镧,钕)杂化复合物,借助红外(IR)、热重(DSC-TG)、扫描电镜(SEM)等测试技术对所制备的壳聚糖杂化材料的物化性能进行了表征,并采用培养基扩散法和营养肉汤稀释法等抑菌实验方法对其进行了抑菌活性实验,结果表明该稀土纳米壳聚糖杂化材料具有很好的热稳定性及抑菌性能。     

Facile and Rapid Synthesis of 9H-Carbazole-9-Carboxylic Acids Under Microwave Irradiation

The reaction of halogenated 9H-carbazoles or carbazole with bromoesters in DMF under microwave irradiation readily affords a series of 9H-carbazoles-9-hydroxylic acids.     

金催化炔基膦酸酯水合反应合成β-羰基膦酸酯

β-羰基膦酸酯是一类重要的有机化合物和反应中间体,在有机合成及药物化学中发挥着重要的作用.提供了一种高原子经济性、高选择性、温和的炔基膦酸酯水合反应体系.实验结果表明:在阳离子金催化剂(2.5 mol%)的催化作用下,以1,2-二氯乙烷(1 m L)为溶剂,室温下炔基膦酸酯(1 mmol)与水(3 mmol)发生水合反应,高收率、高区域选择性地得到β-羰基膦酸酯化合物(收率≥92%).该方法具有底物适用范围广、反应条件温和、环境友好等优点,为含β-羰基膦酸酯结构单元的天然产物及复杂药物分子的合成提供了一种新途径.     

A numerical and experimental hybrid approach for the investigation of aerodynamic forces on stay cables suffering from rain-wind induced vibration

The aerodynamic forces on a stay cable under a rain-wind induced vibration (RWIV) are difficult to measure directly in a wind tunnel test. This paper presents a hybrid approach that combines an experiment with computational fluid dynamics (CFD) for the investigation on aerodynamic forces of a stay cable under a RWIV. The stay cable and flow field were considered as two substructures of the system. The oscillation of the stay cable was first measured by using a wind tunnel test of a RWIV under an artificial rainfall condition. The oscillation of the cable was treated as a previously known moving boundary condition and applied to the flow field. Only the flow field with the known moving cable boundary was then numerically simulated by using a CFD method (such as Fluent 6.3). The transient aerodynamic forces of the stay cable with a predetermined cable oscillation were obtained from numerical calculations. The characteristics of the aerodynamic forces in the time domain and frequency domain were then analysed for various cases. To verify the feasibility and accuracy of the proposed hybrid approach, the transient aerodynamic forces were applied to a single-degree-of-freedom model (SDOF) of the stay cable to calculate the RWIV of the cable. A comparison was performed between the oscillation responses of the stay cable obtained from the calculated (SDOF model) and experimental results, and the results indicate that the hybrid approach accurately simulates the transient aerodynamic forces of the stay cable. The equivalent damping ratios induced by the aerodynamic forces were obtained for various wind speeds. Furthermore, a nonlinear model of the aerodynamic force is proposed based on the calculation results, and the coefficients in the model were identified by a nonlinear least-squares technique.