全文获取类型
收费全文 | 306篇 |
免费 | 6篇 |
国内免费 | 2篇 |
专业分类
化学 | 209篇 |
晶体学 | 6篇 |
力学 | 6篇 |
数学 | 50篇 |
物理学 | 43篇 |
出版年
2023年 | 1篇 |
2022年 | 13篇 |
2021年 | 11篇 |
2020年 | 14篇 |
2019年 | 17篇 |
2018年 | 5篇 |
2017年 | 7篇 |
2016年 | 11篇 |
2015年 | 15篇 |
2014年 | 17篇 |
2013年 | 35篇 |
2012年 | 17篇 |
2011年 | 20篇 |
2010年 | 26篇 |
2009年 | 16篇 |
2008年 | 24篇 |
2007年 | 16篇 |
2006年 | 10篇 |
2005年 | 11篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 4篇 |
2001年 | 1篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1993年 | 1篇 |
排序方式: 共有314条查询结果,搜索用时 15 毫秒
81.
A simple and concise mathematical model describing the deformation and the electrical behavior of a bi-morph piezoelectric curved sensor subjected to pure bending is developed. In particular, the influence of the couple moment on the electrical potential generated in the sensor is investigated and the results are presented in graphical form. (© 2014 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
82.
Nevin Arslan 《Phosphorus, sulfur, and silicon and the related elements》2020,195(8):628-637
AbstractThe interaction of [Ru(η6-arene)(μ-Cl)Cl]2 and Ir(η5-C5Me5)(μ-Cl)Cl]2 with a new Ionic Liquid-based phosphinite ligand, [(Ph2PO)-C6H9N2Ph]Cl, (2) gave [Ru((Ph2PO)-C6H9N2Ph)(η6-p-cymene)Cl2]Cl (3), [Ru((Ph2PO)-C6H9N2Ph)(benzene)Cl2]Cl (4) and [Ir((Ph2PO)-C6H9N2Ph)(C5Me5)Cl2]Cl (5), complexes. All the compounds were characterized by a combination of multinuclear NMR and IR spectroscopy as well as elemental analysis. Furthermore, the Ru(II) and Ir(III) catalysts were applied to asymmetric transfer hydrogenation of acetophenone derivatives using 2-propanol as a hydrogen source. The results showed that the corresponding alcohols could be obtained with good activity (up to 55% ee and 99% conversion) under mild conditions. Notably, [Ir((Ph2PO)-C6H9N2Ph)(C5Me5)Cl2]Cl (5) is more active than the other analogous complexes in the transfer hydrogenation (up to 81% ee). 相似文献
83.
Fatma Arslan Martin Behrendt Werner Ernst Eberhard Finckh Gunther Greb Friedrich Gumbmann Martin Haller Stefan Hofmann Ralf Karschnick Matthias Klein Wolfgang Kretschmer Jochen Mackiol Gerhard Morgenroth Christian Pagels Markus Schleicher 《Angewandte Chemie (International ed. in English)》1995,34(2):183-186
84.
The object of the present paper is to study a type of Riemannian manifolds called generalized recurrent manifolds. We have constructed two concrete examples of such a manifold whose scalar curvature is non-zero non-constant. Some other properties have been considered. Among others it is shown that on a generalized recurrent manifold with constant scalar curvature, Weyl-semisymmetry and semisymmetry are equivalent. Sufficient condition for a generalized recurrent manifold to be a special quasi Einstein manifold is obtained. 相似文献
85.
Selective addition of H2O to fullerene C60 catalyzed by Cp2MCl2 (M = Ti, Zr, Hf) catalysts to yield 1-hydroxy-1,2-dihydrofullerene has been realized for the first time. 相似文献
86.
87.
Ali İhsan Öztürk Fatih Aslan Ökkeş Yılmaz Mehmet Alğın Mustafa Arslan H. İbrahim Mutlu 《Phosphorus, sulfur, and silicon and the related elements》2013,188(5):585-595
Abstract Hexa(4-bromo-2-formyl-phenoxy)cyclotriphosphazene (2) and hexa(4-chloro-2- formyl-phenoxy)cyclotriphosphazene (3) were obtained from the reactions of hexachloro- cyclotriphosphazene (1) with 5-bromosalicylaldehyde and 5-chlorosalicylaldehyde in the presence of (C2H5)3N and K2CO3 at room temperature, respectively. The new two organocyclotriphosphazenes bearing formyl groups were reacted with 4-cyano aniline, 2-phenyl aniline, 4-aceto aniline, 5-chloro-2-hydroxy aniline, 2-hydroxy aniline, 4-hydroxy aniline, 2-(4-morpholino)ethyl amine, 4-carboxy aniline, 4-carbomoyl aniline, 2-mercapto aniline, and 5-amino isoquonoline to prepare cyclotriphosphazene derivatives containing a Schiff base at room temperature. However, fully phenoxy-substituted cyclotriphosphazenes containing a Schiff base were isolated from the reactions of the compound 2 and 3 with 5-chloro-2-hydroxy aniline, 2-hydroxy aniline, 4-hydroxy aniline, and 2-(4-morpholino)ethyl amine. The structures of the synthesized compounds were characterized by elemental analysis, IR, and NMR (1H, 13C, 31P) spectroscopy. According to the results of the analysis, all synthesized compounds were found to be fully substituted organocyclotriphosphazenes, such as hexa[4-bromo-2-(5-chloro-2-hydroxy-pheyliminomethyl)phenoxy]cyclotriphosphaze (2a). All cyclotriphosphazene derivatives synthesized gave fluorescence emission peaks in range between 300 nm and 410 nm. 相似文献
88.
Demet Sezgin Mansuroğlu Hakan Arslan Don VanDerveer Gün Binzet 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):3221-3230
A series of new N-(2,2-diphenylacetyl)-N ′-substituted thiourea derivatives (1–9) have been prepared and characterized by elemental analyses, IR and 1H NMR spectroscopy. N-(2,2-diphenylacetyl)-N ′-(4-chlorophenyl)-thiourea was also characterized by a single crystal X-ray diffraction study. The compound crystallizes in the monoclinic space group P21/c with Z = 4 and a = 9.6551(19) Å, b = 20.060(4) Å, c = 9.894(2) Å, β = 104.29(3)°. The molecular conformation of the compound is stabilized by an intramolecular (N1-H1···O1) hydrogen bond that forms a pseudo-six-membered ring. 相似文献
89.
Mahmut Erzengin Dudu Demir Mikail Arslan Selma Sinan 《Applied biochemistry and biotechnology》2014,173(7):1597-1606
Paraoxonase 1 (PON1: EC 3.1.8.1) is a calcium-dependent enzyme associated with high-density lipoproteins (HDLs) and has a protective effect against oxidation of low-density lipoproteins (LDLs) in mammals. PON1 is the best-studied member of a family of enzymes called serum paraoxonases, or PONs, identified in mammals and other vertebrates as well as in invertebrates. PONs exhibit a range of important activities, including drug metabolism and detoxification of organophosphates such as nerve agents. This study reports, for the first time, purification and biochemical characterization of serum PON1 from different bovine breeds namely Swiss Black, Holstein, and Montofon. Bovine serum PON1s were purified using ammonium sulfate precipitation followed by Sepharose-4B-l-tyrosine-1-naphthylamine hydrophobic interaction chromatography. SDS–polyacrylamide gel electrophoresis of the purified enzymes indicates a single band with an apparent MW of 43 kDa. The purified enzymes had a specific activity of 10.78, 27.00, and 22.38 U/mg for Swiss Black, Holstein, and Montofon bovines, respectively. The overall purification rates of our method were 262.47-, 2,476.90-, and 538.06-fold for Swiss Black, Holstein, and Montofon bovines, respectively. Furthermore, using phenyl acetate as a substrate, we determined the K M and V max values of the purified enzymes, as 0.80 mM, 1428.5 U/ml for Swiss Black; 0.40 mM, 714.3 U/ml for Holstein; and 0.50 mM, 1,111.1 U/ml for Montofon bovine. The present study has revealed that there is no substantial difference in PON1 activities among the studied bovine breeds. 相似文献
90.
Arslan HK Shekhah O Wieland DC Paulus M Sternemann C Schroer MA Tiemeyer S Tolan M Fischer RA Wöll C 《Journal of the American Chemical Society》2011,133(21):8158-8161
We report the synthesis of layered [Zn(2)(bdc)(2)(H(2)O)(2)] and [Cu(2)(bdc)(2)(H(2)O)(2)] (bdc = benzdicarboxylate) metal-organic frameworks (MOF) carried out using the liquid-phase epitaxy approach employing self-assembled monolayer (SAM) modified Au-substrates. We obtain Cu and Zn MOF-2 structures, which have not yet been obtained using conventional, solvothermal synthesis methods. The 2D Cu(2+) dimer paddle wheel planes characteristic for the MOF are found to be strictly planar, with the planes oriented perpendicular to the substrate. Intercalation of an organic dye, DXP, leads to a reversible tilting of the planes, demonstrating the huge potential of these surface-anchored MOFs for the intercalation of large, planar molecules. 相似文献