三种氨基酸荧光光谱的量子化学研究

氨基酸荧光光谱的量子化学计算为氨基酸荧光分析方法的设计与选择提供了一定的理论依据。本文采用量子化学半经验方法AM1对三种氨基酸的荧光光谱进行了理论研究。对三种化合物的结构进行优化后 ,从其结构参数可知分子具有刚性平面结构 ,具有大的离域π键。并对优化后的构型作振动分析 ,均未出现虚频率 ,证明该结构是稳定构型。在此基础上 ,采用单激发态组态相互作用 (CIS)方法计算其荧光激发波长及强度 ,并给出了三种化合物荧光光谱的波长与CIS组态数之间的关系。所得计算结果与实验值基本吻合。     

基于垂直谐振腔结构的半导体光放大器理论分析

由新型垂直腔半导体光放大器（VCSOAs）器件结构出发,在反射模式和透射模式两种 情况下,计算了VCSOAs的分布布拉格反射堆（DBR）反射率、单程增益与增益、带宽的关系 ,其中DBR反射率的增大伴随着增益的上升,但也伴随着带宽的减小.通过引入增益-带宽 积的概念,以均衡增益与带宽.计算中表明:10 dB以上增益,50 GHz以上带宽可以实现. 计算结果与文献实验相吻合,对优化VCSOAs的结构设计和性能有所裨益.     

Non-invasive monitoring of living cell culture by lensless digital holography imaging

A non-invasive detection method for the status analysis of cell culture is presented based on digital holography technology.Lensless Fourier transform digital holography (LFTDH) configuration is developed for living cell imaging without prestaining.Complex amplitude information is reconstructed by a single inverse fast Fourier transform,and the phase aberration is corrected through the two-step phase subtraction method.The image segmentation is then applied to the automatic evaluation of confiuency.Finally,...     

Compact and high-power broadband terahertz source based on femtosecond photonic crystal fiber amplifier

We present a review of the development of a compact and high-power broadband terahertz (THz) source optically excited by a femtosecond photonic crystal fiber (PCF) amplifier.The large mode area of the PCF and the stretcher-free configuration make the pump source compact and very efficient.Broadband THz pulses of 150 μW extending from 0.1 to 3.5 THz are generated from a 3-mm-thick GaP crystal through optical rectification of 12-W pump pulses with duration of 66 fs and a repetition rate of 52 MHz.A strong saturation effect is observed,which is attributed to pump pulse absorption;a Z-scan measurement shows that three-photon absorption dominates the nonlinear absorption when the crystal is pumped by femtosecond pulses at 1 040 nm.A further scale-up of the THz source power is expected to find important applications in THz nonlinear optics and nonlinear THz spectroscopy.     

苯酚磺酞类酸性染料与人血清白蛋白的结合

在人体条件下 ,用荧光光谱法研究了苯酚磺酞类酸性染料苯酚红、甲酚红、氯酚红、溴甲酚紫、间甲酚紫与人血清白蛋白 (HSA)之间的相互作用。实验表明 :苯酚磺酞类酸性染料对人血清白蛋白的荧光有较强的猝灭作用 ,其荧光猝灭主要为静态猝灭 ,从荧光猝灭结果求得不同温度下各染料与HSA的结合常数K ,发现染料取代基的引入使K值增大 ,且随反应温度上升K值下降。由染料与HSA反应焓变、熵变 ,确定染料与HSA的结合主要是静电引力。依据非辐射能量转移机理 ,探讨了不同温度下该类染料与HSA相互结合时 ,其给体 受体间距离和能量转移效率。进一步证实了该类反应为单一静态猝灭过程 ,且阐明了其猝灭机理是通过能量转移产生的。     

Synthesis,Characterization and Biological Activities of Novel Acrylamide Compounds

With dimethomorph and flumorph as the leading compounds, four novel acrylamide compounds with two types of structure were designed and synthesized by means of the method of ＂me too chemistry＂. The target compounds were characterized by 1H NMR, IR, MS, and elemental analysis. The influences of solvent and raw material on the yield were investigated and optimum processing conditions were determined. The results of preliminary biological tests show that all those compounds exhibit certain antifungal activities.     

Catalytic performances of Ni/mesoporous SiO2 catalysts for dry reforming of methane to hydrogen

Several mesoporous silicas with different morphologies were controllably prepared by sol-gel method with adjustable ratio of dual template,and they were further impregnated with aqueous solution of nickel nitrate,followed by calcination in air.The synthesized silica supports and supported nickel samples were characterized using N₂-adsorption/desorption,X-ray diffraction（XRD）,H₂ temperature-programmed reduction（H₂-TPR）,Scanning electron microscope（SEM）,Transmission electron microscope（TEM） and thermo-gravimetric analysis（TGA-DTG） techniques.The Ni nanoparticles supported on shell-like silica are highly dispersed and yielded much narrower nickel particle-size than those on other mesoporous silica.The methane reforming with dioxide carbon reaction results showed that Ni nanoparticles supported on shell-like silica carrier exhibited the better catalytic performance and catalytic stability than those of nickel catalyst supported on other silica carrier.The thermo-gravimetric analysis on used nickel catalysts uncovered that catalyst deactivation depends on the type and nature of the coke deposited.The heterogeneous nature of the deposited coke was observed on nickel nanoparticles supported on spherical and peanut-like silica.Much narrower and lower TGA derivative peak was founded on Ni catalyst supported on the shell-like silica.     

THE DYNAMICS OF FERTILITY IN C-K MODEL WITH ENDOGENOUS FERTILITY

lhtroduCtlonThe relatloDshlp bet W6W6en the economic gr OWOWth and population growth Is the one of mostimportant problems In the economic growth theorem．In the empirical analyses,the level offertility and the level ofincomeper caplta Is one of*the strongest observably negative correl砒ions,In cross－country dataIS]．Constructing a mathematical model to confirm the empirical indingsIs a m叼or method In thetheoretical study、BeckerI6];GalorI7]and TaTamuraW use OLG modelto discuss this…     

流动注射氢化物发生-原子荧光光谱法测定土壤中有效态As(Ⅲ)和As(Ⅴ)

提出了一种流动注射氢化物发生 原子荧光光谱法测定土壤中有效态As(Ⅲ )和As(Ⅴ )的方法。在0 1mol·L-1柠檬酸介质 (pH =3 1)中选择性测定As(Ⅲ ) ,然后用L 半胱氨酸流动注射在线还原As(Ⅴ )后测定总砷 ,由二者之差求得As(Ⅴ )。设计了在线还原及氢化物发生流路和操作程序 ,选择了各项化学条件和流路参数。As(Ⅲ )和As(Ⅴ )的检出限 (3σ)分别为 0 11和 0 0 7ng·mL-1。对于 10ng·mL-1As(Ⅲ )溶液 ,连续7次测定得精密度 (RSD)为 1 43% ,应用于实际土壤样品的测定 ,加标回收率在 82 %～ 10 4%之间     

迁移算子离散本征值及其聚点的分布

讨论了各向异性、能量相关、非均匀有界凸体介质中迁移算子的谱,在省略某些不符合实际的 特殊条件的情况下,对这类算子离散本征值及其聚点的位置分布,同样获得了一个类似的结果.