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Xuanyu Zhang Dr. Rui You Zeyue Wei Dr. Xiao Jiang Dr. Jiuzhong Yang Prof. Yang Pan Dr. Peiwen Wu Qingdong Jia Dr. Zhenghong Bao Dr. Lei Bai Prof. Mingzhou Jin Dr. Bobby Sumpter Dr. Victor Fung Prof. Weixin Huang Dr. Zili Wu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(21):8045-8045
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Tianwei Xue Prof. Li Peng Olga A. Syzgantseva Maria A. Syzgantseva Peiwen Guo Huiyan Lai Ruiqing Li Jiawen Chen Shumu Li Prof. Xiaomei Yan Prof. Shuliang Yang Prof. Jun Li Prof. Buxing Han Prof. Wendy L. Queen 《Angewandte Chemie (International ed. in English)》2023,62(44):e202309737
Every year vast quantities of silver are lost in various waste streams; this, combined with its limited, diminishing supply and rising demand, makes silver recovery of increasing importance. Thus, herein, we report a controllable, green process to produce a host of highly porous metal–organic framework (MOF)/oligomer composites using supercritical carbon dioxide (ScCO2) as a medium. One resulting composite, referred to as MIL-127/Poly-o-phenylenediamine (PoPD), has an excellent Ag+ adsorption capacity, removal efficiency (>99 %) and provides rapid Ag+ extraction in as little as 5 min from complex liquid matrices. Notably, the composite can also reduce sliver concentrations below the levels (<0.1 ppm) established by the United States Environmental Protection Agency. Using theoretical simulations, we find that there are spatially ordered polymeric units inside the MOF that promote the complexation of Ag+ over other common competing ions. Moreover, the oligomer is able to reduce silver to its metallic state, also providing antibacterial properties. 相似文献
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通过Tyndal效应,电镜观察,电导率测定,结合聚合实验,发现铁体系催化剂在加氢汽油介质中为胶体催化剂,而且是聚结不稳定胶体体系.催化剂各组分配比,加入顺序影响胶粒的形态,因而影响到催化活性与聚合物微观结构.其中较佳配比,较佳加入顺序(Fe)∶(Cl)∶(Al)=1∶2.5∶20,催化剂颗粒比较小,均匀,因而比表面积大,催化活性高,相反其他配比的颗粒大,不均匀,催化活性低.陈化使胶粒聚集变大,故催化活性降低. 相似文献
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Controllable Fabrication of Tungsten Oxide Nanoparticles Confined in Graphene‐Analogous Boron Nitride as an Efficient Desulfurization Catalyst 下载免费PDF全文
Peiwen Wu Dr. Wenshuai Zhu Aimin Wei Bilian Dai Dr. Yanhong Chao Prof. Changfeng Li Prof. Huaming Li Prof. Sheng Dai 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(43):15421-15427
Tungsten oxide nanoparticles (WOxNPs) are gaining increasing attention, but low stabiliity and poor dispersion of WOxNPs hinder their catalytic applications. Herein, WOxNPs were confined in graphene‐analogous boron nitride (g‐BN) by a one‐step, in situ method at high temperature, which can enhance the interactions between WOxNPs and the support and control the sizes of WOxNPs in a range of about 4–5 nm. The as‐prepared catalysts were applied in catalytic oxidation of aromatic sulfur compounds in which they showed high catalytic activity. A balance between the W loading and the size distribution of the WOxNPs could govern the catalytic activity. Furthermore, a synergistic effect between g‐BN and WOxNPs also contributed to high catalytic activity. The reaction mechanism is discussed in detail and the catalytic scope was enlarged. 相似文献
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Peiwen Ye Jingya Lu Meichang Li Hongwei Zhang Yuyao Chen Fenghuan Wei 《Biomedical chromatography : BMC》2020,34(6):e4817
Folium Camelliae Nitidissimae (jinhuacha in Chinese, JHC) is a kind of caffeine-less tea with antioxidant, antitumor and antibacterial effects. Studies on the chemical profiles and hepatoprotective effects of JHC extracts have not been systematically conducted so far. This study comprehensively investigated the compound profiles of JHC extract by ultrafast liquid chromatography with quadrupole time-of-flight tandem mass spectrometry. We also determined JHC's hepatoprotective effects against CCl4-induced liver injury in mice. A JHC extract was administered orally to mice at 1.95 and 7.80 g/kg body weight once daily for 14 consecutive days prior to CCl4 treatment. Eighty-four compounds including flavonoids, organic acids, catechins, coumarins, phenylpropanol, amino acids, anthraquinones, saponins and nucleosides in JHC extract were authentically identified or tentatively identified by comparing MS information and retention times with those of authentic standards or available references. JHC administration significantly decreased elevated levels of aspartate aminotransferase and alanine aminotransferase in mouse serum, inhibited hepatic malondialdehyde formation and enhanced glutathione and superoxide dismutase activities in the liver of CCl4-treated mice. The histological observations also further supported the results. These results demonstrate that JHC contains various chemical compounds and its hepatoprotective effects against CCl4-induced liver injury correlated with decreasing lipid oxidation are significant. 相似文献
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Zheng P Jiang X Zhang X Zhang W Shi L 《Langmuir : the ACS journal of surfaces and colloids》2006,22(22):9393-9396
Template synthesis of various morphological gold colloidal nanoparticles using a thermoresponsive and pH-responsive coordination triblock copolymer of poly(ethylene glycol)-b-poly(4-vinylpyridine)-b-poly(N-isopropylacrylamide) is studied. The template morphology of the thermoresponsive and pH-responsive coordination triblock copolymer, which can be tuned by simply changing the pH or temperature of the triblock copolymer aqueous solution, ranges from single chains to core-corona micelles and further to micellar clusters. Various morphological gold colloidal nanoparticles such as discrete gold nanoparticles, gold@polymer core-shell nanoparticles, and gold nanoparticle clusters are synthesized on the corresponding template of the triblock copolymer by first coordination with gold ions and then reduction by NaBH4. All three resultant gold colloidal nanoparticles are stable in aqueous solution, and their sizes are 2, 10, and 7 nm, respectively. The gold@polymer core-shell nanoparticles are thermoresponsive. The gold nanoparticle cluster has a novel structure, and each one holds about 40 single gold nanoparticles. 相似文献
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Peiwen Zhou James D. Fisher Richard J. Staples Ashwani Vij Nicholas R. Natale 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):1146-1147
The title compound, C14H21NO5, possesses an isoxazolyl group in the axial position of the 1,3‐dioxanyl ring. The two rings are rotated about the bond joining them such that the two C(methyl)—C(dioxanyl)—C—C torsion angles are 92.1 (2) and ?84.1 (2)°. In this conformation, neither the methyl nor ethoxycarbonyl substituents on the isoxazole are presented towards the dioxanyl chair. 相似文献
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