Morphology controllable conjugated network polymers based on AIE-active building block for TNP detection

Luminescent conjugated network polymer is one of the most promising chemo-sensors owing to their good chemical/optical stability and multiple functionalization.Herein,three conjugated network polymers were prepared by using aggregation-induced emission active 1,1,2,2-tetrakis(4-formyl-(1,1'-biphenyl))-ethane(TFBE) unit as monomer and hydrazine as linker.Through regulating the synthetical condition,the polyme ric network can form either unifo rm two-dimensional azine-linked nanosheets(ANS),conjugated microporous polymers(A-CMP) or covalent organic frameworks(A-COF).All of these polymers exhibited good stability and high fluorescence quantum efficiency with the quantum yield of6.31% for A-NS,5.26% for A-CMP,and 5.80% for A-COF,as well as fast and selective fluorescence quenching response to 2,4,6-trinitrophenol(TNP).And the best TNP sensing performance with the Stern-Volmer constants(K_(sv)) values up to 8 × 10~5 L/mol and a detection limit of 0.09 μmol/L was obtained for A-NS.The study explores various strategies to construct conjugated polymers with different nanoarchitectures based on the same building block for sensitive detection of explosives.     

Ag@硅氧倍半聚合物的合成及其对对硝基苯酚的催化还原性能

以氨丙基三乙氧基硅烷和草酰氯为原料,合成得到链上含亚氨基和羰基官能团的硅氧倍半聚合物。以此聚合物为载体,通过配位吸附和还原得到银纳米粒子（平均粒径约为15 nm）高度分散于硅氧烷聚合物表面的复合物。研究结果表明,复合物中银负载量（质量分数）约为13.66%,在水溶液中25℃、6 min内可将对硝基苯酚（4-NP）完全催化还原为对氨基苯酚（4-AP）,且7次循环使用后依然保持95%以上的催化活性。在常温常压条件下,催化剂的最高活性达到33.0 g_4-AP·g_Ag^-1,表现出优异的催化还原性能。     

Access to multi-functionalized oxazolines via silver-catalyzed heteroannulation of enamides with sulfoxonium ylides

Disclosed herein is an efficient Ag-catalyzed 4+1 heteroannulation reaction of enamides with α-carbonyl sulfoxonium ylides.The diastereoselective transformation provides a practical access to a diverse range of multi-functionalized oxazoline derivatives.The synthetic utility of the resultant tetrasubstituted oxazolines is further demonstrated by a series of useful manipulations into valuable building blocks of pharmaceutical relevance.     

Upgrade of beamline BL08B at Taiwan Light Source from a photon‐BPM to a double‐grating SGM beamline

During the last 20 years, beamline BL08B has been upgraded step by step from a photon beam‐position monitor (BPM) to a testing beamline and a single‐grating beamline that enables experiments to record X‐ray photo‐emission spectra (XPS) and X‐ray absorption spectra (XAS) for research in solar physics, organic semiconductor materials and spinel oxides, with soft X‐ray photon energies in the range 300–1000 eV. Demands for photon energy to extend to the extreme ultraviolet region for applications in nano‐fabrication and topological thin films are increasing. The basic spherical‐grating monochromator beamline was again upgraded by adding a second grating that delivers photons of energy from 80 to 420 eV. Four end‐stations were designed for experiments with XPS, XAS, interstellar photoprocess systems (IPS) and extreme‐ultraviolet lithography (EUVL) in the scheduled beam time. The data from these experiments show a large count rate in core levels probed and excellent statistics on background normalization in the L‐edge adsorption spectrum.     

基于云环境的分布式软件接口自动化测试

软件测试是保证软件质量,提供可靠服务的重要技术手段。目前基于Web Service的分布式软件越来越多,其测试技术手段也越来越受到关注。Web Service的分布性和多样性使手工测试变得非常低效,因而需要不断提高Web Service测试的自动化程度。另外,云计算因其计算成本低、可伸缩性强的特点为自动化测试提供了新的支持环境。本文结合Web Service的测试需求,首次提出了基于云环境的Web Service接口自动化测试的技术框架,分析了框架内原子Web Service、组合Web Service测试的关键技术,并研发了基于CloudStack云平台的自动化测试的原型系统。实验结果表明,本文所提出的基于云平台的WebService自动化测试方案可行且提高了测试效率。     

生物矿化法制备HgS/聚氨酯复合薄膜及其对Ba2+的传感性能

通过生物矿化法制备出HgS/聚氨酯纳米复合材料并用FTIR、SEM等对材料进行了表征. 研究发现聚氨酯分子可以控制HgS的成核和晶体生长. 聚氨酯的量子限域效应已通过紫外-可见光谱证实,在约291 nm处有明显的特征吸收峰. 荧光性能研究结果表明HgS/聚氨酯纳米粒子复合薄膜对Ba²⁺的存在十分敏感,少量的Ba²⁺会使荧光强度明显上升,水中常见离子几乎对此没有影响.     

定轴转动中打击中心位置分析

刚体定轴转动的打击中心是一个很重要的力学概念,但在很多《大学物理》教材中都没有介绍.本文以一根质量均匀分布的细杆绕端点作定轴转动为例,首先从动力学的角度,分析刚体的受力和力矩,根据动力学方程,分别计算出打击中心位置;然后从运动学角度出发,以转轴O点的切向速度和切向加速度等于零为条件,再分别寻找打击中心的位置.计算结果表明:上述4种方法得出的刚体打击中心位置是相同的.最后简介刚体打击中心在体育运动、日常生活中一些应用.     

Preparation of yolk-shell sulfur/carbon nanocomposite via an organic solvent route for lithium–sulfur batteries

A yolk-shell sulfur/carbon (S/C) composite for the cathode of lithium–sulfur batteries was successfully prepared by an accessible method with tetrahydrofuran as solvent. The as-prepared composites are characterized by thermal gravimetric, X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption and desorption. In this composite, sulfur particle is encapsulated in the carbon shell even entering into the micropores of carbon Bp2000. The electrochemical performance of the S/C composites is evaluated. The results indicate that the S/C composite with 50 wt% sulfur content shows good reversibility, excellent rate capability, and slow degradation. It delivers an initial capacity of 784.4 mAh g^?1 (based on sulfur weight) and preserves at 598.3 mAh g^?1 after 195 cycles at 1C. It achieves a high-capacity retention of 76.27 % from the 5th to 200th cycle, and as high as 91.19 % during the latter 150 cycles. The improvement is mainly attributed to the favorable structure of the S/C composite, in which the carbon cannot only facilitate transport of electrons and Li⁺ ions but also trap polysulfides and retard the shuttle effect during charge/discharge process.     

Study on the performance of LiMn2O4 using spent Zn–Mn batteries as manganese source

Recycling spent Zn–Mn batteries by synthesizing the products with high added value is very active internationally. In this work, we have successfully synthesized the spinel LiMn₂O₄ cathode materials for rechargeable lithium-ion batteries by simple sol–gel method using the manganese source that is recovered from spent Zn–Mn batteries through hydrometallurgy recycling technology. The influence of sintering temperature on the structure, the morphological properties, and the electrochemical properties of the product is investigated. The results show that spinel LiMn₂O₄ prepared at 700 °C has the best comprehensive performance. Moreover, the electrochemical performance of spinel LiMn₂O₄ has been further optimized by Co-ion doping.