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Alinezhad Heshmatollah Vafaeezadeh Majid Mahmoodi Hashemi Mohammad 《Research on Chemical Intermediates》2017,43(4):2615-2625
Research on Chemical Intermediates - A metal-free method for activation of hydrogen peroxide (H2O2) is introduced using piperidinium trifluoroacetate (PPHTFA) ionic liquid as catalyst. The catalyst... 相似文献
114.
Jorge Gimenez‐Lopez Christian Tihic Rasmussen Hamid Hashemi Maria U. Alzueta Yide Gao Paul Marshall C. Franklin Goldsmith Peter Glarborg 《国际化学动力学杂志》2016,48(11):724-738
A detailed chemical kinetic model for oxidation of acetylene at intermediate temperatures and high pressure has been developed and evaluated experimentally. The rate coefficients for the reactions of C2H2 with HO2 and O2 were investigated, based on the recent analysis of the potential energy diagram for C2H3 + O2 by Goldsmith et al. and on new ab initio calculations, respectively. The C2H2 + HO2 reaction involves nine pressure‐ and temperature‐dependent product channels, with formation of triplet CHCHO being dominant under most conditions. The barrier to reaction for C2H2 + O2 was found to be more than 50 kcal mol?1 and predictions of the initiation temperature were not sensitive to this reaction. Experiments were conducted with C2H2/O2 mixtures highly diluted in N2 in a high‐pressure flow reactor at 600–900 K and 60 bar, varying the reaction stoichiometry from very lean to fuel‐rich conditions. Model predictions were generally in satisfactory agreement with the experimental data. Under the investigated conditions, the oxidation pathways for C2H2 are more complex than those prevailing at higher temperatures and lower pressures. Acetylene is mostly consumed by recombination with H to form vinyl (reducing conditions) or with OH to form a CHCHOH adduct (stoichiometric to lean conditions). Both C2H3 and CHCHOH then react primarily with O2. The CHCHOH + O2 reaction leads to formation of significant amounts of glyoxal (OCHCHO) and formic acid (HOCHO), and the oxidation chemistry of these intermediates is important for the overall reaction. 相似文献
115.
Abbas Afkhami Hasan Bagheri Ali Shirzadmehr Hosein Khoshsafar Pegah Hashemi 《Electroanalysis》2012,24(11):2176-2185
A novel and effective potentiometric sensor for the rapid determination of Cd2+ based on carbon paste electrode consisting of the room temperature ionic liquid 1‐butyl‐3‐methylimidazolium hexafluorophosphate, multiwalled carbon nanotubes, silica nanoparticles and ionophore was constructed. The prepared composite has a low potential drift, high selectivity and fast response time, which leads to a more stable potential signal. A linear dynamic range of 4.50×10?9–1.00×10?1 mol L?1 with a detection limit of 2.00×10?9 mol L?1 was obtained. The modified electrode was successfully applied to the accurate determination of trace amounts of Cd2+ in environmental and biological samples. 相似文献
116.
Seyed Mosayeb Daryanavard Amin Jeppsson‐Dadoun Lars I. Andersson Mahdi Hashemi Mohamed Abdel‐Rehim 《Biomedical chromatography : BMC》2013,27(11):1481-1488
This study presents the use of molecularly imprinted polymer (MIP) as packing material for microextraction by packed syringe (MEPS) to achieve higher extraction selectivity. Pentycaine was used as template for MIP. Development and validation of the determination of lidocaine, ropivacaine, mepivacaine and bupivacaine in human plasma and urine samples utilizing MIP‐MEPS and liquid chromatography–tandem mass spectrometry (LC‐MS/MS) were carried out. The MEPS MIP‐cartridge could be used for 100 extractions before it was discarded. The extraction recovery ranged from 60 to 80%. The correlation coefficients values were >0.999 for all assays using lidocaine, ropivacaine, mepivacaine and bupivacaine in the calibration range 5–2000 nmol/L. The accuracy of the studied compounds, given as a percentage variation from the nominal concentration values, ranged from ‐4.9 to 8.4% using plasma and urine samples. The between‐batch precision, given as the relative standard deviation, at three different concentrations (quality control samples) was ranged from ?4.7 to 14.0% and from 1.8 to 12.7% in plasma and urine, respectively. The lower limit of quantification and limit of detection of the studied substances were 5.0 and 1.0 nm , respectively. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
117.
Synthesis of coprecipitated strontium hexaferrite nanoparticles in the presence of polyvinyl alcohol
A. DavoodiB. Hashemi M.H. Yousefi 《Journal of magnetism and magnetic materials》2011,323(23):3054-3057
Strontium hexaferrite (SrFe12O19) nanoparticles were synthesized by the chemical coprecipitation method and using polyvinyl alcohol (PVA) as a protective agent. The synthesized samples were characterized by differential thermal analysis, X-ray diffraction, scanning and transmission electron microscopy, particle size analyzer, sedimentation test and vibrating sample magnetometer. In the presence of PVA, the single-phase SrFe12O19 nanoparticles were obtained at low temperature of 650 °C. The average particle size of SrFe12O19 precursor was 15 nm, which increased to 61 nm after calcination at 650 °C. The magnetic measurements indicated that PVA decreased coercivity from 4711 to 3216 Oe with particle size reduction. The results showed that PVA as a protective agent could be effective in decreasing the particle size, calcination temperature and coercivity of SrFe12O19 nanoparticles. 相似文献
118.
F. Nazari Serenjeh P. Hashemi M. Safdarian Z. Kheirollahi 《Journal of the Iranian Chemical Society》2014,11(3):733-739
A semi-automated cold column trapping-cloud point extraction (CCT-CPE) method was developed and applied to the determination of phenazopyridine in human serum. In the proposed technique, a mixture of sample (pH 8) and Triton X-100 (0.4 % v/v) was incubated at 90 °C for 5 min in a heating sample cell. The developed turbid solution was then flowed through a CCT preconcentration column packed with C18 sorbent using a peristaltic pump. A pair of thermal electric cooler (TEC) plates was used for cooling the column. The surfactant-rich phase was retained on the CCT at 0 °C and desorbed, subsequently, in an elevated temperature by ethanol. The analytical parameters such as pH, surfactant concentration, temperature and incubation time were optimized by a central composite design (response surface) method. Six replicated analyses at the optimized conditions resulted in a recovery of 99.7 % and a relative standard deviation of 2.45 for phenazopyridine. The detection limit of the method (3σ) was 0.50 mg L?1 for the analyte. Compared to conventional CPE, the proposed CCT-CPE method required less sample handling, eliminated the centrifugation step and was substantially faster. The method was successfully applied to the determination of phenazopyridine in some human serum and tablet samples. 相似文献
119.
Behrooz Maleki Saba Hemmati Reza Tayebee Sirous Salemi Yasaman Farokhzad Mehdi Baghayeri Farrokhzad Mohammadi Zonoz Elahe Akbarzadeh Rohollah Moradi Azam Entezari Mohammad Reza Abdi Samaneh Sedigh Ashrafi Fereshteh Taimazi Majid Hashemi 《Helvetica chimica acta》2013,96(11):2147-2151
A convenient synthesis of sulfonamides and sulfonyl azides from thiols is described. In situ preparation of sulfonyl chlorides from thiols was accomplished by oxidation with chloramine‐T (=N‐chlorotosylamide=N‐chloro‐4‐methylbenzenesulfonamide), tetrabutylammonium chloride (Bu4NCl), and H2O. The sulfonyl chlorides were then further allowed to react with excess amine or NaN3 in the same pot. 相似文献
120.
A numerical method for solving a special class of optimal control problems is given. The solution is based on state parametrization as a polynomial with unknown coefficients. This converts the problem to a non-linear optimization problem. To facilitate the computation of optimal coefficients, an improved iterative method is suggested. Convergence of this iterative method and its implementation for numerical examples are also given. 相似文献