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971.
We develop an integral version of Deligne cohomology for smooth proper real varieties. For this purpose the role played by singular cohomology in the complex case has to be replaced by the ordinary bigraded Gal(mathbbC/mathbbR){Gal(mathbb{C}/{mathbb{R}})}-equivariant cohomology of Lewis et al. (Bull Am Math Soc (N.S.) 4(2):208–212, 1981), the equivariant counterpart of singular cohomology. The theory is aimed at giving more precise information about the 2-primary components of regulators. We establish basic properties and give a geometric interpretation for the groups in dimension 2 in weights 1 and 2. 相似文献
972.
973.
Blay G Fernandez I Marco-Aleixandre A Pedro JR 《The Journal of organic chemistry》2006,71(17):6674-6677
The (S,S)-mandelamide III catalyzes the additions of both aryl- and alkylalkynylzinc reagents to heteroaromatic aldehydes with good yields and enantioselectivities up to 92%. This catalyst is easily prepared in a one-step procedure, and both enantiomers are available. Unlike most other described methods, using this catalyst does not require the addition of Ti(O(i)Pr)4. 相似文献
974.
Gisselle R. Apud Pedro A. Aredes-Fernández Marina Kritsanida Raphael Grougnet 《Natural product research》2020,34(18):2656-2659
AbstractTwenty four extracts from Bignoniaceae plants of northwest Argentina were tested for antifungal activity against Aspergillus species responsible of the grape black rot. Stems and leaves of Amphilophium cynanchoides, Macfadyena cynanchoides, Tecoma stans and Jacaranda mimosifolia were separately extracted with solvents of increasing polarity to obtain the dichloromethane (fCH2Cl2), ethyl acetate (fEtOAc) and methanol extracts (fMeOH). The fCH2Cl2 from stem of M. cynanchoides had the lowest IC50 (1.0–1.2?mg/mL) and MID values (0.6–1.2?mg) and the highest ID values (5.0–6.8?mm) on A. niger and A. carbonarius. The main contributors of the antifungal activity of fCH2Cl2 were identified as lapachol (MIC?=?0.25–1.00?mg/ml) and 1-hydroxy-4-methylanthraquinone (MIC?=?0.0625–0.125?mg/mL). These compounds synergized the antifungal activity of sodium metabisulfite and showed an additive effect in mixtures with propiconazol. They might be used as additives of commercial antifungals to protect grapes against A. niger and A. carbonarius. 相似文献
975.
J.M.A. Figueiredo 《Physica A》2007,386(1):167-175
A first-principles Monte Carlo code that exactly simulates quantum dynamics is presented which makes no use of amplitude calculations, only noise sources. The subtle question concerning how to map random choices in amplitude interferences is explained. In this formalism negative values of the Wigner function have clear logical meaning. 相似文献
976.
977.
Pedro A. Gonzalez Beermann Bruce R. McGarvey Boris O. Skadtchenko Subra Muralidharan Raymond C.W. Sung 《Journal of nanoparticle research》2006,8(2):235-241
Mn2+-doped ZnS nanoparticles of average size 2.5±0.3 nm have been studied and characterized in the dopant concentration range 0.1–0.3% using XRD, EPR, XPS and photoluminescence methods. The experimental results obtained from these studies indicate that the doping of Mn2+ occurs primarily at the T
d sites at low dopant concentration, causing the4T1(G) → 6A1(S) transition to take place in the host lattice; the observed decrease in the intensity of photoluminescence at high dopant concentration is due to the setting in of the strong Mn2+–Mn2+ interaction arising from cluster formation at the highly distorted sites near the particle surface.An erratum to this article can be found at 相似文献
978.
The problem of fermions in 1+1 dimensions in the presence of a pseudoscalar Coulomb potential plus a mixing of vector and scalar Coulomb potentials which have equal or opposite signs is investigated. We explore all the possible signs of the potentials and discuss their bound-state solutions for fermions and antifermions. We show the relation between spin and pseudospin symmetries by means of charge-conjugation and γ5 chiral transformations. The cases of pure pseudoscalar and mixed vector–scalar potentials, already analyzed in previous works, are obtained as particular cases. The results presented can be extended to 3+1 dimensions. 相似文献
979.
I. de Pedro J.M. Rojo J. Rodríguez Fernández T. Rojo 《Journal of solid state chemistry》2011,184(8):2075-2082
The Co2−xCux(OH)AsO4 (x=0 and 0.3) compounds have been synthesized under mild hydrothermal conditions and characterized by X-ray single-crystal diffraction and spectroscopic data. The hydroxi-arsenate phases crystallize in the Pnnm orthorhombic space group with Z=4 and the unit-cell parameters are a=8.277(2) Å, b=8.559(2) Å, c=6.039(1) Å and a=8.316(1) Å, b=8.523(2) Å, c=6.047(1) Å for x=0 and 0.3, respectively. The crystal structure consists of a three-dimensional framework in which M(1)O5-trigonal bipyramid dimers and M(2)O6-octahedral chains (M=Co and Cu) are present. Co2(OH)AsO4 shows an anomalous three-dimensional antiferromagnetic ordering influenced by the magnetic field below 21 K within the presence of a ferromagnetic component below the ordering temperature. When Co2+ is partially substituted by Cu2+ions, Co1.7Cu0.3(OH)AsO4, the ferromagnetic component observed in Co2(OH)AsO4 disappears and the antiferromagnetic order is maintained in the entire temperature range. Heat capacity measurements show an unusual magnetic field dependence of the antiferromagnetic transitions. This λ-type anomaly associated to the three-dimensional antiferromagnetic ordering grows with the magnetic field and becomes better defined as observed in the non-substituted phase. These results are attributed to the presence of the unpaired electron in the dx2−y2 orbital and the absence of overlap between neighbour ions. 相似文献
980.
Lucía Guillade Paula Mora Pedro Villar Rosana Alvarez Angel R. de Lera 《Chemical science》2021,12(45):15157
Inspired by the biogenetic proposal of an intramolecular Diels–Alder (IMDA) cycloaddition, the total synthesis of natural product nahuoic acid A, a cofactor-competitive inhibitor of the epigenetic enzyme lysine methyl transferase SETD8, has been carried out. A non-conjugated pentaenal precursor was synthesized with high levels of stereoselectivity at seven stereogenic centers and with the appropriate control of double bond geometries. Although the IMDA reaction of the non-conjugated pentaenal using Me2AlCl for catalysis at −40 °C selectively afforded the trans-fused diastereomer corresponding to the Re-endo mode of cycloaddition, under thermal reaction conditions it gave rise to a mixture of diastereomers, that preferentially formed through the exo mode, including the cis-fused angularly-methylated octahydronaphthalene diastereomer precursor of nahuoic acid A. The natural product could be obtained upon oxidation and overall deprotection of the hydroxyl groups present in the Si-exo IMDA diastereomer.The total synthesis of natural product nahuoic acid A, a cofactor-competitive inhibitor of the epigenetic enzyme lysine methyl transferase SETD8, has been carried out based on the biogenetic proposal of an intramolecular Diels–Alder (IMDA) cycloaddition. 相似文献