Application of solution techniques for rapid growth of organic crystals

Single crystals of a pure hydrocarbon, 1,3,5-triphenylbenzene, with properties suitable for high-energy neutron detection were grown from toluene solutions using slow evaporation and temperature reduction methods with growth rates up to 10 mm/day. Application of the rapid growth technique developed earlier for growth of large water-soluble crystals shows that crystals of aromatic compounds can be successfully grown from solutions in large volumes required for their use as scintillator materials for radiation detection.     

Stable base loci, movable curves, and small modifications, for toric varieties

We show that the dual of the cone of divisors on a complete -factorial toric variety X whose stable base loci have dimension less than k is generated by curves on small modifications of X that move in families sweeping out the birational transforms of k-dimensional subvarieties of X. We give an example showing that it does not suffice to consider curves on X itself. Supported by a Graduate Research Fellowship from the NSF     

Multisegmented one-dimensional nanorods prepared by hard-template synthetic methods

In the science and engineering communities, the nanoscience revolution is intensifying. As many types of nanomaterials are becoming more reliably synthesized, they are being used for novel applications in all branches of nanoscience and nanotechnology. Since it is sometimes desirable for single nanomaterials to perform multiple functions simultaneously, multicomponent nanomaterials, such as core-shell, alloyed, and striped nanoparticles, are being more extensively researched. Nanoscientists hope to design multicomponent nanostructures and exploit their inherent multiple functionalities for use in many novel applications. This review highlights recent advances in the synthesis of multisegmented one-dimensional nanorods and nanowires with metal, semiconductor, polymer, molecular, and even gapped components. It also discusses the applications of these multicomponent nanomaterials in magnetism, self-assembly, electronics, biology, catalysis, and optics. Particular emphasis is placed on the new materials and devices achievable using these multicomponent, rather than single-component, nanowire structures.     

Observation of a red-blue detuning asymmetry in matter-wave superradiance

We report the first experimental observation of strong suppression of matter-wave superradiance using blue-detuned pump light and demonstrate a pump-laser detuning asymmetry in the collective atomic recoil motion. In contrast to all previous theoretical frameworks, which predict that the process should be symmetric with respect to the sign of the detuning of the pump laser from the one-photon resonance, we find that for condensates the symmetry is broken. With high condensate densities and red-detuned pump light the distinctive multiorder, matter-wave scattering pattern is clearly visible, whereas with blue-detuned pump light superradiance is strongly suppressed. However, in the limit of a dilute atomic gas symmetry is restored.     

Blow-up and decay criteria for a model of chemotaxis

For a system of equations introduced by Jäger and Luckhaus (1992) [6] as a model of chemotaxis, the questions of blow-up and global existence criteria are investigated. Specifically, for a convex region, a lower bound for the blow-up time is derived if the solution blows up, and explicit criteria to ensure non-blow-up are determined.     

The existence of soliton metrics for nilpotent Lie groups

We show that a left-invariant metric g on a nilpotent Lie group N is a soliton metric if and only if a matrix U and vector v associated the manifold (N, g) satisfy the matrix equation U v = [1], where [1] is a vector with every entry a one. We associate a generalized Cartan matrix to the matrix U and use the theory of Kac–Moody algebras to analyze the solution spaces for such linear systems. An application to the existence of soliton metrics on certain filiform Lie groups is given.     

Some uniqueness and continuous dependence theorems for nonlinear elastodynamics in exterior domains

AMS (MOS) Nos. 73C50, 73C15; 35B30, 35M05

Uniqueness and Höolder continuous dependence upon the initial data of the null solution to the initial boundary value problem of nonlinear hyperelasticity are proved for exterior domains subject to mild asymptotic behaviour on the displacement, velocity and stress components. The strain-energy is not required to be locally sign-definite although at sufficiently large spatial distances it must be non-negative. Other limitations imposed on the strain-energy become identically satisfied upon reduction to the linear theory.     

Developments in electrochemical processes for recycling lead–acid batteries

The lead–acid battery recycling industry is very well established, but the conventional pyrometallurgical processes are far from environmentally benign. Hence, recent developments of lead–acid battery recycling technologies have focused on low-temperature (electro)hydrometallurgical processes, the subject of this review, covering modified electrolytes, improved reaction engineering, better reactor design and control of operating conditions.     

Electrophoresis of ssDNA through nanoelectrode gaps from molecular dynamics: impact of gap width and chain length

Molecular dynamics simulations were performed to study the translocation of single-stranded (ss) DNA through the nanoscale gap between the nanoscale electrodes of a proposed genomic sequencing device. An applied electric field forces the ssDNA to move in the direction of the nanoscale gap in platinum electrodes. A series of simulations utilizing eight different nanoscale gap distances as well as seven different nucleotide chain lengths were performed to determine the impact of these variables on the overall design of the sequencing device and the translocation behavior of ssDNA. The results clearly indicate a threshold value of the gap width below which the ssDNA will readily enter and traverse the nanoscale gap. Translocation velocities obtained for various chain lengths were consistent with simulated bulk data; however, successful translocation was inconsistent, possibly related to the sample's affinity for the metal electrodes. An attempt at overcoming this barrier was made through the implementation of shaped electrodes as well as pre-threading of the ssDNA sample.