Effect of Satureja khuzestanica essential oil on oxidative stability of sunflower oil during accelerated storage

In this study, the application of various concentrations (0.02%, 0.04%, 0.06% and 0.08%) of Satureja khuzestanica essential oil (EO) was examined on the oxidative stability of sunflower oil and compared to butylated hydroxyanisole (BHA) during storage at 60°C. Gas chromatography (GC) and GC-mass spectrometry analyses of the oils revealed that carvacrol (87.7%) was the major component of EO. Peroxide value and anisidine value measurements in sunflower oil showed that all concentrations of EO had antioxidant effects in comparison to BHA. Oil samples supplemented with EO concentration of 0.08% were the most stable during storage (p?相似文献   

Simultaneous spectrophotometric determination of uranium and zirconium using cloud point extraction and multivariate methods

A cloud point extraction (CPE) process using the nonionic surfactant Triton X-114 to simultaneous extraction and spectrophotometric determination of uranium and zirconium from aqueous solution using partial least squares (PLS) regression is investigated. The method is based on the complexation reaction of these cations with Alizarin Red S (ARS) and subsequent micelle-mediated extraction of products. The chemical parameters affecting the separation phase and detection process were studied and optimized. Under the optimum experimental conditions (i.e. pH 5.2, Triton X-114?=?0.20%, equilibrium time 10?min and cloud point 45?°C), calibration graphs were linear in the range of 0.01?C3?mg?L^?1 with detection limits of 2.0 and 0.80???g L^?1 for U and Zr, respectively. The experimental calibration set was composed of 16 sample solutions using an orthogonal design for two component mixtures. The root mean square error of predictions (RMSEPs) for U and Zr were 0.0907 and 0.1117, respectively. The interference effect of some anions and cations was also tested. The method was applied to the simultaneous determination of U and Zr in water samples.     

On solving continuous-time dynamic network flows

Temporal dynamics is a crucial feature of network flow problems occurring in many practical applications. Important characteristics of real-world networks such as arc capacities, transit times, transit and storage costs, demands and supplies etc. are subject to fluctuations over time. Consequently, also flow on arcs can change over time which leads to so-called dynamic network flows. While time is a continuous entity by nature, discrete-time models are often used for modeling dynamic network flows as the resulting problems are in general much easier to handle computationally. In this paper, we study a general class of dynamic network flow problems in the continuous-time model, where the input functions are assumed to be piecewise linear or piecewise constant. We give two discrete approximations of the problem by dividing the considered time range into intervals where all parameters are constant or linear. We then present two algorithms that compute, or at least converge to optimum solutions. Finally, we give an empirical analysis of the performance of both algorithms.     

Observability of light charged Higgs decay to muon in top quark pair events at LHC

In this paper the charged Higgs signal through the decay to a pair of muon and neutrino (H ^±→μν) is analyzed. The analysis attempts to estimate the amount of muonic signal of the charged Higgs at LHC at a center of mass energy of 14 TeV. The signal process is the top quark pair production with one of the top quarks decaying to a charged Higgs (non SM anomalous top decay) and the other decaying to a W boson which is assumed to decay hadronically to two light jets. Due to the small branching ratio of charged Higgs decay to muon, results are quoted for data corresponding to an integrated luminosity of 300 fb⁻¹ which is expected to be collected at the LHC high luminosity regime. It is shown that a signal significance close to 5σ down to below 1σ is achievable for a charged Higgs mass in the range 80 GeV<m(H ^±)<150 GeV taking the top quark pair production with both top quarks decaying to W bosons as the main irreducible background.     

Wideband tunable laser phase noise reduction using single sideband modulation in an electro-optical feed-forward scheme

A wideband laser phase noise reduction scheme is introduced where the optical field of a laser is single sideband modulated with an electrical signal containing the discriminated phase noise of the laser. The proof-of-concept experiments on a commercially available 1549 nm distributed feedback laser show linewidth reduction from 7.5 MHz to 1.8 kHz without using large optical cavity resonators. This feed-forward scheme performs wideband phase noise cancellation independent of the light source and, as such, it is compatible with the original laser source tunability without requiring tunable optical components. By placing the proposed phase noise reduction system after a commercial tunable laser, a tunable coherent light source with kilohertz linewidth over a tuning range of 1530-1570 nm is demonstrated.     

A Facile One‐Pot Synthesis of Substituted Quinolines via New Multicomponent Reaction

An efficient synthesis of quinoline derivatives is described via the reaction between ethyl chloropyruvate or alkyl 4‐chloroacetoacetate and activated acetylenic compounds in the presence of nucleophilic form of isatin in water as the solvent. Nucleophilic form of isatin is produced from the reaction of isatin and triethylamin.     

Evolutionary Algorithms for Approximate Optimal Control of the Heat Equation with Thermal Sources

In this paper, optimal control problem (OCP) governed by the heat equation with thermal sources is considered. The aim is to find an optimal control which puts the system in a finite time T, into a stationary regime and to minimize a general objective function. To obtain an approximate solution of this problem, a partition of the time-control space is considered and the discrete form of the problem is converted to a quasi assignment problem. Then by using an evolutionary algorithm, an approximate optimal control function is obtained as a piecewise linear function. Numerical examples are given to show the proficiency of the presented algorithm.     

An AlGaN/GaN HEMT with reduced surface electric field and improved breakdown voltage

A reduced surface electric field in AlGaN/GaN high electron mobility transistor (HEMT) is investigated by employing a localized Mg-doped layer under the two-dimensional electron gas (2-DEG) channel as an electric field shaping layer. The electric field strength around the gate edge is effectively relieved and the surface electric field is distributed evenly as compared with those of HEMTs with conventional source-connected field plate and double field plate structures with the same device physical dimensions. Compared with the HEMTs with conventional source-connected field plate and double field plate, the HEMT with Mg-doped layer also shows that the breakdown location shifts from the surface of the gate edge to the bulk Mg-doped layer edge. By optimizing both the length of Mg-doped layer, L_m, and the doping concentration, a 5.5 times and 3 times the reduction in the peak electric field near the drain side gate edge is observed as compared with those of the HEMTs with source-connected field plate structure and double field plate structure, respectively. In a device with V_GS=-5 V, L_m=1.5 μm, a peak Mg doping concentration of 8× 10¹⁷ cm^-3 and a drift region length of 10 μm, the breakdown voltage is observed to increase from 560 V in a conventional device without field plate structure to over 900 V without any area overhead penalty.     

Piezoelectric composites with periodic multi-coated inhomogeneities

A new, robust homogenization scheme for determination of the effective properties of a periodic piezoelectric composite with general multi-coated inhomogeneities is developed. In this scheme the coating does not have to be thin, the shape and orientation of the inclusion and coatings do not have to be identical, their centers do not have to coincide, their properties do not have to remain uniform, and the microstructure can be with the 2D elliptic or the 3D ellipsoidal inclusions. The development starts from the local electromechanical equivalent inclusion principle through the introduction of the position-dependent equivalent eigenstrain and electric field. Then with a Fourier series expansion and a superposition procedure, the volume-averaged equivalent eigenstrain and electric field for each phase are obtained. The results in turn are used in an energy equivalent criterion to determine the effective properties of the composite. In this model the interphase interactions in each multi-coated particle and the long-range interactions between the periodically distributed particles are fully accounted for. To demonstrate its wide range of applicability, we applied it to examine the properties of several periodic composites: (i) piezoelectric PZT spherical particles in a polymer matrix, (ii) continuous glassy fibers with thin PZT coating in an epoxy matrix, (iii) spherical PZT particles coated by thick or functionally graded piezoelectric layer, (iv) spheroidal voids coated with a thick non-piezoelectric layer in a PZT matrix, and (v) spherical piezoelectric inhomogeneities with eccentric, non-uniform thickness coating. The calculated results reflect the complex nature of interplay between the properties of core, matrix, and coating, as well as whether the coating is uniform, functionally graded, or eccentric. The accuracy of this new scheme is checked against the double-inclusion and other micromechanics models, and good agreement is observed.     

Ruthenium/dendrimer complex immobilized on silica-functionalized magnetite nanoparticles catalyzed oxidation of stilbenes to benzil derivatives at room temperature

A new ruthenium/dendrimer complex stabilized on the surface of silica-functionalized nano-magnetite was fabricated and well characterized. The nano-catalyst showed good activity in the synthesis of benzil derivatives via the oxidation of stilbenes with high turnover frequency (TOF) at room temperature. Moreover, the catalyst could also be reused up to fifteen times without any loss of its activity.