Lyotropic nanowire dispersions are attractive precursors for semiconductor device fabrication because they permit the alignment control of active nanomaterials. The reliable production of nanowire-based mesophases, however, is very challenging in practice. We show that appropriately functionalized high-aspect-ratio nanowires of single-crystal ZnO spontaneously form nematic phases in organic and aqueous media. These systems show isotropic, biphasic, and nematic phases on increasing concentration, in reasonable agreement with Onsager's theory for rigid rods interacting via excluded volume. Suspensions were readily processed to produce films with large-area monodomains of aligned nanowires. Imprints of the director field in quiescently dried films display a propensity for bend deformation in the organic mesophase versus splay deformation in the aqueous case, suggesting that system elasticity may be tuned via surface functionalization. These results provide critical insight for the utilization of semiconductor nanowires as novel mesogens and further enable the use of solution-based routes for fabricating optoelectronic devices. 相似文献
A new approach to the rapid determination of amoxicillin (AMO) in human plasma followed by solid phase microextraction (SPME) fiber coatings based on conducting polymers (polypyrrole and polythiophene) and high performance liquid chromatography (HPLC) has been described. The porous structures of the electrochemically deposited polymer coatings have been characterized by scanning electron microscopy (SEM). The experimental parameters relating to the extraction efficiency of the SPME fibers such as pH, extraction time and desorption conditions (solvents, time) were studied and selected. The SPME/HPLC-UV method was linear over a working range of 1-50 μg ml(-1). The inter-day accuracy (expressed as coefficients of variations, CVs) was less than 15% and precision (expressed as the relative standard deviations, RSDs) with percentage values was less than 5.9%. Amoxicillin was found to be stable in the human plasma at room temperature (20 °C) within 8 hours. The developed method was successfully applied to the analysis of real human plasma samples. The limit of detection and limit of quantification for amoxicillin in plasma were 1.21 μg ml(-1) and 3.48 μg ml(-1), respectively. 相似文献
Electrochemistry and biomembranes are interface science in that both are concerned with the phenomena at, as well as across, the interfaces. Membrane electrochemistry may be defined as the application of electrochemistry to biomembrane studies. Additionally, transport processes within the membrane are involved in biomembranes. Since biomembranes are diverse and are usually not amenable to probing by electrochemicophysical techniques, model membrane systems have been developed for their investigation.
The introduction of experimental bilayer lipid membranes (BLM) technique and its modifications have been instrumental in the development and testing of membrane transport concepts (carriers vs channels) and electronic processes in membranes. Instead merely viewing a biomembrane as a physical barrier containing carriers or channels to carry out ionic processes, an ultrathin lipid or biological membrane can also be considered as a complete ‘electrochemical cell’ with one membrane/solution interface reducing (as a cathode) and the other membrane/solution interface oxidizing (as an anode). It is now possible to understand energy transduction (charge generation, separation, and redox reactions) in terms of ultrathin lipid membranes separating two aqueous solutions.
In this paper, we shall discuss the basic principles of electrochemistry as they are applied to membrane studies. Emphasis will be on experimental bilayer lipid membranes (BLM) which have been extensively investigated as models of biomembranes. 相似文献
Over the last decade nanofluids (colloidal suspensions of solid nanoparticles) sparked excitement as well as controversy.
In particular, a number of researches reported dramatic increases of thermal conductivity with small nanoparticle loading,
while others showed moderate increases consistent with the effective medium theories on well-dispersed conductive spheres.
Accordingly, the mechanism of thermal conductivity enhancement is a hotly debated topic. We present a critical analysis of
the experimental data in terms of the potential mechanisms and show that, by accounting for linear particle aggregation, the
well established effective medium theories for composite materials are capable of explaining the vast majority of the reported
data without resorting to novel mechanisms such as Brownian motion induced nanoconvection, liquid layering at the interface,
or near-field radiation. However, particle aggregation required to significantly enhance thermal conductivity, also increases
fluid viscosity rendering the benefit of nanofluids to flow based cooling applications questionable. 相似文献
A notion of anin-tree is introduced. It is then used to characterize and count plane embeddings of outerplanar graphs. In-trees have also been applied in the study of independent vertex covers of faces in outerplanar graphs.This research was partially supported by the grant RP.I.09, from the Institute of Informatics, University of Warsaw. Hospitality of the Institute of Datalogy, University of Copenhagen where this research has been completed is gratefully acknowledged. 相似文献
We give a number of structural results for the problem of constructing a minimum-length 2-connected network for a set of terminals in a graph, where edge-weights satisfy the triangle inequality. A new algorithmic framework, based on our structural results, is given. 相似文献
The generalized Steiner problem (GSP) is concerned with the determination of a minimum cost subnetwork of a given network where some (not necessarily all) vertices satisfy certain pairwise (vertex or edge) connectivity requirements.The GSP has applications to the design of water and electricity supply networks, communication networks and other large-scale systems where connectivity requirements ensure the communication between the selected vertices when some vertices and/or edges can become inoperational due to scheduled maintenance, error, or overload.The GSP is known to beNP-complete. In this paper we show that if the subnetwork is required to be biconnected or respectively edge-biconnected, and the underlying network is outerplanar, the GSP can be solved in linear time. 相似文献
The problem of linearity of probability measures on hyperfinite factors is studied in Part I. Part II contains the extension of Vital-Hahn-Saks, Egoroff and Lusic theorems for probability measures on von Neumann algebras. These problems have immediate connections with properties of physical states on observable algebras in the sense of Mackey. 相似文献
The aim of this paper is to prove that every finitely generated, arithmetical variety of finite type, in which every subdirectly irreducible algebra has linearly ordered congruences has a decidable first order theory of its finite members. The proof is based on a representation of finite algebras from such varieties by some quotients of special subdirect products in which sets of indices are partially ordered into dual trees. Then the result of M. O. Rabin about decidability of the monadic second order theory of two successors is applied.Presented by Stanley Burris. 相似文献