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71.
Covalent adlayer growth on a diamond thin film surface 总被引:1,自引:0,他引:1
Krysiński P Show Y Stotter J Blanchard GJ 《Journal of the American Chemical Society》2003,125(42):12726-12728
The surface of boron-doped diamond thin films can be modified by exposure to a strong oxidizing agent, resulting in the formation of -OH and =O terminated diamond. The -OH groups are reacted with an acid chloride to produce a covalently bound, modified diamond thin film surface. The demonstration of these reactions allows for the facile modification of diamond surfaces using techniques well established for oxide surfaces. Characterization of the covalently bound species shows submonolayer coverage, and time-resolved fluorescence measurements are reflective of the highly featured nature of the diamond film. 相似文献
72.
[reaction: see text] Vinylsilanes are formed in high yields in the reaction of representative acyl(trimethyl)silanes with anions generated from Kocienski's sulfones. 相似文献
73.
Walter?Oelert Magnus?Wolke Pawe??Moskal COSY- collaboration at COSY-Jülich 《Czechoslovak Journal of Physics》2000,50(4):69-90
During the actual lectures, features of the COSY-Jülich accelerator were presented, followed by a short summary of ongoing experiments at the COoler SYnchrotron COSY using internal as well as external beams in the range of 45 MeV to 2.5 GeV. Here the research of the COSY-11 collaboration is presented. This °0 facility studies the hidden and open strangeness production observing the ν and η′ as well the K+Y and K+K? production in the proton—proton interactions at the respective thresholds. 相似文献
74.
75.
Adam Rudziński Anna Tyszka-Zawadzka Paweł Szczepański 《Optical and Quantum Electronics》2007,39(4-6):501-510
The aim of this paper is to present the analysis of influence of defects in 1D photonic crystal (PC) on the density of states
and simultaneously spontaneous emission, in both spatial and frequency domains. In our investigations we use an analytic model
of 1D PC with defects. Our analysis reveals how presence of a defect causes a defect mode to appear. We show that a defect
in 1D PC has local character, being negligible in regions of PC situated far from the defected elementary cell. We also analyze
the effect of multiple defects, which lead to photonic band gap splitting. 相似文献
76.
77.
In this article, we begin a systematic study of conformal properties of codimension-1 foliations. We first define and study
local conformal invariants. A case of particular interest is that of harmonic foliations of the plane. Then we study existence
of totally umbilical and “Dupin” foliations on compact 3-manifolds of constant curvature.
相似文献
78.
Maciej Kubicki Teresa Borowiak Jerzy Suwiński Paweł Wagner 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(1):106-108
Crystalline 4-nitro-1-phenylimidazole, C9H7N3O2, (I), and 4′-nitro-1-phenyl-4,1′-biiimidazole, C12H9N5O2, (II), contain C—H⃛O and C—H⃛N hydrogen bonds, connecting the molecules into infinite chains. The aromatic fragments in both compounds are nearly planar. The dihedral angles between the benzene and imidazole rings are 26.78 (5)° in (I) and 29.36 (8)° in (II). 相似文献
79.
Ewa D?browska Artur Mucha Wanda Sawka-Dobrowolska Pawe? Kafarski 《Journal of organometallic chemistry》2009,694(23):3806-3813
Three-component reaction of a primary amine, diethyl phosphite and triethyl orthoformate followed by acid hydrolysis of the adduct provides N-substituted aminomethylenebisphosphonic acids in good yields. Being extremely versatile, it is commonly utilized for preparation of compounds possessing potential antiosteoporotic, antibacterial, anticancer, antiparasitic or herbicidal activity. However, the mechanism of the reaction remains unknown. p-Nitroaniline has been found an interesting tool to shed light on this matter. Its use allowed to separate and identify four intermediates, both non-phosphorus and phosphorus containing, and subsequently suggest the mechanism of the whole process. The acquired knowledge was helpful in explanation the route and the final product structure obtained for more complex reaction proceeding with the use of 4-aminopyridine. Additional alkylation of the pyridine nitrogen atom, leading to unexpected N-(1-alkylpyridinium-4-amino)methylenebisphosphonic acids was unambiguously proved. 相似文献
80.
Laser treatment of a solid surface was modeled by applying an analytical theory as well as by using Monte Carlo simulations. The crystalline surface was assumed to be initially smooth and chemically uniform, that is free of impurities built into the structure. Creation of surface defects by a laser beam was assumed to have entirely random nature. In particular, the surface was assumed to have been scanned by the beam focused successively on randomly chosen points. In the course of the ablation process, the beam produces a pyramidal crater whose dimensions are proportional to the applied laser power. According to the assumed nature of the scanning procedure, the craters formed by the beam are allowed to overlap. The influence of the number of laser pulses and the crater dimensions on the structural and adsorptive properties of the surface were examined by analysis of the variation of the mean surface depth and the surface width. Changes in the adsorptive properties were also estimated by the calculation of the thermally programmed desorption (TPD) spectra of monomolecular adsorbates desorbed from laser-treated surfaces. Additionally, equilibrium adsorption isotherms were calculated for the obtained surfaces. 相似文献