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31.
Kučinskaitė Agnė Pobłocka-Olech Loretta Krauze-Baranowska Mirosława Briedis Vitalis Savickas Aruñas Sznitowska Małgorzata 《平面色谱法杂志一现代薄层色谱法》2007,20(2):121-125
SPE and TLC have been used for qualitative and quantitative analysis of salidroside, rosavin, rosarin, and rosin in commercially available dry extracts from Rhodiola rosea roots. The best separation of all the compounds was achieved on silica gel TLC plates with ethyl acetate—methanol—water, 77 + 13 + 10 (v/v), as mobile phase. UV detection was performed at λ = 215 nm for salidroside and at λ= 245 nm for the rosavins (rosavin, rosarin, and rosin). Detection limits for salidroside and the rosavins were 90 ng and 60 ng per spot, respectively. Results from quantitative analysis confirmed the manufacturer’s declaration of the amounts of salidroside and the rosavins in the extracts.
相似文献32.
Cl···O intramolecular contacts are analysed here. Hence the Cambridge Structural Database (CSD) search was performed to find
five-membered Cl–C=C–C=O pseudo-rings closed through Cl···O intramolecular contacts. Such rings were analysed and it was found
that some of Cl···O distances are smaller than the corresponding sum of van der Waals radii. Additionally ab initio MP2/6-311++G(d,p)
calculations and AIM analyses were carried out here on 3-chloropropenal and its fluoro derivatives to deepen the nature of
intramolecular Cl···O interactions, some of findings may indicate that they are attractive and stabilizing ones.
This paper is dedicated to Prof. T. M. Krygowski on the occasion of his 70th birthday 相似文献
33.
The solvation force of a simple fluid confined between identical planar walls is studied in two model systems with short ranged fluid-fluid interactions and long-ranged wall-fluid potentials decaying as -Az(-p),z--> infinity, for various values of p. Results for the Ising spins system are obtained in two dimensions at vanishing bulk magnetic field h=0 by means of the density-matrix renormalization-group method; results for the truncated Lennard-Jones (LJ) fluid are obtained within the nonlocal density functional theory. At low temperatures the solvation force f(solv) for the Ising film is repulsive and decays for large wall separations L in the same fashion as the boundary field f(solv) approximately L(-p), whereas for temperatures larger than the bulk critical temperature f(solv) is attractive and the asymptotic decay is f(solv) approximately L(-(p+1)). For the LJ fluid system f(solv) is always repulsive away from the critical region and decays for large L with the the same power law as the wall-fluid potential. We discuss the influence of the critical Casimir effect and of capillary condensation on the behavior of the solvation force. 相似文献
34.
Maria Nowakowska Mirosława Smoluch Dorota Sendor 《Journal of inclusion phenomena and macrocyclic chemistry》2001,40(3):213-219
The effect of -, - and -cyclodextrin onthe photochemical stability of 7-amino-4-methylcoumarin (C120)was studied. Using spectroscopic techniques (UV/Vis absorption spectroscopy, fluorescence, fluorescence anisotropy and circular dichroism) combined with HPLC/MS and MS analysis it was demonstrated that addition of -cyclodextrin to the aqueoussolution of C120 markedly inhibits the photodegradation of that dye. This results from theformation of an inclusion complex between C120 and -cyclodextrin. 相似文献
35.
36.
The Monte-Carlo model of a light-emitting diode 总被引:1,自引:0,他引:1
The first complete Monte-Carlo model of a surface light-emitting diode is presented in this paper. In the model all important phenomena (including the two-dimensional diffusion of minority carriers before their recombination in the active region and the re-emission of radiation) are taken into account. The influence of various construction parameters on the external quantum efficiency of the homojunction GaAs diode is examined. 相似文献
37.
38.
Summary
A simple two-velocity model (-model)of the Boltzmann-Enskog equation for a gas of hard spheres is proposed. Physical properties of such a model are analyzed and its differences with respect to the Carleman model are investigated. Global existence theorems and some qualitative properties of solutions of the -model are also proved.On leave from Dept. of Mathematics and Mechanics, University of Warsaw, Poland. 相似文献
39.
The thermal decomposition of cadmium acetate dihydrate in helium and in air atmosphere has been investigated by means of a
coupled TG-DTA-MS method combined with X-ray diffraction analysis. Dehydration of Cd(CH3COO)2·2H2O is a two-stage process with Cd(CH3COO)2·H2O as intermediate. The way of Cd(CH3COO)2 decomposition strongly depends on the surrounding gas atmosphere and the rate of heating. CdO, acetone and CO2 are the primary products of decomposition in air. In helium decomposition goes by two parallel and consecutive reactions
in which intermediates, Cd and CdCO3, are formed. Metallic cadmium oxidizes and cadmium carbonate decomposes giving CdO. Some of the metallic cadmium, depending
on the heating rate and the concentration of oxygen, evaporates. Acetone is partially oxidized in secondary reactions with
oxygen.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
40.
D. Płusa J. J. Wysłocki B. Wysłocki R. Pfranger 《Applied Physics A: Materials Science & Processing》1986,40(3):167-170
From measurements of the magnetic domain widthsD versus grain thicknessL, we have determined the domain wall energy in the demagnetized state for a sintered Nd15Fe77B8 magnet: = 56 erg/cm2. Using this wall energy and the published magnetocry-stalline constantK
1=4.9×107 erg/cm3, we have calculated the exchange constantA=4.0×10–6 erg/cm, domain wall thickness
B=89 Å, and the critical diameter for single domain particlesD
c=0.67 m. 相似文献