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101.
Pavlyuk A. V. Davydov V. N. Mys'kiv M. G. 《Russian Journal of Coordination Chemistry》2001,27(12):865-870
The crystals of [C9H7N(C3H5)]2CuIICl4(IV) were obtained through ac electrochemical synthesis using CuCl2· 2H2O, N-allylquinolinium chloride, and copper electrodes in an ethanol-benzene medium. These crystals transformed with time into crystals of the [C9H7N(C3H5)][CuIICl3(C9H7N)] complex (V). When tin(II) chloride was added to the initial reagents, the [C9H7N(C3H5)]CuI
2Cl3complex (VI) was obtained. The X-ray diffraction analysis (DARCh-1 autodiffractometer, MoK
radiation, Zr filter) indicated that complexes IVand Vcrystallize in the triclinic system: space group P
; for IV, a= 12.817(4), b= 10.435(3), c= 9.606(3) Å, = 97.94(2)°, = 107.28(2)°, = 95.99(2)°, V= 1200.6(6) Å3, Z= 2; for V, a= 16.992(5), b= 8.243(2), c= 7.345(3) Å, = 91.89(3)°, = 91.19(3)°, = 88.18(3)°, V= 1027.5(6) Å3, Z= 2. Crystals VIare monoclinic, space group P21/n, a= 13.578(5), b= 15.079(4), c= 6.953(4) Å, = 105.08(4)°, V= 1370.6(10) Å3, Z= 4. Structures IV–VIconsist of N-allylquinolinium cations and different anions: isolated [CuCl4]2–tetrahedrons (IV), [C9H7NCuCl3]–tetrahedrons (V) containing a quinoline molecule, and a polymer chain |[CuI
4Cl6]2–}
n
(VI) in which two independent metal atoms have trigonal-pyramidal and planar-trigonal environments. The C=C bond of the allyl group is not involved in cooordination with the Cu(I) atom. 相似文献
102.
The software in MATHLAB medium has been developed to model ESR spectra of paramagnetic centers in single crystals. By means of this program, the angular dependences of ESR spectra found in KY(WO4)2, potassium yttrium tungstate, doped with gadolinium were analyzed. The spectra analysis indicates that they are determined by the presence of Gd3+ ions with the electron spin S = 7/2 occupying the structural position of Y3+ ions in the crystal structure. Parameters of spin Hamiltonian were defined for the analyzed ESR spectrum of Gd3+. Unusual features of the analyzed ESR spectra have been discovered in the region of 9.5 GHz which remind by appearance SHF line. The researches made show the position of this line to correspond to the region of quasi-intersection of energetic levels, and along with the line shape it is most likely to reflect the peculiarities of the region in whose interval wave functions of the energetic levels undergo substantial modifications. 相似文献
103.
Kamila Kapusniak Karolina Lubas Malwina Wojcik Justyna Rosicka-Kaczmarek Volodymyr Pavlyuk Karolina Kluziak Idalina Gonalves Joana Lopes Manuel A. Coimbra Janusz Kapusniak 《Molecules (Basel, Switzerland)》2021,26(18)
Dietary fiber can be obtained by dextrinization, which occurs while heating starch in the presence of acids. During dextrinization, depolymerization, transglycosylation, and repolymerization occur, leading to structural changes responsible for increasing resistance to starch enzymatic digestion. The conventional dextrinization time can be decreased by using microwave-assisted heating. The main objective of this study was to obtain dietary fiber from acidified potato starch using continuous and discontinuous microwave-assisted heating and to investigate the structure and physicochemical properties of the resulting dextrins. Dextrins were characterized by water solubility, dextrose equivalent, and color parameters (L* a* b*). Total dietary fiber content was measured according to the AOAC 2009.01 method. Structural and morphological changes were determined by means of SEM, XRD, DSC, and GC-MS analyses. Microwave-assisted dextrinization of potato starch led to light yellow to brownish products with increased solubility in water and diminished crystallinity and gelatinization enthalpy. Dextrinization products contained glycosidic linkages and branched residues not present in native starch, indicative of its conversion into dietary fiber. Thus, microwave-assisted heating can induce structural changes in potato starch, originating products with a high level of dietary fiber content. 相似文献
104.
A. G. Dedov N. K. Zaitsev P. M. Zaitsev A. V. Pavlyuk S. G. Suslov 《Journal of Analytical Chemistry》2000,55(6):583-585
An alternating-current voltammetric procedure has been developed for the indirect determination of formaldehyde as its hydrazone
at a stationary hanging mercury drop over the formaldehyde concentration range from 0.2 to 15 mg/L in a buffer solution of
pH 5.6 ± 0.4 without removing dissolved oxygen. An EKOTEST-VA miniature voltammetric analyzer connected to a computer was
used. The detection limit for formaldehyde in the proposed procedure was 0.2 mg/L. 相似文献
105.
106.
V. I. Timofeev B. F. Pavlyuk A. A. Lashkov T. A. Seregina A. G. Gabdulkhakov B. K. Vaĭnshteĭn A. M. Mikhaĭlov 《Crystallography Reports》2007,52(6):1072-1078
Uridine phosphorylase (UPh) belongs to pyrimidine nucleoside phosphorylases. This enzyme catalyzes cleavage of the C-N glycoside bond in uridine to form uracil and ribose-1’-phosphate. Uridine phosphorylase supplies cells with nucleotide precursors by catalyzing the phosphorolysis of purine and pyrimidine nucleosides. This is an alternative to de novo nucleotide synthesis. The three-dimensional structure of native uridine phosphorylase from Salmonella typhimurium (StUPh) in a new crystal form was solved and refined at 1.90 Å resolution (R st = 20.37%; R free = 24.69%; the rmsd of bond lengths and bond angles are 0.009 Å and 1.223°, respectively). A homodimer containing two asynchronously functioning active sites was demonstrated to be the minimum structural unit necessary for function of the hexameric StUPh molecule (L 33L 2). Each active site is formed by amino acid residues of both subunits. 相似文献
107.
108.
Matiichuk V. S. Frolov D. A. Pokhodylo N. T. Pavlyuk V. V. Obushak M. D. 《Russian Journal of Organic Chemistry》2018,54(5):799-801
Russian Journal of Organic Chemistry - Reaction of 3-aryl-2-chloropropanal with 1-arylsulfonylpropan-2-ones in aqueous ammonia and alcohol under the conditions of Hantzsch pyrrole synthesis led to... 相似文献
109.
110.
Onishchuk D. A. Pavlyuk A. S. Parfenov P. S. Litvin A. P. Nabiev I. R. 《Optics and Spectroscopy》2018,125(5):751-755
Optics and Spectroscopy - The principle of operation of near-infrared LEDs based on PbS nanocrystals and aspects of their development are considered. The aging of nanocrystals with different ligand... 相似文献