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71.
碳化铁催化剂的制备及其对CO加氢的催化活性 总被引:2,自引:0,他引:2
以Fe2O3为原料,采用两种预处理方法制备了碳化铁催化剂. 结果表明,直接在CO气氛下进行碳化处理,或者以H2预还原后再用CO进行碳化处理均可以制备出碳化铁催化剂. 碳化温度是制备过程中的关键因素. 对于Fe2O3样品,较适宜的碳化温度是350 ℃,而对于添加了K助剂的样品,只有经H2预还原处理后再于350 ℃用CO碳化处理4 h才能将样品完全转化为Fe5C2. 在CO加氢的评价实验中,碳化铁催化剂表现出很高的催化活性,生成的烃类产物中主要是饱和烷
烃,未检测到乙烯的生成. 而在K改性的催化剂上反应产物中烯烃的含量明显提高. 相似文献
72.
The authors presented a novel synthetic route for the imidazolium functionalized poly(arylene ether ketone)s, derived from an engineering plastics polymer, a poly(arylene ether ketone) with 3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl moiety(PAEK-TM). The preparation of anion exchange membranes comprised converting benzylic methyl groups to bromomethyl groups by a radical reaction, followed by the functionalization of bromomethylated PAEK with alkyl imidazoles, i.e., methyl, butyl or vinyl imidazole. The structure of imidazolium functionalized PAEK was proved by 1H NMR spectra. A class of flexible and tough membranes was then achieved by subsequent film-forming and anion exchange processes. The water uptake and hydroxide conductivities of membranes are comparable or superior to those of quaternary ammonium(QA) anion exchange membranes. This work demonstrated a new route for non-QA anion exchange membrane design, avoiding the chloromethylation reagent and precisely controlling the degree and location of imidazolium groups. 相似文献
73.
以苯酚和含有不同链长的长链脂肪酮作为原料, 制备了与双酚A结构相似的双酚单体, 并与4, 4'-二氟二苯酮共聚, 合成了几种含有不同长度脂肪族侧链结构的聚醚醚酮类(PEEKs)聚合物. 利用元素分析和核磁共振氢谱(1H NMR)对所合成的双酚单体进行了表征, 并用红外光谱(FTIR)\, 示差量热扫描仪(DSC)、热失重分析仪(TGA)和电子拉力机对所合成的聚合物结构和性能的关系进行了研究. 相似文献
74.
N. A. Pavlycheva N. Sh. Lebedeva A. I. V’yugin V. E. Maizlish G. P. Shaposhnikov S. A. Znoiko I. G. Abramov M. B. Abramova 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(11):1847-1850
The interaction of benzotriazolyl derivatives of phthalodinitriles with copper(II) acetate was studied thermogravimetrically and spectroscopically. Electron acceptor properties of peripheral substituents had a predominant influence on the enthalpy parameter of formation of copper(II)phthalocyanines. 相似文献
75.
S. Falciano M. Guanziroli H. Hofer P. Lecomte P. Le Coultre H. Suter V. L. Telegdi G. Viertel B. Betev K. Freudenreich A. Ereditato E. Gorini P. Strolin P. Bordalo L. Cerrito L. Kluberg A. Romana R. Salmeron J. Varela J. J. Blaising A. Degré P. Juillot R. Morand B. Mours M. Winter NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1986,31(4):513-526
We present the angular distributions of muon pairs obtained in a high-statistics experiment using a 194-GeV/c π- impinging on a tungsten target. Our results are based on the analysis of 145,000 events with positive Feynmanx and mass above 4.07 GeV/c2, excluding the ? region. Simple first-order QCD relations allow us to determine the ratio of annihilation with hard-gluon emission to the sum of annihilation with hard-gluon emission and hard-gluon Compton scattering, which is found to be about 58% to 75%. We determine the parton square intrinsic transverse momenta to be of the order of 0.6 (GeV/c)2, and about 30% larger in the pion than in the nucleon. At largex 1, our data agree with the higher-twist hypothesis, and support the interpretation of the relevant scale parameter as the dimuon square transverse momentum. 相似文献
76.
77.
N. Sh. Lebedeva N. A. Pavlycheva A. I. V’yugin O. I. Davydova V. E. Maizlish G. P. Shaposhnikov 《Russian Journal of General Chemistry》2005,75(4):645-650
Thermodynamic characteristics of dimerization of water-soluble zinc, copper, and cobalt complexes of sulfo- and carboxy-substituted phthalocyanines were obtained. A correlation of the aggregative capacity of the metal phthalocyanines with the nature of the central metal atoms and the number and position of peripheral substituents was revealed.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 683–688.Original Russian Text Copyright © 2005 by Lebedeva, Pavlycheva, V’yugin, Davydova, Maizlish, Shaposhnikov. 相似文献
78.
M. Asai J. L. Bailly H. B?ttcher F. Bruyant C. Caso Y. Chiba H. Dibon B. Epp A. Ferrando F. Fontanelli S. N. Ganguli T. Gémesy R. Hamatsu P. Hidas T. Hirose J. Hrubec T. Kageya N. Khalatyan E. Kistenev I. Kita S. Kitamura V. Kubik J. MacNaughton M. Markytan S. Matsumoto I. S. Mittra L. Montanet G. Neuhofer G. Pinter P. Porth T. Rodrigo J. Singh S. Squarcia K. Takahashi R. Tanaka L. A. Tikhonova U. Trevisan R. Wischnewski T. Yamagata S. A. Zotkin NA EHS-RCBC Collaboration 《Zeitschrift fur Physik C Particles and Fields》1990,46(4):593-598
Properties of proton diffractive dissociation have been investigated for four-prong final states in proton-proton reactions at 360 GeV/c, in particular forpp→ppπ +π? mπ 0(m=0,1,2). Mass distributions and decay angular distributions are given. The decay of the diffractive system is seen to be very anisotropic, and largep T is suppressed at higher masses. It is found that the “pomeron” couples with a single valence quark of the incident proton, but indications for a diquark-pomeron coupling are also found. Similarities with fragmentation in lepton-hadron deep inelastic scattering are underlined. 相似文献
79.
新型燃料电池质子交换膜──含叔丁基的磺化聚芳醚砜 总被引:5,自引:1,他引:4
以3,3'-二磺酸钠基-4,4'-二氯二苯砜(SDCDPS)、叔丁基对苯二酚(TBHQ)、二氟二苯酮(DFBP)为原料,利用亲核缩聚反应,通过调整磺化单体(SDCDPS)和非磺化单体(DFBP)的比例与叔丁基对苯二酚(TBHQ)共聚,合成了不同磺化度的聚芳醚砜.聚合物成膜后的研究结果表明,该膜具有良好的机械性能和电化学性能,可能在质子交换膜燃料电池中得到应用. 相似文献
80.