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991.
Stephan Denifl Dr. Fabio Zappa Dr. Ingo Mähr Filipe Ferreira da Silva Abid Aleem Andreas Mauracher Dr. Michael Probst Prof. Dr. Jan Urban Prof. Dr. Pavel Mach Prof. Dr. Arntraud Bacher Dr. Olof Echt Prof. Dr. Tilmann D. Märk Paul Scheier Prof. Dr. 《Angewandte Chemie (International ed. in English)》2009,48(47):8940-8943
992.
Emanuel Makrlík Petr Vaňura Pavel Selucky 《Monatshefte für Chemie / Chemical Monthly》2008,275(2):597-600
From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium
M
2+ (aq) + 1 · Sr2+ (nb) ⇄ 1 · M
2+ (nb) + Sr2+ (aq) taking place in the two-phase water-nitrobenzene system (M
2+ = Cu2+, Zn2+, Cd2+, Pb2+, UO2
2+, Fe2+, Co2+, and Ni2+; 1 = valinomycin; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the 1 · M
2+ complexes in water saturated nitrobenzene were calculated; they were found to increase in the order Fe2+ < Cd2+, Co2+ < Ni2+ < UO2
2+, Zn2+ < Cu2+ < Pb2+. 相似文献
993.
Vratislav Langer Pavel Mach
ubomír Smr
ok Viktor Milata 《Acta Crystallographica. Section C, Structural Chemistry》2009,65(4):o183-o185
The title compound, C12H12FNO3, a potential precursor for fluoroquinoline synthesis, is essentially planar, with the most outlying atoms displaced from the best‐plane fit through all non‐H atoms by 0.163 (2) and 0.118 (2) Å. Molecules are arranged in layers oriented parallel to the (011) plane. The arrangement of the molecules in the structure is controlled mainly by electrostatic interactions, as the dipole moment of the molecule is 5.2 D. In addition, the molecules are linked by a weak C—H...O hydrogen bond which gives rise to chains with the base vector [1,1,1]. Electron transfer within the molecule is analysed using natural bond orbital (NBO) analysis. Deviations from the ideal molecular geometry are explained by the concept of non‐equivalent hybrid orbitals. 相似文献
994.
We present a new algebraic extension of the classical MacMahon Master Theorem. The basis of our extension is the Koszul duality for non-quadratic algebras defined by Berger. Combinatorial implications are also discussed.
995.
The distribution of property is established through various mechanisms. In this paper we study the acreage distribution of land plots owned by natural persons in the Zlín Region of the Czech Republic. We show that the data are explained in terms of a simple model in which the inheritance and market behavior are combined. 相似文献
996.
Nicolas Delerue Sudhir Dixit Fred Gannaway David Howell Myriam Qurshi Grahame Blair Stewart Boogert Gary Boorman Chafik Driouichi Lawrence Deacon Alexander Aryshev Pavel Karataev Nobuhiro Terunuma Junji Urakawa Axel Brachmann Joe Frisch Marc Ross 《Pramana》2007,69(6):1147-1150
A new laser-wire has been installed in the extraction line of the ATF at KEK. It aims at demonstrating that laser-wires can
be used to measure micrometre scale beam size. In parallel, studies have been made to specify a laser suitable for the ILC
laser-wires.
相似文献
997.
Rulísek L Sebek P Havlas Z Hrabal R Capek P Svatos A 《The Journal of organic chemistry》2005,70(16):6295-6302
The stereoselectivity of the reaction of furan (1) with maleic anhydride (2) and maleimide (3) was studied experimentally and theoretically. Although the two reactions are highly similar with regard to their preference for endo and exo steroisomers, notable differences were experimentally observed and explained on the basis of calculated reaction-free energies and transition-state barriers. The experimental values of rate constants (k(1+2endo) = (1.75 +/- 0.48) x 10(-5); mol(-1) l s(-1); k(1+2exo) = (3.10 +/- 0.55) x 10(-5); mol(-1) l s(-1); k(1+3endo) = (1.93 +/- 0.082) x 10(-5); mol(-1) l s(-1), k(1+3exo) = (1.38 +/- 0.055) x 10(-5); mol(-1) l s(-1) all at 300 K) and the observed reaction course clearly confirm that neither of these reactions are prototypical examples of Diels-Alder [4 + 2] cycloadditions, whose dominant preference is for endo isomers. However, only by comparing their energetics-calculated at the CCSD(T) level of theory-with the analogous reactions involving cyclopentadiene (8) as a diene can these observations be understood. The low thermodynamic stability of furan [4 + 2] adducts opens retro-Diels-Alder reaction channels and overrules the very small kinetic preference (calculated and measured here) of initial formation for endo stereoisomers. On a macroscopic scale "an irregular"-thermodynamically more stable-exo stereoisomer was consequently observed as a dominant species. 相似文献
998.
Surface Brillouin spectroscopy (SBS) has been widely used for elastic property characterization of thin films. For films thicker than 500 nm, however, the wavelength of surface acoustic wave in the frequency range available for SBS is smaller than film thickness, and the SBS measures only the Rayleigh wave of the film. The laser-SAW technique, on the other hand, measures only the low-frequency portion of the surface acoustic wave dispersion and can estimate only one elastic modulus of the film (typically Young's modulus). In this work, we have combined the two methods to determine both Young's modulus and Poisson's ratio of a diamond-like carbon (DLC) film. It was found that reasonable estimates can be obtained for the longitudinal wave velocity, shear wave velocity, and Young's modulus of the film. The Poisson's ratio, however, still has a relatively large measurement error. 相似文献
999.
The 2S electron bubble placed in liquid helium has been previously believed to be spherical. We show that the 2S bubble is morphologically unstable at pressures above -1.23 bars. The 2S state being known to be radially unstable at pressures below -1.33 bars, the result leaves only a very narrow pressure range in which it can be found in a spherical configuration. Our stability analysis indicates that the 2S bubble is unstable against perturbations proportional to any of the third spherical harmonics Y(3m). Our numerical simulations show that there exist nonspherical stable configurations, such as the ones Maris and Konstantinov predicted for the 1P, 1D, and 2P electron bubbles and confirmed experimentally for the 1P. We believe that the 2S bubbles can also be produced and that our prediction will yield itself to experimental verification. 相似文献
1000.
It is believed that a disordered one-dimensional (1D) wire with coherent electronic conduction is an insulator with the mean resistance approximately equal e(2L/xi) and resistance dispersion Delta(rho) approximately equal e(L/xi), where L is the wire length and xi is the electron localization length. Here we show that this 1D insulator undergoes at full coherence the crossover to a 1D "metal," caused by thermal smearing and resonant tunneling. As a result, Delta(rho) is smaller than unity and tends to be L/xi independent, while grows with L/xi first nearly linearly and then polynomially, manifesting the so-called medium localization. 相似文献