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31.
32.
Petr Munster Tomas Horvath Josef Vojtech Ondrej Havlis Martin Slapak Pavel Skoda 《Fiber and Integrated Optics》2017,36(3):144-156
Currently, individual optical fibers are mostly used for each non-data application, which is very inefficient and uneconomical. Sharing a single fiber for multiple applications is a promising solution. However, in the case of a non-data application, the situation is much more complicated compared to data because of special application´s requirements. In laboratory setup, we performed a measurement with a standard G.652D optical fiber for analyzing possible interaction of stable frequency/accurate time transmission, 1.25/10Gbps data transmission (typical bitrates for access point-to-point networks), and high-power sensor signal for different channel spacing and different pulse duration of sensor signal. 相似文献
33.
Electrochemical properties and radical anions of carbocycle‐fluorinated quinoxalines and their substituted derivatives 下载免费PDF全文
Leonid A. Shundrin Irina G. Irtegova Nadezhda V. Vasilieva Pavel A. Avrorov Natalia Yu. Selikhova Arkady G. Makarov Alexander Yu. Makarov Yuri G. Slizhov Andrey V. Zibarev 《Journal of Physical Organic Chemistry》2017,30(8)
Electrochemical reduction (ECR) and oxidation (ECO) of 5,6,7,8‐tetrafluoroquinoxaline ( 1 ) and its derivatives bearing various substituents R (7‐H ( 2 ), 7,8‐H2 (3 ), 6‐CF3 ( 4 ), 6‐Cl ( 5 ), 5,7‐Cl2 ( 6 ), 5‐NH2 ( 7 ), 6‐OCH3 ( 8 ), 6,7‐(OCH3)2 ( 9 ), 6,7,8‐(OCH3)3 ( 10 ), 5,6,7,8‐(OCH3)4 ( 11 ), 6‐OCH3,7‐N(CH3)2 ( 12 ), 6‐N(CH3)2 ( 13 ), 6,7‐(N(CH3)2)2 ( 14 ), 5,6,7‐(N(CH3)2)3 ( 15 ), and 7,8‐cyclo‐(=CF‐CF = CF‐CF=) ( 16 )) in the carbocycle have been studied by cyclic voltammetry in MeCN. For 1 – 4 and 7 – 15 , the first reduction peaks have been found to be 1‐electron and reversible, thus corresponding to the formation of their radical anions (RAs), which are long lived at 295 K except those of 4 – 6 and 15 , 16 . Irreversible hydrodechlorination has been observed for 5 and 6 at the first step of their ECR confirmed by EPR detection of corresponding RAs of 2 and 5,7‐H2 derivative of 1 ( 17 ) at the next steps. Electrochemically generated RAs of 1 – 3 , 7 – 14 , and 17 have been characterized in MeCN by EPR spectroscopy together with DFT calculations at the (U)B3LYP/6‐31 + G(d) level of theory using PCM to describe the solvent. A noticeable alternation of spin density on the –NCCN– moiety of quinoxaline has been observed for all RAs possessing R‐substitution asymmetry. The comparative electron‐accepting ability of 1 – 15 has been analyzed in terms of their experimental reduction peak potentials and the (U)B3LYP/6‐31 + G(d)‐calculated gas‐phase first adiabatic electron affinities (EAs). The differences in electron transfer solvation energies for 1 – 15 have been evaluated on the basis of ECR peaks' potentials and calculated gas‐phase EAs. The ECO of 1 – 5 and 7 – 14 has been found to be irreversible. 相似文献
34.
We investigate the statistics of the numberN(R, S) of lattice pointsnZ
2, in an annular domain (R, w)=(R+w)A\RA, whereR, w>0. HereA is a fixed convex set with smooth boundary andw is chosen so that the area of (R, w) isS. The statistics comes fromR being taken as random (with a smooth density) in some interval [c
1
T,c
2,T],c
2>c
1>0. We find that in the limitT the variance and distribution of N=N(R; S)–S depend strongly on howS grows withT. There is a saturation regimeS/T, asT, in which the fluctuations in N coming from the two boundaries of are independent. Then there is a scaling regime,S/Tz, 0<z<, in which the distribution depends onz in an almost periodic way going to a Gaussian asz0. The variance in this limit approachesz for genericA, but can be larger for degenerate cases. The former behavior is what one would expect from the Poisson limit of a distribution for annuli of finite area. 相似文献
35.
Tavrov A Korablev O Ksanfomaliti L Rodin A Frolov P Nishikwa J Tamura M Kurokawa T Takeda M 《Optics letters》2011,36(11):1972-1974
To suppress starlight for direct exoplanet observation, we propose a common-path achromatic rotational-shearing coronagraph (CP-ARC), which is an interferocoronagraph with an angular-adjustable field rotator. The CP-ARC aims to maintain unwanted detection of stellar light, which can be suppressed incompletely by interference because of the finite diameter of the star. Compared to the previous interferocoronagraph, which had a nonadjustable 180° field rotation, the proposed CP-ARC can improve the coronagraphic contrast by several orders if the CP-ARC is combined with medium or large telescopes where the companion-star separation is optically resolved by more than a few Airy radii. The CP-ARC is made robust against mechanical disturbances due to the common-path interferometer principle. 相似文献
36.
Zeidler A Salmon PS Fischer HE Neuefeind JC Simonson JM Lemmel H Rauch H Markland TE 《Physical review letters》2011,107(14):145501
The method of oxygen isotope substitution in neutron diffraction is introduced as a site specific structural probe. It is employed to measure the structure of light versus heavy water, thus circumventing the assumption of isomorphism between H and D as used in more traditional neutron diffraction methods. The intramolecular and intermolecular O-H and O-D pair correlations are in excellent agreement with path integral molecular dynamics simulations, both techniques showing a difference of ?0.5% between the O-H and O-D intramolecular bond distances. The results support the validity of a competing quantum effects model for water in which its structural and dynamical properties are governed by an offset between intramolecular and intermolecular quantum contributions. 相似文献
37.
We report experiments on self-focusing of femtosecond diffraction-resistant vortex beams in water. These beams are higher-order Bessel beams with weak azimuthal modulation of the transverse intensity patterns. The modulation overrides the self-focusing dynamics and results in the formation of regular bottlelike filament distributions. The peak-power thresholds for filamentation, at a particular distance, are relatively accurately estimated by the adaptation of the Marburger formula derived earlier for Gaussian beams. The nonlinear conversion of the incident conical waves into the localized spatial wave packets propagating near the beam axis is observed. 相似文献
38.
A.M. Khvedelidze D.M. Mladenov H.-P. Pavel G. Röpke 《The European Physical Journal C - Particles and Fields》2002,24(1):137-141
The Hamiltonian reduction of classical SU(2) Yang–Mills field theory to the equivalent unconstrained theory of gauge invariant local dynamical variables is generalized
to the case of nonvanishing -angle. It is shown that for any -angle the elimination of the pure gauge degrees of freedom leads to a corresponding unconstrained non-local theory of self-interacting
second rank symmetric tensor fields, and that the obtained classical unconstrained gluodynamics with different -angles are canonically equivalent as on the original constrained level.
Received: 16 November 2001 / Published online: 5 April 2002 相似文献
39.
Zahorik P 《The Journal of the Acoustical Society of America》2002,111(4):1832-1846
In most naturally occurring situations, multiple acoustic properties of the sound reaching a listener's ears change as sound source distance changes. Because many of these acoustic properties, or cues, can be confounded with variation in the acoustic properties of the source and the environment, the perceptual processes subserving distance localization likely combine and weight multiple cues in order to produce stable estimates of sound source distance. Here, this cue-weighting process is examined psychophysically, using a method of virtual acoustics that allows precise measurement and control of the acoustic cues thought to be salient for distance perception in a representative large-room environment. Though listeners' judgments of sound source distance are found to consistently and exponentially underestimate true distance, the perceptual weight assigned to two primary distance cues (intensity and direct-to-reverberant energy ratio) varies substantially as a function of both sound source type (noise and speech) and angular position (0 degrees and 90 degrees relative to the median plane). These results suggest that the cue-weighting process is flexible, and able to adapt to individual distance cues that vary as a result of source properties and environmental conditions. 相似文献
40.
Vladimir Müller Pavel Pták Josef Tkadlec 《International Journal of Theoretical Physics》1992,31(5):843-854
LetL be a concrete (=set-representable) quantum logic. Letn be a natural number (or, more generally, a cardinal). We say thatL admits intrinsic coverings of the ordern, and writeL
C
n
, if for any pairA, BL we can find a collection {C
i
iI}, where cardI<n andC
i
L for anyiI, such thatA B=
il
C
i
. Thus, in a certain sense, ifLC
n
, then the rate of noncompatibility of an arbitrary pairA,BL is less than a given numbern. In this paper we first consider general and combinatorial properties of logics ofC
n
and exhibit typical examples. In particular, for a givenn we construct examples ofL
C
n+1\C
n
. Further, we discuss the relation of the classesC
n
to other classes of logics important within the quantum theories (e.g., we discover the interesting relation to the class of logics which have an abundance of Jauch-Piron states). We then consider conditions on which a class of concrete logics reduce to Boolean algebras. We conclude with some open questions. 相似文献