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41.
Palladium‐Catalyzed Stereoselective Intramolecular Oxidative Amidation of Alkenes in the Synthesis of 1,3‐ and 1,4‐Amino Alcohols and 1,3‐Diamines 下载免费PDF全文
Prof. Dr. Andrei V. Malkov Dr. Darren S. Lee Dr. Maciej Barłóg Dr. Mark R. J. Elsegood Prof. Dr. Pavel Kočovský 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(17):4901-4905
An efficient and practical Pd‐catalyzed intramolecular oxidative allylic amidation provides facile access to derivatives of 1,3‐ and 1,4‐amino alcohols and 1,3‐diamines. The method operates under mild reaction conditions (RT) with molecular oxygen (1 atm) as the sole reoxidant of Pd. Excellent diastereoselectivities were attained with substrates bearing a secondary stereogenic center 相似文献
42.
Interactions of DNA bases frequently involve the DNA base amino groups. In contrast to the empirical force fields, the ab initio calculations predict nonplanar DNA base amino groups. The same conclusion also follows from the density functional theory (DFT ) calculations. Both local and nonlocal density approximations were used. Optimized geometries of two other molecules with nonplanar amino groups (aniline, formamidine) are presented for comparison. The influence of nonplanar DNA base amino groups on the conformational variability of DNA is discussed. © 1996 John Wiley & Sons, Inc. 相似文献
43.
Pavel indel Dalibor Matula Jaroslav Hole
ek 《Journal of polymer science. Part A, Polymer chemistry》1996,34(11):2163-2171
The effect of a basic layer (SiO2—R3Al intermediate) in the one-phase silica supported titanium-based catalyst was investigated using the simple model catalyst systems obtained by reacting the activated silica gel consecutively with R3Al and TiCl4. Mode of the interaction of SiO2 with R3Al—resulting in the formation of the basic layer—was observed via analysis of the concentration of the unreacted OH groups on the silica surface employing IR spectroscopy and via analysis of the concentration of aluminium in solvent using AA spectroscopy. It was found that nature of the alkyl group in R3Al modified the structure of the basic layer, thus influencing the catalyst performance including the concentration of both the sum of Ti2+ and Ti3+ and the ESR-active Ti (III) centers. The sum of Ti2+ and Ti3+ ranged from 45 to 52 mol % and the amount of the ESR-active Ti (III) species ranged from 6 to 17 mol % of the all titanium content. A significant effect of alkyl group at organoaluminium compound on the molecular weight distribution of the resulting polymer was observed. © 1996 John Wiley & Sons, Inc. 相似文献
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Iqra Bano Pavel Horky Syed Qamar Abbas Muhammad Majid Akram Hafiz Muhammad Bilal Fawad Ali Tapan Behl Syed Shams ul Hassan Simona Bungau 《Molecules (Basel, Switzerland)》2022,27(7)
Ferroptosis is a recently described programmed cell death mechanism that is characterized by the buildup of iron (Fe)-dependent lipid peroxides in cells and is morphologically, biochemically, and genetically distinct from other forms of cell death, having emerged to play an important role in cancer biology. Ferroptosis has significant importance during cancer treatment because of the combination of factors, including suppression of the glutathione peroxidase 4 (Gpx4), cysteine deficiency, and arachidonoyl (AA) peroxidation, which cause cells to undergo ferroptosis. However, the physiological significance of ferroptosis throughout development is still not fully understood. This current review is focused on the factors and molecular mechanisms with the diagrammatic illustrations of ferroptosis that have a role in the initiation and sensitivity of ferroptosis in various malignancies. This knowledge will open a new road for research in oncology and cancer management. 相似文献
46.
We derive symplectically invariant uncertainty relations for a set of canonically conjugated variables. The uncertainty relations obtained are multimode analogs of the Robertson–Schrödinger inequalities. Our uncertainty relations are equivalent to the necessary and sufficient conditions for a matrix to be a correlation matrix of some quantum state, obtained by R. Simon and coauthors. The advantage of our inequalities, compared to that suggested by Simon, consists in its simplicity and more obvious symplectic invariance. We derive our inequalities for the case of a two-mode system in explicit form. Particular cases of small and large degrees of correlation between the first and second modes are analyzed in detail. 相似文献
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Karataev P Aryshev A Boogert S Howell D Terunuma N Urakawa J 《Physical review letters》2011,107(17):174801
We represent the first experimental observation of the point spread function (PSF) of optical transition radiation (OTR) performed at KEK-Accelerator Test Facility extraction line. We have demonstrated that the PSF vertical polarization component has a central minimum with a two lobe distribution. However, the distribution width varied significantly with wavelength. We assume that we observed a severe effect from spherical or chromatic aberrations which are not taken into account in any existing theoretical model. We believe that the result of this work will encourage theoreticians to continue developing the theory as it is important for various transition radiation applications. Nonuniform distribution of the OTR PSF creates an opportunity for developing a submicrometer transverse beam size monitor. 相似文献
49.
We calculate the effect of radial confinement on the Schwinger pair production rate by solving the Dirac equation in a flux-tube cylinder containing a constant chromoelectric field in the longitudinal direction. We show how the Dirac equation separates into radial and longitudinal equations for a mass term which has an arbitrary radial dependence and introduce radial confinement by having a finite mass inside the cylinder and an infinitely large mass outside. The resulting boundary conditions are equivalent to the MIT boundary condition. The equations are solved analytically for a constant quark mass inside the flux-tube, which acts like a waveguide. The discretization of the transverse wave vector which has a continuous spectrum in the non-confined case leads to a large suppression of the Schwinger pair-production rate for small radii. The minimal radius where pairs are created decreases with increasing field strength. The suppression turns out to be larger for heavier quarks than for light quarks. 相似文献