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排序方式: 共有319条查询结果,搜索用时 15 毫秒
21.
Jyoti Kannoujia Pavan Kumar Bangalore Srinivas Kantevari Prabhakar Sripadi 《Journal of mass spectrometry : JMS》2020,55(10)
The HPLC‐DAD and GC/MS methods were successfully used for the identification and characterization of the impurities in an agrochemical insecticide, bifenthrin technical. Three impurities ranging from 0.175%–0.541% were detected by the HPLC‐DAD method. The LC/MS technique with ESI or APCI source failed to detect the impurities detected by HPLC‐DAD, due to lack of ionization in ESI or APCI. The three impurities were enriched by prep‐HPLC, and then their structures were elucidated based on the GC/EIMS and CIMS data. The EI mass spectra of bifenthrin and its impurities displayed molecular ion and provided structure indicative fragment ions; the CIMS data further confirmed their molecular weight. The identity of the impurity 1 was further confirmed by the synthesis of the authentic sample followed by NMR and GC/MS data. 相似文献
22.
Potential of magnetic resonance spectroscopy to detect metastasis in axillary lymph nodes in breast cancer 总被引:5,自引:0,他引:5
Seenu V Pavan Kumar MN Sharma U Gupta SD Mehta SN Jagannathan NR 《Magnetic resonance imaging》2005,23(10):1005-1010
Focused pathological evaluation of axillary lymph nodes in breast cancer is gaining importance. Nuclear magnetic resonance (NMR) spectroscopy that assesses the whole of the specimen has the potential in evaluating micrometastases. The biochemical changes associated with breast cancer metastases in axillary nodes by in vitro NMR and its use in the detection of axillary metastases in a clinical setting in comparison with conventional histopathology is presented in this study. Eighty-eight lymph nodes obtained from 30 patients with breast cancer were investigated. Histopathology revealed metastases in 20 nodes from 11 patients, while in vitro NMR spectroscopy revealed metastases in 22 nodes. Out of these 22 nodes, 16 were the same, which showed metastases on histopathology, while 6 nodes have shown metastases only on in vitro magnetic resonance spectroscopy (MRS). These 6 nodes with suspicion of metastases on MRS were subjected to reevaluation with serial sectioning and immunohistochemistry, but no additional metastases were revealed. Forty metabolites could be identified from the MR spectrum of lymph nodes. The levels of the glycerophosphocholine-phosphocholine (GPC-PC), choline, lactate, alanine and uridine diphosphoglucose were elevated significantly in nodes with metastases. In addition, the intensity ratio of GPC-PC/threonine (Thr) was higher in nodes with metastases, and using this as marker, MRS detected the axillary metastases with a sensitivity, specificity and accuracy of 80%, 91% and 88%, respectively. Neoadjuvant chemotherapy (NACT) lowered the concentrations of GPC-PC and GPC-PC/Thr ratio. The accuracy of MRS in detecting metastases was 75% in patients who received NACT (n=9) as compared to 96% in those who did not (n=21). Our results demonstrate the potential of in vitro MRS in characterizing the metabolite profile of the axillary nodes with breast cancer metastases. It detected axillary metastases with reasonable accuracy and can be complementary to histopathological evaluation and immunohistochemistry. 相似文献
23.
Wiedeking M Tabor SL Pavan J Volya A Aguilar AL Calderin IJ Campbell DB Cluff WT Diffenderfer E Fridmann J Hoffman CR Kemper KW Lee S Riley MA Roeder BT Teal C Tripathi V Wiedenhöver I 《Physical review letters》2005,94(13):132501
Excited states in 20O were populated in the reaction 10Be(14C,alpha) at Florida State University (FSU). Charged particles were detected with a particle telescope consisting of 4 annularly segmented Si surface barrier detectors and gamma radiation was detected with the FSU gamma detector array. Five new states were observed below 6 MeV from the alpha-gamma and alpha-gamma-gamma coincidence data. Shell model calculations suggest that most of the newly observed states are core-excited 1p-1h excitations across the N=Z=8 shell gap. Comparisons between experimental data and calculations for the neutron-rich O and F isotopes imply a steady reduction of the p-sd shell gap as neutrons are added. 相似文献
24.
S. N. Liddick P. F. Mantica R. V.F. Janssens B. A. Brown M. P. Carpenter A. D. Davies M. Honma M. Horoi T. Mizusaki A. C. Morton W. F. Mueller T. Otsuka J. Pavan H. Schatz A. Stolz S. L. Tabor B. E. Tomlin M. Wiedeking 《The European physical journal. Special topics》2007,150(1):135-136
We have utilized the selective process of β decay to
populate low-energy excited states in the neutron-rich 22Ti,
23V, 24Cr, and 25Mn nuclei. The goal was to systematically
track the monopole shift of the νf5/2 single-particle
level with increased occupancy of the πf7/2 orbital.
The β-decay properties of the parent nuclides, along
with the low-energy structure of the daughters, are
presented and compared with the results of shell model calculations
employing the GXPF1 interaction. 相似文献
25.
Gianni Pavan 《Applied Acoustics》2010,71(11):991-993
26.
D. Bazzacco F. Brandoline K. Löwenich P. Pavan C. Rossi Alvarez M. De Poli A. M. I. Haque 《Hyperfine Interactions》1990,59(1-4):129-132
The g-factor of the first 2+ state in198Hg,200Hg and202Hg has been measured using the thin foil Transient Field technique. The values were calibrated to the known g-factor of the
first 5/2− state in199Hg. The levels were Coulomb excited by 217 MeV nickel ions with gadolinium acting as ferromagnetic medium. The obtained values
are rather constant and contradict a previously observed dip at200Hg. Two other g-factors have been remeasured in199Hg. 相似文献
27.
A convenient one-pot three-component approach for the synthesis of 2-C-branched O-glycosides has been developed from 2-nitroglycals. These 2-C-branched sugars have been shown to be precursors for a variety of biologically and synthetically relevant molecules. 相似文献
28.
V. Pavan 《Journal of statistical physics》2011,142(4):792-827
In this paper we extend the general construction of entropic approximation for kinetic operators modelling canonical systems.
More precisely, this paper aims at pursuing to thermalized systems the works of Levermore, Schneider and Junk on moments problems
relying on entropy minimization in order to construct BGK approximations and moments based equations. 相似文献
29.
The aim of this article is to construct a BGK operator for gas mixtures starting from the true Navier-Stokes equations. That is the ones having transport coefficients given by the hydrodynamical limit of the Boltzmann equation(s). Here the same hydrodynamical limit is obtained by introducing relaxation coefficients on certain moments of the distribution functions. Next the whole model is set by using entropy minimization under moments constraints. In our case the BGK operator allows to recover the exact Fick and Newton laws and satisfy the fundamental properties of the Boltzmann equations for inert gas mixtures. 相似文献