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61.
Absolute OH· concentrations and relative H-atom and O-atom profiles have been measured in a laminar, co-flowing methane/air diffusion flame burning at atmospheric pressure. Laser absorption and laser-induced fluorescence methods were used to probe the A
2 X
2IIitransition in OH·. The maximum OH· concentration is found to be 1.8±0.2 ×1016 cm–3 (mole fraction =5.0×10–3) at a temperature of 2080 K, which is twice the value calculated assuming local total equilibrium but less than half that predicted from partial equilibrium (O2+H2 2OH·). Multiphoton ionization (2+1 process at 243 nm) has been used to detect H atoms, while laser-induced fluorescence at 845 nm excited by two-photon absorption at 226 nm was employed to observe O atoms. In both cases it was found that low photon intensities (2×108W/cm2) and a retroreflected beam, Doppler-free geometry was required in order to avoid the photolytic production of the species of interest. For all of the concentration profile data it is necessary to correct the raw signals for variations in collisional quenching. In the case of the multiphoton ionization measurements the variation in electron detection sensitivity as a function of flame position must be accounted for as well. Establishing absolute H-atom and O-atom concentrations is discussed in terms of partial equilibrium considerations and detailed flame structure calculations.Formerly the National Bureau of Standards 相似文献
62.
Paul McGill 《Probability Theory and Related Fields》1989,83(3):355-389
Summary We study how Brownian motion behaves under time change by a fluctuating additive functionalA
t
, in particular letting be the first passage time ofA
t
to zero we computeP
–x[B
dy] explicitly in certain cases. The calculation is not an easy one, our method uses the Désiré André relation for the overshoot of a Lévy process and depends on some elliptic function identities. This paper only considers the one boundary case whereA
t
is increasing (resp. decreasing) on the positive (resp. negative) half line. 相似文献
63.
Dudley Paul Johnson 《Journal of Theoretical Probability》1989,2(4):433-436
We show that under suitable conditions $$\begin{gathered} E_x f\left\{ {a + \int_0^t \beta \left[ {b + \int_0^s {\alpha \left( {X_r } \right)dr, c + s, X_s } } \right]ds, b + \int_0^t {\alpha \left( {X_s } \right)ds, c + t, X_t } } \right\} \hfill \\ = e^{tG} f\left[ {a, b, c, x} \right] \hfill \\ \end{gathered} $$ whereX t is a Brownian motion andG is the generator of a (C 0) contraction semigroupe tG. 相似文献
64.
S. Bamidele Sanni H. Behm Paul T. Beurskens E. Kayode Adesogan James I. Durodola 《Journal of chemical crystallography》1988,18(5):575-582
A new cytotoxic macrocyclic diterpenoid named Japodagrol, C20H28O4, has been isolated from the ornamental plantJatropha podagrica, family Euphorbiaceae, grown in Nigeria. The structure of the title compound, C20H28O4, was solved by X-ray analysis.M
r
=332.44, monoclinic space groupC2,a=23.285(4),b=6.5105(12),c=12.505(3) Å,=98.504(17),V=1874.8 Å3,Z=4,D
c
=1.178 Mg/m3. CuK radiation (graphite crystal monochromator, =1.54184 A), (CuK)=6.13 cm–1,F(000)=720,T=290 K. Final conventionalR factor=0.035,R
w
=0.038 for 3349 observed reflections. The structure was solved with the programDirdif. The 5-membered ring is closed to a half-chair form. The compound contains inter- and intramolecular hydrogen bonds. 相似文献
65.
66.
S. Kushinsky J. Coyotupa K. Honda M. Hiroi K. Kinoshita M. Foote C. Chan R. Y. Ho W. Paul W. J. Dignam 《Mikrochimica acta》1970,58(3):491-503
Summary A gas Chromatographic method for the determination of estrone, estradiol and estriol in plasma of normal females is described. Purification is done by means of TLC of the free compounds and the acetates and quantitation is achieved by electron capture-gas chromatography of the estrogen heptafluorobutyrates. Experiments on the validation of the method are described along with some examples of its application.
Supported by USPHS Grants AM 09908 and RCDA 5 K 3-AM-31, 321 (S. K.) and a grant from the Ford Foundation. 相似文献
Zusammenfassung Eine gaschromatographische Methode zur Bestimmung von Östron, Östradiol und Östriol im normalen weiblichen Plasma wurde beschrieben. Die Reinigung erfolgte durch Dünnschichtchromatographie der freien Verbindungen und ihrer Acetate. Die quantitative Bestimmung wurde gaschromatographisch mit Hilfe eines Elektroneneinfangdetektors an Hand der Östrogenheptafluorobutyrate bewerkstelligt. Versuche zur Bewertung dieser Methode sowie Beispiele für ihre Anwendung wurden beschrieben.
Supported by USPHS Grants AM 09908 and RCDA 5 K 3-AM-31, 321 (S. K.) and a grant from the Ford Foundation. 相似文献
67.
Accreditation and Quality Assurance - 相似文献
68.
69.
70.
Let {ø n (dμ)} be a system of orthonormal polynomials on the unit circle with respect to a measuredμ. Szegö's theory is concerned with the asymptotic behavior ofø n (dμ) when logμ′∈L 1. In what follows we will discuss the asymptotic behavior of the ratioø n (dμ 2)/ø n (dμ 1) on the unit circle whendμ 1 anddμ 2 are close in a sense (e.g.,dμ 2=gdμ 1, where g≥0 is such thatQ(e it )g(t) andQ(e it )/g(t) are bounded for a suitable polynomialQ) and μ 1 ′ >0 almost everywhere or (a somewhat weaker requirement) lim n→∞Φ n (dμ 1,0)=0 for the monic polynomial Φ n . The asymptotic behavior of the same fraction outside the unit circle was discussed in an earlier paper. 相似文献