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31.
The detailed characterization of multifunctional hybrid organosilazane/organosilylamine telechelic oligomers by IR and 1H, 13C and 29Si NMR spectroscopy in one and two dimenions has been undertaken. The specific multifunctional oligomers, comprising NH/NH2 or SiCl functionalities depending on the monomer feed-ratio, were prepared from mono- and di-functionally reacted dichlorodimethylsilane (DDS) and mono-, di-, tri- and tetra-functionally reacted ethylenediamine (EDA). Varying the feed-ratio afforded control of the microstructures of the oligomers and the preparation of oligomers with, in some cases, conterminously located silicon–chlorine (SiCl) groups. The combination of the NMR methods with the IR technique has enabled the detailed microstructural characterization of the oligomers and the identification of the functionalities therein. This approach and the knowledge gained from the DDS/EDA system has been applied to the microstructural characterization of other hybrid organosilazane/silylamine preceramic telechelic oligomers. 相似文献
32.
Based on the SU(n)-algebra the Markoff master equation in discrete product space is reformulated to explicitly deal with composite systems. The resulting local (single node) and nonlocal (multi-node) state parameters allow a systematic approach to non-classical features of the state, like variance and covariance tensors. For local optical driving forces, inter-node interactions, and local damping channels the solution of the master equation is unraveled into stochastic quantum trajectories. Sampling leads to a joint distribution function in terms of those state parameters. Its linear moments define the ensemble-density matrix. The average variance and covariance are in terms of non-linear moments, which should be distinguished from their entirely statistical counterpairs. Non-classicality of the network dynamics is shown to reflect itself in the luminescence-photonstatistics. 相似文献
33.
34.
A Network Simulation of High-congestion Road-traffic Flows in Cities with Marine Container Terminals
James A. Pope Terry R. Rakes Loren Paul Rees Ingrid W. M. Crouch 《The Journal of the Operational Research Society》1995,46(9):1090-1101
Port cities where marine cargo terminals are located are generally near urban areas characterized by high-congestion road traffic. Changes in cargo traffic volumes into a marine terminal, or in the surrounding traffic arteries, which carry this traffic, can significantly affect the terminal's operations. Conversely, activity at the terminal can have an impact on the traffic levels and congestion for a considerable distance from the terminal. This paper demonstrates a methodology useful for studying the impact of road traffic flows on marine container terminals located in highly congested areas. This model was developed at the request of the Virginia Center for World Trade and was used to answer three planning questions in the port of Hampton Roads, Virginia, USA-what would be the impact of: opening a new section of interstate highway, a projected doubling of container traffic at one terminal, and a daily unit train in the vicinity of another terminal. The problem was made more challenging by limited data-collection funds. None the less, the model was deemed valid by a panel of traffic experts and officials from several major state and private agencies involved in marine traffic management. The model results were subsequently a factor in two major decisions related to terminal management. 相似文献
35.
Paul Howard 《Mathematical Logic Quarterly》2007,53(3):247-254
Two theorems are proved: First that the statement “there exists a field F such that for every vector space over F, every generating set contains a basis” implies the axiom of choice. This generalizes theorems of Halpern, Blass, and Keremedis. Secondly, we prove that the assertion that every vector space over ?2 has a basis implies that every well‐ordered collection of two‐element sets has a choice function. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
36.
Katharina Habermann Lutz Habermann Paul Rosenthal 《Calculus of Variations and Partial Differential Equations》2007,30(2):137-152
A Yang–Mills theory in a purely symplectic framework is developed. The corresponding Euler–Lagrange equations are derived
and first integrals are given. We relate the results to the work of Bourgeois and Cahen on preferred symplectic connections. 相似文献
37.
We study (relative) zeta regularized determinants of Laplace type operators on compact conic manifolds. We establish gluing formulae for relative zeta regularized determinants. For arbitrary self-adjoint extensions of the Laplace-Beltrami operator, we express the relative ζ-determinants for these as a ratio of the determinants of certain finite matrices. For the self-adjoint extensions corresponding to Dirichlet and Neumann conditions, the formula is particularly simple and elegant. 相似文献
38.
Differential algebraic equations with after-effect 总被引:4,自引:0,他引:4
C. T. H. Baker C. A. H. Paul H. Tian 《Journal of Computational and Applied Mathematics》2002,140(1-2):63-80
In this paper, we are concerned with the solution of delay differential algebraic equations. These are differential algebraic equations with after-effect, or constrained delay differential equations. The general semi-explicit form of the problem consists of a set of delay differential equations combined with a set of constraints that may involve retarded arguments. Even simply stated problems of this type can give rise to difficult analytical and numerical problems. The more tractable examples can be shown to be equivalent to systems of delay or neutral delay differential equations. Our purpose is to highlight some of the complexities and obstacles that can arise when solving these problems, and to indicate problems that require further research. 相似文献
39.
40.
The engineering of many modern electronic devices demands control over a crystal down to the thickness of a single layer of atoms—and future demands will be even more challenging. Such control is achieved by the method of crystal growth known as epitaxy, and that makes this method the subject of intense study. More than that, recent advances are revolutionizing our knowledge of how surfaces grow. In fact, growing surfaces show a beautifully rich variety of phenomena, many of which are only now beginning to be uncovered. In the past few years many surface imaging techniques have been used to give us a close look at how crystals grow—while they are growing. The purpose of this article will be to illustrate some of the ways real surfaces grow and change as revealed by some of the latest in situ microscopic imaging technologies.
It is often said that crystal growth is more of an art than a science. Here we will show that it is emphatically both. 相似文献