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101.
Claude Didierjean Julien Marin Emmanuel Wenger Jean‐Paul Briand Andr Aubry Gilles Guichard 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(3):o200-o203
X‐ray studies reveal that tert‐butyl (6S)‐6‐isobutyl‐2,4‐dioxopiperidine‐1‐carboxylate occurs in the 4‐enol form, viz. tert‐butyl (6S)‐4‐hydroxy‐6‐isobutyl‐2‐oxo‐1,2,5,6‐tetrahydropyridine‐1‐carboxylate, C14H23NO4, when crystals are grown from a mixture of dichloromethane and pentane, and has an axial orientation of the isobutyl side chain at the 6‐position of the piperidine ring. Reduction of the keto functionality leads predominantly to the corresponding β‐hydroxylated δ‐lactam, tert‐butyl (4R,6S)‐4‐hydroxy‐6‐isobutyl‐2‐oxopiperidine‐1‐carboxylate, C14H25NO4, with a cis configuration of the 4‐hydroxy and 6‐isobutyl groups. The two compounds show similar molecular packing driven by strong O—H⋯O=C hydrogen bonds, leading to infinite chains in the crystal structure. 相似文献
102.
Walter D. Neumann Paul Norbury 《Transactions of the American Mathematical Society》2003,355(2):519-538
We show that although the fundamental group of the complement of an algebraic affine plane curve is not easy to compute, it possesses a more accessible quotient, which we call the Orevkov invariant.
103.
Nathan S. Feldman Paul McGuire 《Proceedings of the American Mathematical Society》2003,131(6):1793-1801
In this paper we show that the spectral picture of an irreducible subnormal operator may be arbitrarily prescribed subject only to certain natural necessary conditions. This completes work begun by the second author.
104.
105.
106.
Earth-orbiting spacecraft often contain solar arrays or antennas supported by a preloaded mast. Due to weight and cost considerations, the supporting structures of the spacecraft appendages are made extremely light and flexible. Therefore, it is essential to investigate the influence of all physical and structural parameters on the dynamic behavior of the overall structure. The governing equation of motion and its general solution for the preloaded mast are developed. Furthermore, the mass moment of inertia of the mast subjected to bending vibrations is included in the governing equation of motion to investigate its influence on determining the circular frequencies. To verify the developed formulations, a finite element technique was implemented. The accuracy and limitation of the technique on calculating the circular frequencies are discussed. Although the study described in this paper primarily focuses on the mast for the space station solar arrays, the developed formulations and techniques can be applied to any large and flexible beam in zero gravity. 相似文献
107.
108.
109.
Dan Archdeacon C. Paul Bonnington Joanna A. Ellis-Monaghan 《Discrete and Computational Geometry》2007,38(3):573-594
Steinitz's theorem states that a graph is the 1-skeleton of a convex polyhedron if and only if it is 3-connected and
planar. The polyhedron is called a geometric realization of the embedded graph. Its faces are bounded by convex polygons whose
points are coplanar. A map on the torus does not necessarily have such a geometric realization. In this paper we relax the
condition that faces are the convex hull of coplanar points. We require instead that the convex hull of
the points on a face can be projected onto a plane so that the boundary of the convex hull of the projected points is the
image of the boundary of the face. We also require that the interiors of the convex hulls of different faces do not intersect.
Call this an exhibition of the map. A map is polyhedral if the intersection of any two closed faces is simply connected. Our
main result is that every polyhedral toroidal map can be exhibited. As a corollary, every toroidal triangulation has a geometric
realization. 相似文献
110.
J. A. Ratto Paul T. Inglefield R. A. Rutowski K.-L. Li Alan Anthony Jones Ajoy K. Roy 《Journal of Polymer Science.Polymer Physics》1987,25(7):1419-1430
Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C2D2Cl4 from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications. 相似文献