全文获取类型
收费全文 | 162篇 |
免费 | 12篇 |
国内免费 | 3篇 |
专业分类
化学 | 116篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 20篇 |
物理学 | 35篇 |
出版年
2023年 | 6篇 |
2022年 | 5篇 |
2021年 | 1篇 |
2020年 | 7篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 9篇 |
2014年 | 8篇 |
2013年 | 10篇 |
2012年 | 11篇 |
2011年 | 12篇 |
2010年 | 5篇 |
2009年 | 6篇 |
2008年 | 8篇 |
2007年 | 9篇 |
2006年 | 14篇 |
2005年 | 11篇 |
2004年 | 7篇 |
2003年 | 4篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1998年 | 1篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 7篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有177条查询结果,搜索用时 15 毫秒
171.
Jianyu Wang Pusheng Liu Mercedes Boronat Pau Ferri Zhaoguo Xu Peng Liu Baojian Shen Zhendong Wang Jihong Yu 《Angewandte Chemie (International ed. in English)》2020,59(39):17225-17228
Zeolite Y, with a high SiO2/Al2O3 ratio (SAR), plays an important role in fluidized catalytic cracking processes. However, in situ synthesis of zeolite Y with high SARs remains a challenge because of kinetic limitations. Here, zeolite Y with an SAR of 6.35 is synthesized by a hydroxyl radical assisted route. Density‐functional theory (DFT) calculations suggest that hydroxyl radicals preferentially enhanced the formation of Si‐O‐Si bonds, thus leading to an increased SAR. To further increase the SAR, a dealumination process was carried out using citric acid, with a subsequent second‐step hydrothermal crystallization, giving an SAR of up to 7.5 while maintaining good crystallinity and high product yield. The resultant zeolite Y shows good performance in cumene cracking. Introduced here is a new strategy for synthesizing high SAR zeolite Y, which is widely used in commercial applications. 相似文献
172.
Let μ be a nonnegative Borel measure on the unit disk of the complex plane. We characterize those measures μ such that the general family of spaces of analytic functions, F(p, q, s), which contain many classical function spaces, including the Bloch space, BMOA and the Q s spaces, are embedded boundedly or compactly into the tent-type spaces ${T^{\infty}_{p, s}(\mu)}$ . The results are applied to characterize boundedness and compactness of Riemann–Stieltjes operators and multiplication operators on F(p, q, s). 相似文献
173.
We show how to construct low energy solutions to the Randall-Sundrum II (RSII) model by using an associated five-dimensional anti-de Sitter space (AdS(5)) and/or four-dimensional conformal field theory (CFT(4)) problem. The RSII solution is given as a perturbation of the AdS(5)-CFT(4) solution, with the perturbation parameter being the radius of curvature of the brane metric compared to the AdS length ?. The brane metric is then a specific perturbation of the AdS(5)-CFT(4) boundary metric. For low curvatures the RSII solution reproduces 4D general relativity on the brane. Recently, AdS(5)-CFT(4) solutions with a 4D Schwarzschild boundary metric were numerically constructed. We modify the boundary conditions to numerically construct large RSII static black holes with radius up to ~20?. For a large radius, the RSII solutions are indeed close to the associated AdS(5)-CFT(4) solution. 相似文献
174.
Sara S. KuwaharaJoel L. Cuello Graham MyhreStanley Pau 《Optics and Lasers in Engineering》2011,49(3):434-438
Red and blue lasers, holding promise as an electric light source for photosynthetic systems on account of being true monochromatic, high-power, and having high electrical-conversion efficiency, were employed in growing a green alga, Chlamydomonas reinhardtii. The laser treatments tested included: 655-nm Red; 680-nm Red; 655-nm Red+474-nm Blue and 680-nm Red+474-nm Blue. A white cold cathode lamp with spectral output similar to that of white fluorescent lamp served as control. C. reinhardtii successfully grew and divided under the 655 and 680-nm red lasers as well as under the white-light control. Supplementing either red with blue laser, however, resulted in increased algae cell count that significantly exceeded those under both red lasers and the white-light control on average by 241%. 相似文献
175.
176.
Adrián Fontana-Escartín Karima El Hauadi Sonia Lanzalaco Maria M. Pérez-Madrigal Elaine Armelin Pau Turon Carlos Alemán 《Macromolecular bioscience》2023,23(9):2300024
Virtually, all implantable medical devices are susceptible to infection. As the main healthcare issue concerning implantable devices is the elevated risk of infection, different strategies based on the coating or functionalization of biomedical devices with antiseptic agents or antibiotics are proposed. In this work, an alternative approach is presented, which consists of the functionalization of implantable medical devices with sensors capable of detecting infection at very early stages through continuous monitoring of the bacteria metabolism. This approach, which is implemented in surgical sutures as a representative case of implantable devices susceptible to bacteria colonization, is expected to minimize the risk of worsening the patient's clinical condition. More specifically, non-absorbable polypropylene/polyethylene (PP/PE) surgical sutures are functionalized with conducting polymers using a combination of low-pressure oxygen plasma, chemical oxidative polymerization, and anodic polymerization, to detect metabolites coming from bacteria respiration. Functionalized suture yarns are used for real-time monitoring of bacteria growth, demonstrating the potential of this strategy to fight against infections. 相似文献
177.