(Pressure + volume + temperature) properties for binary oligomeric solutions of poly(ethylene glycol mono-4-octylphenyl ether) with 1-octanol or acetophenone at pressures up to 50 MPa

Densities were measured with a high-pressure densitometer for two binary oligomeric systems of poly(ethylene glycol mono-4-octylphenyl ether) (PEGOPE) with 1-octanol or acetophenone at temperatures from 298.15 K to 348.15 K and pressures up to 50 MPa. While the excess volumes are negative in (acetophenone + PEGOPE) over the entire composition range, those are found to change from positive to negative with increasing mole fraction of the solvent in (1-octanol + PEGOPE). The pressure-effect on the liquid densities can be represented accurately by the Tait equation. Moreover, an empirical equation with two characteristic parameters correlates well the PVT data over the entire experimental conditions for each binary system. The experimental specific volumes were also correlated with the Flory–Orwoll–Vrij (FOV) and the Schotte equations of state to within the experimental uncertainty.     

Contractible subgraphs, Thomassen’s conjecture and the dominating cycle conjecture for snarks

We show that the conjectures by Matthews and Sumner (every 4-connected claw-free graph is Hamiltonian), by Thomassen (every 4-connected line graph is Hamiltonian) and by Fleischner (every cyclically 4-edge-connected cubic graph has either a 3-edge-coloring or a dominating cycle), which are known to be equivalent, are equivalent to the statement that every snark (i.e. a cyclically 4-edge-connected cubic graph of girth at least five that is not 3-edge-colorable) has a dominating cycle.We use a refinement of the contractibility technique which was introduced by Ryjá?ek and Schelp in 2003 as a common generalization and strengthening of the reduction techniques by Catlin and Veldman and of the closure concept introduced by Ryjá?ek in 1997.     

Development and Validation of an LC–ESI-MS Ion-Trap Method for Analysis of Impurities in Transkarbam 12, a Novel Transdermal Accelerant

A new, sensitive LC–MS method for evaluation of the purity of Transkarbam 12 (T12), a novel and highly effective accelerant of transdermal penetration, has been developed and validated. T12 and its impurities (6-aminohexanoic acid, AH, ε-caprolactam, CA, and dodecyl 6-(6-aminohexanamido)hexanoate, DAH) were characterized by MS and MS–MS analysis. Separation was achieved on a 150 mm × 3 mm, 5-μm particle, phenyl–hexyl column. The mobile phase was a gradient prepared from water, formic acid, and acetonitrile. The method was validated within the concentration range 50–250 ng mL^?1; correlation coefficients were >0.998. The accuracy of the method was from 98.6–105.0% for AH, 102.6–104.8% for CA, and 97.9–100.9% for DAH. Precision was in the range 3.19–4.42% for AH, 3.22–5.81% for CA, and 4.8–8.78% for DAH. The selectivity of the method and sample stability were also confirmed. The practical applicability of the method was proven by analysis of T12 bulk substance.     

Relative acidities and structure analysis of cis and trans isomers of 1,5‐oxazaspiro[5.5] undecane derivatives by multinuclear magnetic resonance

The relative acidities of the cis and trans isomers of a series of 1,5‐oxazaspiro[5.5]undecane derivatives were determined by measuring ΔpK in acid‐base titrations followed by ¹ H NMR. Relative structural stabilities were determined by measuring substituent chemical shift and γ‐gauche effects in ¹³C, ¹⁵N, and ¹⁷O NMR. Crystallographic characterization of a model spiro[5.5]undecane is presented to support the basicity in solid state. Copyright © 2010 John Wiley & Sons, Ltd.     

Field‐effect transistors based on PPV derivatives as a semiconducting layer

A series of modified thiophene groups containing PPV‐based semiconducting materials, poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(2,2′bithienylenevinylene)] ( PPBT ), poly[(2,5‐bis(octyloxy)‐1,4‐phenylenevinylene)‐alt‐(5,5‐thiostilylenevinylene)] ( PPTVT ), have been synthesized through a Horner coupling reaction. From the FTIR and ¹H NMR spectroscopy, the configuration of the vinylene groups in the polymers was all trans (E) geometry. The weight‐average molecular weights (M_w) of PPBT and PPTVT were found to be 11,700 and 11,800, with polydispersity indices of 2.51 and 2.53, respectively. PPBT and PPTVT thin films exhibit UV–visible absorption maxima at 538 and 558 nm, respectively, and the strong absorption shoulder peaks at 578 and 602 nm, respectively. Solution processed field‐effect transistors (FET) fabricated using all the polymers showed p‐type OTFT characteristics. The field‐effect mobility of the PPTVT was obtained up to 2.3 × 10^?3 cm² V^?1 s^?1, an on/off ratio of 1.0 × 10⁵ with ambient air stability. Studies of the atomic force microscopy (AFM) and X‐ray diffraction (XRD) analysis of the polymer thin films revealed that all the polymers were amorphous structure. The greater planarity and rigidity of PPTVT compared to PPBT results in elongation of conjugation length and better π–π stacking of polymer chains in amorphous region, which leads to improved FET performance. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 111–120, 2009     

Molecular design,synthesis, and properties of Y‐type nonlinear optical polyester containing tricyanovinylthiophene with enhanced thermal stability of second harmonic generation

1‐{3,4‐Di‐(2‐hydroxyethoxy)phenyl}‐2‐(2‐thiophenyl)ethene (5) was prepared and condensed with terephthaloyl chloride to yield polyester (6). Polymer 6 was reacted with tetracyanoethylene to give a new Y‐type polyester (7) containing 1‐(3,4‐dioxyethoxy)phenyl‐2‐{5‐(2,2,3‐tricyanovinyl)‐2‐thiophenyl)}ethenyl groups as NLO‐chromophores, which are components of the polymer backbones. Polyester 7 is soluble in common organic solvents such as N,N‐dimethylformamide and acetone. Polymer 7 showed a thermal stability up to 300 °C in thermogravimetric analysis with glass transition temperature (T_g) obtained from differential scanning calorimetry near 126 °C. The second harmonic generation (SHG) coefficient (d₃₃) of poled polymer film at the 1560 nm fundamental wavelength was around 6.57 × 10^?9 esu. The dipole alignment exhibited high thermal stability up to the T_g, and there was no SHG decay below 125 °C due to the partial main‐chain character of polymer structure, which is acceptable for NLO device applications. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1911–1919, 2009     

Studies on organo-phosphorus, -arsenic,and -antimony polytungstates and polymolybdates: V. Syntheses and structures of benzylarsonic polymolybdates

In order to investigate the influence of organic groups on the structural types of organoarsenic polymolybdates, benzylarsonic acid has been selected to react with sodium molybdate. Three new complexes have been synthesized and characterized: [C(NH₂)₃]₄ [(C₆H₅CH₂As)₂Mo₆O₂₄] (1), Cs₄[(C₆H₅CH₂AS)₂Mo₆O₂₄]·5H₂O ( 2 ) and [(n-C₄H₉)₄N]₃Na[(C₆H₅CH₂As)₂Mo₆O₂₄] · 6H_aO( 3 ). Molecular structure of compound 1 has been determined by means of single-crystal X-ray diffraction studies. It is monoclinic, space group P 2 ₁/n with cell dimensions of a = 12 . 342( 2 ), b = 18.621( 2 ), c = 10.042( 2 )Å, β = 105.80(1)°, V = 2220.5 ų, z = 2, μ = 15.854 cm^?1, R = 0.023. It is demonstrated that the structural types of benzylarsonic polymolybdates are the same as those for alkylarsonic polymolybdates but different from those for arylarsonic polymolybdates. Their elemental analyses, IR and UV spectra and electrochemical behaviors in aqueous solution have been reported. It is suggested that the arsenic—carbon bond has great influence on the structural types of organoarsenic polymolybdates.     

Spatial inhomogeneity of the interaction between bistable ferromagnetic wires

An experimental study and a theoretical calculation are presented of the hysteresis loop of two bistable ferromagnetic wires. A new effect—an asymmetry of the shift of the switching field at the first and the second Barkhausen jump—is found experimentally. The effect is explained as a consequence of the spatial dependence of the stray field. It is also reproduced within our recent calculation of the stray field from the magnetisation profile. Theoretical results qualitatively agree with the experimental data.     

Removal of acidic dyestuffs in aqueous solution by nanofiltration

Separation of acidic dyestuffs, including Acid red 4, Acid orange 10, and Acid red 27, from aqueous solution by nanofiltration (NF) was shown to be a feasible process to accomplish an effective removal over a broad operational range. For most experiments conducted in this study, dyestuff rejections of greater than 98% were achieved. The permeate flux for experiments conducted with various dyestuffs was increased with increasing operating pressure and solution temperature. The permeability was increased and the rejection of dyestuffs was slightly decreased with increasing cross-flow velocity of solution. The effect of solution pH on the rejection of dyestuff was elucidated by the electrostatic characteristics between the species of dyestuff and the membrane surface. Maximum permeability was obtained for experiments operated in aqueous solution of pH 5, which was close to the isoelectric point of the membrane.