首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   686篇
  免费   16篇
  国内免费   2篇
化学   516篇
晶体学   1篇
力学   22篇
数学   114篇
物理学   51篇
  2024年   1篇
  2023年   1篇
  2022年   9篇
  2021年   22篇
  2020年   11篇
  2019年   13篇
  2018年   19篇
  2017年   5篇
  2016年   21篇
  2015年   18篇
  2014年   18篇
  2013年   41篇
  2012年   39篇
  2011年   47篇
  2010年   40篇
  2009年   28篇
  2008年   45篇
  2007年   39篇
  2006年   33篇
  2005年   34篇
  2004年   34篇
  2003年   27篇
  2002年   17篇
  2001年   5篇
  2000年   14篇
  1999年   12篇
  1998年   9篇
  1997年   11篇
  1996年   10篇
  1995年   8篇
  1994年   4篇
  1993年   8篇
  1992年   6篇
  1991年   4篇
  1990年   3篇
  1989年   4篇
  1988年   4篇
  1987年   1篇
  1986年   3篇
  1985年   5篇
  1984年   7篇
  1983年   5篇
  1982年   5篇
  1981年   2篇
  1980年   3篇
  1979年   2篇
  1978年   2篇
  1977年   3篇
  1975年   1篇
  1973年   1篇
排序方式: 共有704条查询结果,搜索用时 343 毫秒
101.
A novel nickel beta-diketonate adduct, Ni(tta)2.tmeda, has been synthesized using 2-thenoyltrifluoroacetone as the beta-diketonate and N,N,N,'N'-tetramethylethylendiamine as the Lewis base. It has been characterized by elemental analyses, IR, 1H NMR, 13C NMR spectroscopy and single-crystal X-ray diffraction studies. Physical and thermal properties of Ni(tta)2.tmeda precursor have been also extensively investigated. Its efficacy as a metal-organic chemical vapour deposition (MOCVD) precursor for the growth of nickel oxide films has been fully tested by applying it to the deposition of NiO films on quartz substrate. NiO thin films have been characterized by X-ray diffraction (XRD), scanning electron microscopy and UV spectroscopy.  相似文献   
102.
Twelve finds from archaeological excavations carried out in the Aosta region (Italy) were studied by scanning electron microscopy coupled with energy-dispersive X-ray detection (SEM–EDS). The archaeological samples were shards of glazed pottery dating from the fourth to the seventh century AD. Analysis of ceramic bodies revealed a general homogeneity in composition among the studied samples and the use of a noncalcareous clay for their manufacture; however, two shards stand out due to their high iron contents. Glazes proved to be high-lead products with more than 70% PbO in all of the samples investigated but one. For the latter, a composition poorer in lead and richer in silicon, aluminium and iron was found. SEM observation of the contact region between body and glaze suggests that the vitreous coatings were mostly obtained by applying the glazing components onto the unfired clay body; moreover, a comparison between clay and glaze compositions suggests the use of a lead compound mixed with a silica-rich material, not a lead compound by itself.  相似文献   
103.
104.
Highly selective enzymatic reductions of aldehydes to the corresponding alcohols was performed using an E. coli JM109 whole cell biocatalyst. A selective enzymatic method for the reduction of aldehydes could provide an eco-compatible alternative to chemical methods. The simplicity, fairly wide scope and the very high observed chemoselectivity of this approach are its most unique features.  相似文献   
105.
Blood oxygenation level dependent (BOLD) response related to interictal activity was evaluated in a patient with post-traumatic focal epilepsy at repeated continuous electroencephalogram (EEG)-functional magnetic resonance imaging examinations. Lateralized interictal EEG activity induced a main cluster of activation co-localized with the anatomical lesion. Spreading of EEG interictal activity to both frontal lobes evoked bilateral clusters of activation indicating that topography of BOLD response might depend on the spatial distribution of epileptiform activity.  相似文献   
106.
Ketogenic diets (KDs) have been applied in the therapy of paediatric epilepsy for nearly a century. Recently, beneficial results have also been reported on metabolic disorders and neurodegeneration, designating aged individuals as possible recipients. However, KDs efficacy decrease after the suckling period, and very little is known about their impact on the aging brain. In the present study, the effect on the neuronal energetic supply of a KD containing 20% of medium chain triglycerides (MCT) was investigated in Purkinje cells of the cerebellar vermis of late-adult (19-month-old) rats. The animals were fed with the KD for 8 weeks, and succinic dehydrogenase (SDH) activity was cytochemically determined. The following parameters of SDH-positive mitochondria were evaluated by the use of a computer-assisted image analysis system connected to a transmission electron microscope: numeric density (Nv), average volume (V), volume density (Vv), and cytochemical precipitate area/mitochondrial area (R). Young, age-matched, and old animals fed with a standard chow were used as controls. We found significantly higher Nv in MCT-KD-fed rats vs. all the control groups, in young vs. late-adult and old controls, and in late-adult vs. old controls. V and Vv showed no significant differences among the groups. R was significantly higher in MCT-KD-fed rats vs. all the control animals, and in old vs. young and late-adult controls. Present data indicate that the ketogenic treatment counteracted age-related decrease in numeric density of SDH-positive mitochondria, and enhanced their metabolic efficiency. Given the central role of mitochondrial impairment in age-related physio-pathological changes of the brain, these findings may represent a starting point to examine novel potentialities for KDs.  相似文献   
107.
108.
109.
Let ${(\Omega, \mathcal{F}, P)}$ be a probability space. For each ${\mathcal{G}\subset\mathcal{F}}$ , define ${\overline{\mathcal{G}}}$ as the σ-field generated by ${\mathcal{G}}$ and those sets ${F\in \mathcal{F}}$ satisfying ${P(F)\in\{0,1\}}$ . Conditions for P to be atomic on ${\cap_{i=1}^k\overline{\mathcal{A}_i}}$ , with ${\mathcal{A }_1,\ldots,\mathcal{A}_k\subset\mathcal{F}}$ sub-σ-fields, are given. Conditions for P to be 0-1-valued on ${\cap_{i=1}^k \overline{\mathcal{A}_i}}$ are given as well. These conditions are useful in various fields, including Gibbs sampling, iterated conditional expectations and the intersection property.  相似文献   
110.
This paper addresses integer programming problems under probabilistic constraints involving discrete distributions. Such problems can be reformulated as large scale integer problems with knapsack constraints. For their solution we propose a specialized Branch and Bound approach where the feasible solutions of the knapsack constraint are used as partitioning rules of the feasible domain. The numerical experience carried out on a set covering problem with random covering matrix shows the validity of the solution approach and the efficiency of the implemented algorithm.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号