全文获取类型
收费全文 | 560篇 |
免费 | 23篇 |
专业分类
化学 | 424篇 |
力学 | 11篇 |
数学 | 56篇 |
物理学 | 92篇 |
出版年
2024年 | 2篇 |
2023年 | 4篇 |
2022年 | 9篇 |
2021年 | 12篇 |
2020年 | 16篇 |
2019年 | 10篇 |
2018年 | 7篇 |
2017年 | 7篇 |
2016年 | 13篇 |
2015年 | 20篇 |
2014年 | 19篇 |
2013年 | 42篇 |
2012年 | 43篇 |
2011年 | 57篇 |
2010年 | 33篇 |
2009年 | 30篇 |
2008年 | 42篇 |
2007年 | 33篇 |
2006年 | 36篇 |
2005年 | 20篇 |
2004年 | 12篇 |
2003年 | 12篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 5篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1971年 | 2篇 |
1967年 | 1篇 |
排序方式: 共有583条查询结果,搜索用时 15 毫秒
61.
Six derivatives ( 1 , 2 , 3 , 4 , 5 , 6 ) of 2‐phenyl‐1H‐imidazole were tested as catalysts of Henry reaction. Three new ( 4 , 5 , 6 ) 2‐phenyl‐1H‐imidazole derivatives, differently substituted (thio)ureas, were synthesized and determined by 1H NMR and IR spectroscopy and elemental analysis. Two types of catalysis, homogeneous and heterogeneous, were examined and compared. Clay minerals Ca‐MMT and Cu‐MMT were used as solid supports for heterogeneous catalysis. The best results were obtained using compound 2 under conditions of heterogeneous method D from the point of view of yield and reaction time. J. Heterocyclic Chem., (2011) 相似文献
62.
Highly ordered mixed V(2)O(5)-TiO(2) nanotubes can be formed by self-organizing anodization of Ti-V alloys with vanadium content of up to 18 at%. In the resulting oxide nanotube arrays, the vanadium is electrochemically switchable leading to a specific capacitance that can reach up to 220 F g(-1) and an energy density of 19.56 Wh kg(-1) with perfect reversibility and long-term stability. Thus these mixed oxide nanotubes may be considered as a promising candidate for supercapacitors. 相似文献
63.
Shanshan Qin Nikita Denisov Hyesung Kim Prof. Patrik Schmuki 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(10):e202316660
When using single atoms (SAs) as a co-catalyst in photocatalytic H2 generation, achieving a well-dispersed, evenly distributed and adjustable SA surface density on a semiconductor surface is a challenging task. In the present work we use the planar adsorption of tetrakis-(4-carboxyphenyl)-porphyrin (TCPP) and its platinum coordinated analogue, Pt-TCPP, onto anatase TiO2 surfaces to establish a spatially controlled decoration of SAs. We show that the surface Pt SA density can be very well controlled by co-adsorption of Pt-TCPP and TCPP in the planar monolayer regime, and by adjusting the Pt-TCPP to TCPP ratio a desired well dispersed surface density of SAs up to 2.6×105 atoms μm−2 can be established (which is the most effective Pt SA loading for photocatalysis). This distribution and the SA state are maintained after a thermal treatment in air, and an optimized SA density as well as a most active form of Pt for photocatalytic H2 evolution can be established and maintained. 相似文献
64.
Kolar Tjaša Mušič Branka Korošec Romana Cerc Kokol Vanja 《Cellulose (London, England)》2021,28(14):9441-9460
Cellulose - Differently structured aluminum (tri/mono) hydroxide (Al(OH)3 /AlO(OH)) nanoparticles were prepared and used as thermal-management additives to microfibrillated cellulose (MFC),... 相似文献
65.
66.
Elke Baum Patrik Dahlke Volker Kaiser Michel Molinier Roland E. Schmidt Jürgen Pebler Werner Massa Dietrich Babel 《无机化学与普通化学杂志》2006,632(14):2244-2250
67.
68.
Hellmut Haberland Bernd von Issendorff Ji Yufeng Thomas Kolar Gregor Thanner 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1993,26(1):8-12
The change of the cohesive energy and the optical absorption spectra of small singly sized Hg clusters is discussed. The cohesive energy allows one to determine the different regimes of chemical bonding. The optical spectra show an abrupt transition to a collective, plasmon-like absorption as a function of increasing cluster size. The position of the one plasmon peak is: 1) independent of the charge state, 2) nearly independent of cluster size, and 3) agrees with that of the classical Mie plasmon calculated from the experimental dielectric constants. The width of the plasmon peaks is discussed. A strong influence of electronic correlations on the cluster size dependence of the oscillator strength is observed. 相似文献
69.
We theoretically introduce a mesoscopic pendulum from a triple dot. The pendulum is fastened through a singly occupied dot (spin qubit). Two other strongly capacitively coupled islands form a double-dot charge qubit with one electron in excess oscillating between the two low-energy charge states (1,0) and (0,1). The triple dot is placed between two superconducting leads. Under realistic conditions, the main proximity effect stems from the injection of resonating singlet (valence) bonds on the triple dot. This gives rise to a Josephson current that is charge- and spin-dependent and, as a consequence, exhibits a distinct resonance as a function of the superconducting phase difference. 相似文献
70.