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481.
Johansson P 《Physical chemistry chemical physics : PCCP》2007,9(12):1493-1498
New lithium salts for non-aqueous liquid, gel and polymeric electrolytes are crucial due to the limiting role of the electrolyte in modern lithium batteries. The solvation of any lithium salt to form an electrolyte solution ultimately depends on the strength of the cation-solvent vs. the cation-anion interaction. Here, the latter is probed via HF, B3LYP and G3 theory gas-phase calculations for the dissociation reaction: LiX <--> Li(+) + X(-). Furthermore, a continuum solvation method (C-PCM) has been applied to mimic solvent effects. Anion volumes were also calculated to facilitate a discussion on ion conductivities and cation transport numbers. Judging from the present results, synthesis efforts should target heterocyclic anions with a size of ca. 150 A(3) molecule(-1) to render new highly dissociative lithium salts that result in electrolytes with high cation transport numbers. 相似文献
482.
In the present work we control wall thickness oscillations in electrochemically grown TiO2 nanotube arrays by defined water additions to an organic anodization electrolyte. Such corrugated TiO2 nanotubes can be used to build optimized optical stacks that show under white light illumination well defined interference patterns which can be used as a self-cleaning platform for label-free sensing applications. 相似文献
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Yan-Yan Song Zhida Gao Kiyoung Lee Patrik Schmuki 《Electrochemistry communications》2011,13(11):1217-1220
In the present work, we show how TiO2 nanotube layers that are decorated with a Pt-nanoparticle coating can be fabricated and operated as a reusable glucose sensing system. A critical amount of Pt coating is essential not only to provide an effective catalyst for glucose oxidation but also to establish a sufficient conductivity along TiO2 nanotube walls to allow an efficient amperometric operation of the electrode. On such an electrode the self-cleaning photocatalytic features of TiO2 can be maintained and used to re-establish poisoned activity of the Pt particles. 相似文献
486.
We use a counting argument to show that Ore extensions are associative. 相似文献
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Highly ordered V2O5 porous layers were fabricated from vanadium metal foils by self-organizing anodization. The defined porous structure of this material provides excellent lithium-ion transportation and intercalation/extraction properties. As a result the highly ordered porous structure shows a very good electrochromic performance with long term switching stability. 相似文献
489.
Lucie Benesova Milos Pesek Barbora Belsanova Patrik Sekerka Marek Minarik 《Journal of separation science》2010,33(15):2349-2355
The presence of activating mutations within the tyrosine kinase domain of the epidermal growth factor receptor gene has been attributed to a positive response to biological therapy of lung cancer by small‐molecular tyrosine kinase inhibitors, gefitinib and erlotinib. Among the two most significant mutation types are deletions in exon 19 and a single point substitution in exon 21 (termed L858R). The exon 19 deletions can readily be examined by fragment analysis, due to the characteristic length difference between the normal and mutated PCR product. Analysis of the L858R point mutation, however, presents a greater challenge. The current paper is aimed at developing a sensitive, yet simple, low‐cost mutation detection assay directed at the L858R mutation using a method based on CE of heteroduplexes under partial denaturing conditions. We perform optimization of separation conditions on different commercial instruments including ones equipped with 8, 16 and 96 capillaries. We present normalized migration reproducibility in the range from 1 (8 and 16) to 5% (96) RSD. A reliable distinction of the R836R silent polymorphism from a potential presence of the L858R mutation is also demonstrated. In its implementation, the presented assay is just another application running on a conventional CE platform without the need of dedicated instrumentation. 相似文献
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