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991.
Since the seminal remark by Pecora and Carroll [Phys. Rev. Lett. 64, 821 (1990)] that one can synchronize chaotic systems, the main example in the related literature has been the Lorenz equations. Yet this literature contains a mixture of true and false, and of justified and unsubstantiated claims about the synchronization properties of the Lorenz equations. In this note we clarify some of the confusion. (c) 1997 American Institute of Physics. 相似文献
992.
Forman Mark A. Zanoni Brian C. Chopko Emily C. Carroll Patrick J. 《Structural chemistry》1998,9(1):27-32
The synthesis and X-ray crystal structure of the p-bromoanilide derivative of bicyclo[2.2.0]hexane-l-carboxylic acid (1), N-(4-bromophenyl)-bicyclo[2.2.0]hexane-l-carboxamide (2), is reported. N-(4-Bromophenyl)-bicyclo[2.2.0]hexane-l-carboxamide is synthesized in good yield via the DCC coupling of bicyclo[2.2.0]hexane-l-carboxylic acid (1) with p-bromoaniline. Low-temperature X-ray analysis of 2 reveals that the
bonds of the bicyclo[2.2.0]hexane skeleton vicinal to the amide group show a slight lengthening due to conjugative interaction with the -accepting amide group. Ab initio calculations at the 6-31G* level of theory on bicyclo[2.2.0]hexane-l-carboxamide, a model for 2, and for other 1-substituted bicyclo[2.2.0]hexanes are also reported. 相似文献
993.
Let
be a real separable Banach space and {X, X
n, m; (n, m) N
2} B-valued i.i.d. random variables. Set
. In this paper, the compact law of the iterated logarithm, CLIL(D), for B-valued random variables with two-dimensional indices ranging over a subset D of N
2 is studied. There is a gap between the moment conditions for CLIL(N
1) and those for CLIL(N
2). The main result of this paper fills this gap by presenting necessary and sufficient conditions for the sequence
to be almost surely conditionally compact in B, where, for 0, 1 r 2, N
r
(, ) = {(n, m) N
2; n
m n
exp{(log n)
r–1 (n)}} and (·) is any positive, continuous, nondecreasing function such that (t)/(log log t) is eventually decreasing as t , for some > 0. 相似文献
994.
Patrick A. Wayman 《Europhysics News》1998,28(5-6):159-160
George Johstone Stony, th man who maned the electron, was led to the concept of a fundamental unit of electic charge by combining electro-chemistry with the kinetic theory of gases. But his understanding was incomplete (so the discovery of the electron is associated wit JJ Thomsons determination of its charge to mass ratio in October 1897) 相似文献
995.
Friebele EJ Putnam MA Patrick HJ Kersey AD Greenblatt AS Ruthven GP Krim MH Gottschalck KS 《Optics letters》1998,23(3):222-224
We report ultrahigh-sensitivity static strain sensing (noise equivalent strain =1.5n rms) by two fiber etalon cavities made from silica and fluoride fibers. The anomalous thermo-optic coefficient of fluoride glass fibers allows for determination of thermal and laser drift. This sensor is also capable of simultaneous strain and temperature measurement, with errors in strain and temperature of 6.4% and 0.68%, respectively. 相似文献
996.
A Li-Na-containing borosilicate glass was submitted to aqueous corrosion in static mode in tritiated solutions of various pH at room temperature and 90 °C. Tritium counting, β-autoradiography, scanning electron microscopy (SEM) and ion beam analysis (IBA) techniques have been used to investigate the composition variations of the leached glass surfaces. In an acidic medium, the glass surface is covered by a thick hydrated silica layer; mobile elements like Li, Na and B and transition elements like Fe and Mo are strongly depleted. Near pH 7, relative enrichments of aluminium and iron are shown together with strong Li, Na and B depletions. In a basic medium, the glass surface exhibits iron and molybdenum enrichments whereas mobile elements seem to be kept at their nominal concentration level at the glass surface. The tritium activity and distribution on the leached glass surface is shown to depend strongly on the pH of the tritiated solutions. These observations are correlated with the observed changes of the surface morphology and chemistry characterized by IBA and SEM analysis. Elemental solubility versus pH of various chemical species have been calculated for comparison purpose with the experimental observations. 相似文献
997.
Lohier JF Foucoin F Jaffrès PA Garcia JI Sopková-de Oliveira Santos J Perrio S Metzner P 《Organic letters》2008,10(6):1271-1274
A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed. 相似文献
998.
A synthesis of the macrocyclic core structure of callipeltoside A and a C9 epimer has been achieved by applications of chiral vinylzinc or Kishi-Nozaki-Hiyama (K-N-H) additions, Roskamp homologations, and acylketene or intramolecular K-N-H macrolactonizations as key bond-forming steps. 相似文献
999.
Sadar MD Williams DE Mawji NR Patrick BO Wikanta T Chasanah E Irianto HE Soest RV Andersen RJ 《Organic letters》2008,10(21):4947-4950
The new chlorinated peptides sintokamides A to E (1-5) have been isolated from specimens of the marine sponge Dysidea sp. collected in Indonesia. Their structures were elucidated by a combination of spectroscopic and single-crystal X-ray diffraction analyses. Sintokamide A (1) is an inhibitor of N-terminus transactivation of the androgen receptor in prostate cancer cells. 相似文献
1000.
Markt P McGoohan C Walker B Kirchmair J Feldmann C De Martino G Spitzer G Distinto S Schuster D Wolber G Laggner C Langer T 《Journal of chemical information and modeling》2008,48(8):1693-1705
The cysteine protease cathepsin S (CatS) is involved in the pathogenesis of autoimmune disorders, atherosclerosis, and obesity. Therefore, it represents a promising pharmacological target for drug development. We generated ligand-based and structure-based pharmacophore models for noncovalent and covalent CatS inhibitors to perform virtual high-throughput screening of chemical databases in order to discover novel scaffolds for CatS inhibitors. An in vitro evaluation of the resulting 15 structures revealed seven CatS inhibitors with kinetic constants in the low micromolar range. These compounds can be subjected to further chemical modifications to obtain drugs for the treatment of autoimmune disorders and atherosclerosis. 相似文献