全文获取类型
收费全文 | 6477篇 |
免费 | 256篇 |
国内免费 | 46篇 |
专业分类
化学 | 4785篇 |
晶体学 | 24篇 |
力学 | 207篇 |
数学 | 883篇 |
物理学 | 880篇 |
出版年
2023年 | 67篇 |
2022年 | 87篇 |
2021年 | 126篇 |
2020年 | 118篇 |
2019年 | 149篇 |
2018年 | 92篇 |
2017年 | 82篇 |
2016年 | 197篇 |
2015年 | 166篇 |
2014年 | 205篇 |
2013年 | 369篇 |
2012年 | 465篇 |
2011年 | 500篇 |
2010年 | 272篇 |
2009年 | 239篇 |
2008年 | 424篇 |
2007年 | 435篇 |
2006年 | 392篇 |
2005年 | 361篇 |
2004年 | 338篇 |
2003年 | 299篇 |
2002年 | 249篇 |
2001年 | 84篇 |
2000年 | 80篇 |
1999年 | 65篇 |
1998年 | 56篇 |
1997年 | 60篇 |
1996年 | 74篇 |
1995年 | 49篇 |
1994年 | 36篇 |
1993年 | 27篇 |
1992年 | 32篇 |
1991年 | 33篇 |
1990年 | 35篇 |
1989年 | 27篇 |
1988年 | 18篇 |
1986年 | 21篇 |
1985年 | 26篇 |
1984年 | 39篇 |
1983年 | 28篇 |
1982年 | 38篇 |
1981年 | 25篇 |
1980年 | 37篇 |
1979年 | 24篇 |
1978年 | 29篇 |
1977年 | 37篇 |
1976年 | 27篇 |
1975年 | 28篇 |
1974年 | 16篇 |
1973年 | 18篇 |
排序方式: 共有6779条查询结果,搜索用时 125 毫秒
31.
Patrick Dehornoy 《Journal of Combinatorial Theory, Series A》2007,114(3):389-409
Many natural counting problems arise in connection with the normal form of braids—and seem to have not been much considered so far. Here we solve some of them. One of the noteworthy points is that a number of different induction schemes appear. The key technical ingredient is an analysis of the normality condition in terms of permutations and their descents, in the vein of the Solomon algebra. As was perfectly summarized by a referee, the main result asserts that the size of the automaton involved in the automatic structure of Bn associated with the normal form can be lowered from n! to p(n), the number of partitions of n. 相似文献
32.
We consider the 3D Navier–Stokes equation with generalized impermeability boundary conditions. As auxiliary results, we prove the local in time existence of a strong solution (‘strong’ in a limited sense) and a theorem on structure. Then, taking advantage of the boundary conditions, we formulate sufficient conditions for regularity up to the boundary of a weak solution by means of requirements on one of the eigenvalues of the rate of deformation tensor. Finally, we apply these general results to the case of an axially symmetric flow with zero angular velocity. 相似文献
33.
A method for calculating the number of rotamers of a linear alkane and of the number of rotamers with a given number of gauche conformations along the chain as a function of the total number of atoms in the chain, using general equations, is presented. A graphical method for generating individual rotamers was applied to the homologs up to decane, which has 1134 rotamers. The steric energies calculated by molecular mechanics (MM2 force field) were used as measures of the heat of formation for the coiled conformations relative to the anti conformer for each molecule, whereas the statistical entropy differences were calculated for classes of coiled rotamers grouped by the number of gauche bonds and steric energy. The free energy values calculated from these components show that already at 400 K hexane exists preferentially in conformations containing gauche bonds. For larger chains the free energy advantage for the coiled chains increases very steeply. The implications for the question of reactions of linear alkanes occurring on the surface or inside the channels of small- and medium-pore zeolites are briefly examined. 相似文献
34.
We construct division algebras with involution containing a Baer ordering with noninvariant order ring. This gives a negative
answer to a question of Holland, whether the order ring is always invariant under inner automorphisms. Furthermore, we give
examples of any index. Previously, the only known examples of division algebras containing Baer orderings were of index 2
n
or of indexp forp a prime of the form 4m + 3.
Supported in part by the National Science Foundation. 相似文献
35.
Justina Grabowska Karuna Kar Nanda R.T. Rajendra Kumar J.P. Mosnier M.O. Henry Simon B. Newcomb Patrick McNally Lisa OReilly Xu Lu Enda McGlynn 《Superlattices and Microstructures》2007,42(1-6):327
Self-organized ZnAl2O4 nanostructures with the appearance (in SEM) of high aspect ratio horizontal nanowires are grown on uncatalysed c-sapphire by vapour phase transport. The nanostructures grow as three equivalent crystallographic variants on c-sapphire. Raman and cathodoluminescence spectroscopy confirm that the nanostructures are not ZnO and TEM shows that they are the cubic spinel, zinc aluminate, ZnAl2O4, formed by the reaction of Zn and O with the sapphire substrate. 相似文献
36.
Patrick Mather Nino Grizzuti Glenn Heffner Mathias Ricker Willie E. Rochefort Markus Seitz Hans-Werner Schmidt Dale S. Pearson 《Liquid crystals》1994,17(6):811-826
In this paper, we report on the synthesis and detailed characterization of a new semiflexible nematic liquid crystalline polyester which could serve as a 'model' polyester for a variety of physical and physico-chemical investigations. The polymer is a nematic liquid over a wide temperature range-from the glass transition temperature at ∼95°C to the isotropic transition at ∼240°C. We expect this polyester to be particularly useful for studying the effect of flow on the orientation of liquid crystalline polymers, as well as the production and removal of disclinations. 相似文献
37.
38.
Christophe Rochais Vincent Lisowski Patrick Dallemagne Sylvain Rault 《Tetrahedron letters》2004,45(33):6353-6355
Novel arylpyrrolo- and pyrazolopyrrolizinones were prepared in three or four steps starting from aminoarylpyrrole and pyrazole carboxylates through the cyclisation of a Vilsmeier-Haack intermediate. This synthesis was enhanced by diverse N-protections of the aza-heterocycle and furnish new series with potential biological interest. 相似文献
39.
Paul A. Binding Patrick J. Browne Bruce A. Watson 《Journal of Mathematical Analysis and Applications》2004,291(1):246-261
Three inverse problems for a Sturm-Liouville boundary value problem −y″+qy=λy, y(0)cosα=y′(0)sinα and y′(1)=f(λ)y(1) are considered for rational f. It is shown that the Weyl m-function uniquely determines α, f, and q, and is in turn uniquely determined by either two spectra from different values of α or by the Prüfer angle. For this it is necessary to produce direct results, of independent interest, on asymptotics and oscillation. 相似文献
40.
Heinz H. Bauschke Patrick L. Combettes 《Proceedings of the American Mathematical Society》2003,131(12):3757-3766
An iterative method is proposed to construct the Bregman projection of a point onto a countable intersection of closed convex sets in a reflexive Banach space.