全文获取类型
收费全文 | 8477篇 |
免费 | 501篇 |
国内免费 | 258篇 |
专业分类
化学 | 5989篇 |
晶体学 | 57篇 |
力学 | 299篇 |
综合类 | 43篇 |
数学 | 1081篇 |
物理学 | 1767篇 |
出版年
2023年 | 103篇 |
2022年 | 155篇 |
2021年 | 184篇 |
2020年 | 176篇 |
2019年 | 231篇 |
2018年 | 166篇 |
2017年 | 131篇 |
2016年 | 273篇 |
2015年 | 231篇 |
2014年 | 282篇 |
2013年 | 476篇 |
2012年 | 618篇 |
2011年 | 644篇 |
2010年 | 372篇 |
2009年 | 353篇 |
2008年 | 532篇 |
2007年 | 528篇 |
2006年 | 485篇 |
2005年 | 470篇 |
2004年 | 431篇 |
2003年 | 372篇 |
2002年 | 313篇 |
2001年 | 177篇 |
2000年 | 128篇 |
1999年 | 118篇 |
1998年 | 107篇 |
1997年 | 100篇 |
1996年 | 107篇 |
1995年 | 85篇 |
1994年 | 61篇 |
1993年 | 50篇 |
1992年 | 48篇 |
1991年 | 49篇 |
1990年 | 68篇 |
1989年 | 44篇 |
1988年 | 28篇 |
1987年 | 23篇 |
1986年 | 40篇 |
1985年 | 34篇 |
1984年 | 42篇 |
1983年 | 31篇 |
1982年 | 39篇 |
1981年 | 27篇 |
1980年 | 38篇 |
1979年 | 28篇 |
1978年 | 33篇 |
1977年 | 39篇 |
1976年 | 28篇 |
1975年 | 29篇 |
1973年 | 19篇 |
排序方式: 共有9236条查询结果,搜索用时 15 毫秒
991.
采用密度泛函理论中的广义梯度近似,计算了CO在α-U(001)表面的吸附、解离和扩散.结果表明:CO分子以CU3OU2构型化学吸附在α-U(001)表面,吸附能为1.78-1.99eV;吸附后表层U原子向上迁移,伴随着褶皱的产生;CO分子与表面U原子的相互作用主要是U原子的电子向CO分子最低空轨道2π*转移,以及CO2π*/5σ/1π-U6d轨道间杂化而生成新的化学键;CO解离吸附较分子吸附在能量上更为有利,h1(C)+h2(O)和h1(C)+h1(O)(h:空位)解离态吸附能分别为2.71和3.08eV;近邻三重穴位之间C、O原子的扩散能垒分别为0.57和0.14eV,预示O原子较C原子更易在U(001)表面扩散迁移. 相似文献
992.
Patrick J. Fricke Jenna L. Stasko Dylan T. Robbins Alexander C. Gardner Jacqueline Stash Mark J. Ferraro Michael W. Fennie 《Tetrahedron letters》2017,58(48):4510-4513
Propargyl imidates derived from aromatic and aliphatic nitriles cyclize at room temperature in high yields when treated with a catalytic amount of copper (I) iodide. This 5-exo-dig process affords dihydrooxazoles which do not aromatize under the reaction conditions, and which are isolated without chromatography. Investigations of the reaction scope, subsequent functionalization of the reaction products, and preliminary mechanistic data are presented. 相似文献
993.
Sergey Simonov Leokadiya Zorina Natal'ya Kushch Ccile Mzire Patrick Batail 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(3):m126-m128
In the title compound, (C10H9NOS6)K[Hg(SCN)4] or (EDT–TTF–CONHMe)K[Hg(SCN)4)], fully oxidized organic (EDT–TTF–CONHMe)+· radical cations form quasi‐one‐dimensional stacks running along the monoclinic 21 axis and alternating along the crystallographic [101] direction with inorganic anion stacks made from mixed K+–[Hg(SCN)4]2− ribbons. For each anion, three essentially collinear SCN ligands interact with the K+ ions via short N⋯K contacts, while the terminal N atom of the fourth SCN group is engaged in a number of hydrogen‐bond contacts with the –CH, –NH and –CH2 hydrogen‐bond donors of the amide function. Radical cations are dimerized along the stacks and the crystal conductivity is activated. 相似文献
994.
Conformations of cyclopropyl methyl ketone have been studied using ab initio methods in an effort to quantify the effects of conjugative overlap between the cyclopropane ring and an adjacent ketone carbonyl. Results were comparable with previous experimental and theoretical studies. Cyclopropyl methyl ketone exhibits a global energy minimum in the s-cis conformer and a local energy minimum near the s-trans conformer. The potential energy curve obtained was used to derive torsion parameters which were employed in molecular mechanics studies of the conformations of the set of bicyclo[m.1.0]alkan-2-ones having larger ring sizes from five- to 16-membered. Similar conformations for the cyclopropyl ketone substructure are observed for all the medium and large ring systems examined. Possible synthetic ramifications of local conformational anchoring by this functional group array are discussed. 相似文献
995.
The X-ray photoelectron spectra of singly bent, doubly bent, and protonated doubly bent aryldiazonium complexes have been obtained and show that the RN2 ligand is highly reduced. The correlation observed between binding energies and structure of the MN2R moiety permit the assignment of the N(1s) photopeaks. 相似文献
996.
997.
Bould J Macháček J Londesborough MG Macías R Kennedy JD Bastl Z Rupper P Baše T 《Inorganic chemistry》2012,51(3):1685-1694
Three nido-decaborane thiol cluster compounds, [1-(HS)-nido-B(10)H(13)] 1, [2-(HS)-nido-B(10)H(13)] 2, and [1,2-(HS)(2)-nido-B(10)H(12)] 3 have been characterized using NMR spectroscopy, single-crystal X-ray diffraction analysis, and quantum-chemical calculations. In the solid state, 1, 2, and 3 feature weak intermolecular hydrogen bonding between the sulfur atom and the relatively positive bridging hydrogen atoms on the open face of an adjacent cluster. Density functional theory (DFT) calculations show that the value of the interaction energy is approximately proportional to the number of hydrogen atoms involved in the interaction and that these values are consistent with a related bridging-hydrogen atom interaction calculated for a B(18)H(22)·C(6)H(6) solvate. Self-assembled monolayers (SAMs) of 1, 2, and 3 on gold and silver surfaces have been prepared and characterized using X-ray photoelectron spectroscopy. The variations in the measured sulfur binding energies, as thiolates on the surface, correlate with the (CC2) calculated atomic charge for the relevant boron vertices and for the associated sulfur substituents for the parent B(10)H(13)(SH) compounds. The calculated charges also correlate with the measured and DFT-calculated thiol (1)H chemical shifts. Wetting-angle measurements indicate that the hydrophilic open face of the cluster is directed upward from the substrate surface, allowing the bridging hydrogen atoms to exhibit a similar reactivity to that of the bulk compound. Thus, [PtMe(2)(PMe(2)Ph)(2)] reacts with the exposed and acidic B-H-B bridging hydrogen atoms of a SAM of 1 on a gold substrate, affording the addition of the metal moiety to the cluster. The XPS-derived stoichiometry is very similar to that for a SAM produced directly from the adsorption of [1-(HS)-7,7-(PMe(2)Ph)(2)-nido-7-PtB(10)H(11)] 4. The use of reactive boron hydride SAMs as templates on which further chemistry may be carried out is unprecedented, and the principle may be extended to other binary boron hydride clusters. 相似文献
998.
999.
审计作为市场经济的自我约束机制,在经济发展中有着不可或缺的责任.本文利用随机网络技术进行分析,旨在设计出高效率的审计活动方案.首先,利用PERT技术建立了确定型的审计活动模型,在此基础上给出了时间—资源优化下的最优人员分配方案;其次,利用GERT技术建立了随机型的审计活动模型,引入矩母函数和梅森公式进行GERT解析求解求出所需的工期等指标,同时采用蒙特卡罗模拟求解验证解析求解的准确性,为审计活动的工期控制提供了理论依据.最后对于工作时间确定的GERT模型,结合PERT和GERT两种技术对其进行简化分析,从而得到了时间—资源优化下的最优人员分配方案. 相似文献
1000.