全文获取类型
收费全文 | 405篇 |
免费 | 10篇 |
国内免费 | 2篇 |
专业分类
化学 | 182篇 |
晶体学 | 1篇 |
力学 | 9篇 |
数学 | 112篇 |
物理学 | 113篇 |
出版年
2022年 | 6篇 |
2021年 | 12篇 |
2020年 | 9篇 |
2019年 | 4篇 |
2018年 | 8篇 |
2017年 | 3篇 |
2016年 | 8篇 |
2015年 | 14篇 |
2014年 | 4篇 |
2013年 | 17篇 |
2012年 | 20篇 |
2011年 | 29篇 |
2010年 | 13篇 |
2009年 | 19篇 |
2008年 | 26篇 |
2007年 | 18篇 |
2006年 | 23篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 14篇 |
2002年 | 14篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 4篇 |
1995年 | 2篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 6篇 |
1982年 | 5篇 |
1981年 | 6篇 |
1980年 | 4篇 |
1979年 | 7篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1973年 | 3篇 |
1969年 | 1篇 |
1968年 | 2篇 |
1940年 | 1篇 |
1935年 | 2篇 |
排序方式: 共有417条查询结果,搜索用时 0 毫秒
21.
Patrícia Santiago de Oliveira Patricio Iaci Miranda Pereira Natália Cristina Ferreira da Silva Eliane Ayres Fabiano Vargas Pereira Rodrigo Lambert Oréfice 《European Polymer Journal》2013
Polyurethane waterborne synthesis was performed using a two-step method, commonly referred to as a prepolymer method. Nanocomposites based on waterborne polyurethane and cellulose nanocrystals were prepared by the prepolymer method by altering the mode and step in which the nanofillers were incorporated during the polyurethane formation. The morphology, structural, thermal, and mechanical properties of the resulting nanocomposite films were evaluated by Fourier transform infrared spectroscopy (FTIR), small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), and tensile tests. FTIR results indicated that the degree of interaction between the nanofillers and the WPU through hydrogen bonds could be controlled by the method of cellulose nanocrystal incorporation. Data obtained from SAXS experiments showed that the cellulose nanocrystals as well as the step of the reaction in which they are added influenced the morphology of the polyurethane. The reinforcing effect of CNCs on the nanocomposites depends on their morphology. 相似文献
22.
Patricio A. Navarrete‐Encina Juan A. Squella J. Carbajo B. Conde Luis J. Núñez‐Vergara 《合成通讯》2013,43(12):2051-2060
A series of C‐3,4,5‐substituted 2,6‐dimethyl‐1,4‐dihydropyridines (1,4‐DHPs) with pharmacological properties were prepared by a variation from the classical Hantzsch synthesis. The procedure involves treatment of the respective aldehyde with either ethyl‐3‐aminocrotonate or 3‐aminocrotonitrile in anhydrous acetic acid at temperatures not exceeding 60°C, thus minimizing by‐product formation. The structures of title compounds were elucidated by 1H NMR, 13C NMR, FTIR, and elemental analysis. 相似文献
23.
Bernardita Cayupe Carlos Morgan Gustavo Puentes Luis Valladares Hctor Burgos Amparo Castillo Alejandro Hernndez Luis Constandil Miguel Ríos Patricio Sez-Briones Rafael Barra 《Molecules (Basel, Switzerland)》2021,26(12)
Prenatally malnourished rats develop hypertension in adulthood, in part through increased α1-adrenoceptor-mediated outflow from the paraventricular nucleus (PVN) to the sympathetic system. We studied whether both α1-adrenoceptor-mediated noradrenergic excitatory pathways from the locus coeruleus (LC) to the PVN and their reciprocal excitatory CRFergic connections contribute to prenatal undernutrition-induced hypertension. For that purpose, we microinjected either α1-adrenoceptor or CRH receptor agonists and/or antagonists in the PVN or the LC, respectively. We also determined the α1-adrenoceptor density in whole hypothalamus and the expression levels of α1A-adrenoceptor mRNA in the PVN. The results showed that: (i) agonists microinjection increased systolic blood pressure and heart rate in normotensive eutrophic rats, but not in prenatally malnourished subjects; (ii) antagonists microinjection reduced hypertension and tachycardia in undernourished rats, but not in eutrophic controls; (iii) in undernourished animals, antagonist administration to one nuclei allowed the agonists recover full efficacy in the complementary nucleus, inducing hypertension and tachycardia; (iv) early undernutrition did not modify the number of α1-adrenoceptor binding sites in hypothalamus, but reduced the number of cells expressing α1A-adrenoceptor mRNA in the PVN. These results support the hypothesis that systolic pressure and heart rate are increased by tonic reciprocal paraventricular–coerulear excitatory interactions in prenatally undernourished young-adult rats. 相似文献
24.
Claudio Parra Patricio Muoz Luis Bustos Felipe Parra Mario J. Simirgiotis Hugo Escobar 《Molecules (Basel, Switzerland)》2021,26(7)
The Lamiaceae family is an important source of species among medicinal plants highly valued for their biological properties and numerous uses in folk medicine. Origanum is one of the main genera that belong to this family. The purpose of the study was to determine the phenolic composition of the Origanum vulgare extract and evaluate the antimicrobial, antioxidant, and inhibitory activities of this species that grows in the Andean region of the Atacama Desert. High-performance liquid chromatography was performed to determine the main phenols. Rosmarinic acid was identified as the predominant phenolic compound in this species (76.01 mg/100 g DW), followed by protocatechuic acid, which to our knowledge, no previous study reported similar concentrations in O. vulgare. The oregano extract exhibited a content of total phenolic (3948 mg GAE/100 g DW) and total flavonoid (593 mg QE/100 g DW) with a higher DPPH antioxidant activity (IC50 = 40.58 µg/mL), compared to the same species grown under other conditions. Furthermore, it was found to inhibit α-glucosidase activity with an IC50 value (7.11 mg/mL) lower than acarbose (129.32 mg/mL). Pseudomonas syringae and Pantoea agglomerans (both MIC 0.313 mg/mL and MBC 1.25 mg/mL) were the bacteria most susceptible to oregano extract with the lowest concentration necessary to inhibit bacterial growth. These results open the door for the potential use of this plant to manage chronic diseases, and they expand the knowledge of the species cultivated in arid environmental conditions. 相似文献
25.
26.
J. A. Helay?l-Neto L. M. de Moraes V. J. Vasquez 《The European Physical Journal C - Particles and Fields》2010,67(1-2):311-319
In this paper, we reassess the issue of deriving the propagators and identifying the spectrum of excitations associated to the vielbein and spin connection of (1+2)-D gravity in the presence of dynamical torsion, while working in the first-order formulation. A number of peculiarities is pointed out whenever the Chern–Simons term is taken into account along with a combination of bilinear terms in the torsion tensor. We present a procedure to derive the full set of propagators, based on an algebra of enlarged spin-type operators, and we discuss under which conditions the poles of the tree-level 2-point functions correspond to physical excitations that do not conflict with causality and unitarity. 相似文献
27.
28.
Patricio V Poblete J.Ian Munro 《Journal of Algorithms in Cognition, Informatics and Logic》1985,6(3):336-350
A detailed analysis is presented for the behaviour of binary search trees built by using a heuristic that performs only local reorganizations at the bottom of the tree. 相似文献
29.
In this paper we study the direct decomposability of free Tarski algebras. We
show that infinite freely generated Tarski algebras are directly indecomposable, whereas
finite freely generated Tarski algebras can only be decomposed into a direct product of two
factors, one of which is the two-element Tarski algebra. 相似文献
30.
In the context of a complete simply connected Riemannian manifold of pinched negative curvature, we show that several families
of approach domains are equivalent for convergence to points of the boundary, and for the purposes of Hp-theory. 相似文献