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81.
Florentina Golgovici Alexandru Pumnea Aurora Petica Adrian Cristian Manea Oana Brincoveanu Marius Enachescu Liana Anicai 《Chemical Papers》2018,72(8):1889-1903
In the case of hydrogen production involving seawater electrolysis, one of the main targets is to develop more active cathodic materials, to optimize the efficiency of hydrogen evolution reaction (HER) and, by doing so, enhance the overall energy efficiency of electrolysis. Thus, to develop suitable HER electrocatalysts either an increase of the electrode active surface area or a design of a material having high intrinsic catalytic activity should be taken into consideration, both of them decreasing the HER overpotential. In the present work, various Ni–Mo alloy nanostructures (10–40 wt% Mo) have been prepared involving electrochemical deposition from aqueous and deep eutectic solvent (DES)-based electrolytes as potential cathodic materials suitable for hydrogen evolution reaction during water electrolysis. The electrocatalytic activity of the obtained layers has been investigated using real seawater electrolyte. The determined Tafel slopes suggested that the electrodeposited Ni–Mo alloy coatings follow an HER mechanism controlled by the Volmer reaction step. The EIS results indicated that the use of choline chloride-based ionic liquids as electrolytes facilitated Ni–Mo alloy coatings showing a significant increase in surface roughness. Studies of the intrinsic activity showed that the main contribution towards the apparent activity comes from the increase of the real surface area, although a slight increase of the intrinsic electrocatalytic activity in the case of Ni–Mo alloy coatings electrodeposited on Ni foam was also noticed. These results showed that Ni–Mo alloy coatings electrodeposited from the novel electrolytes based on choline chloride–urea–citric acid ternary mixtures associated with a porous substrate may represent a promising technological approach to build cathodic materials suitable for seawater electrolysis. 相似文献
82.
A Three‐Component Assembly Promoted by Boronic Acids Delivers a Modular Fluorophore Platform (BASHY Dyes)
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Fábio M. F. Santos Dr. João N. Rosa Dr. Nuno R. Candeias Cátia Parente Carvalho Ana I. Matos Ana E. Ventura Dr. Helena F. Florindo Dr. Liana C. Silva Dr. Uwe Pischel Dr. Pedro M. P. Gois 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(5):1631-1637
The modular assembly of boronic acids with Schiff‐base ligands enabled the construction of innovative fluorescent dyes [boronic acid salicylidenehydrazone (BASHY)] with suitable structural and photophysical properties for live cell bioimaging applications. This reaction enabled the straightforward synthesis (yields up to 99 %) of structurally diverse and photostable dyes that exhibit a polarity‐sensitive green‐to‐yellow emission with high quantum yields of up to 0.6 in nonpolar environments. These dyes displayed a high brightness (up to 54 000 m ?1 cm?1). The promising structural and fluorescence properties of BASHY dyes fostered the preparation of non‐cytotoxic, stable, and highly fluorescent poly(lactide‐co‐glycolide) nanoparticles that were effectively internalized by dendritic cells. The dyes were also shown to selectively stain lipid droplets in HeLa cells, without inducing any appreciable cytotoxicity or competing plasma membrane labeling; this confirmed their potential as fluorescent stains. 相似文献
83.
A vector field E on an F-manifold (M,°,e) is an eventual identity if it is invertible and the multiplication X?Y:=X°Y°E−1 defines a new F-manifold structure on M. We give a characterization of such eventual identities, this being a problem raised by Manin (2005) [12]. We develop a duality between F-manifolds with eventual identities and we show that this duality is compatible with the local irreducible decomposition of F-manifolds and preserves the class of Riemannian F-manifolds. We find necessary and sufficient conditions on the eventual identity which ensure that the classes of harmonic Higgs bundles, DChk-structures and weak CV-structures are preserved by our duality. Examples of such structures are given in the case of a semi-simple multiplication. We use eventual identities to construct compatible pairs of metrics. 相似文献
84.
De Marco R Tolomelli A Campitiello M Rubini P Gentilucci L 《Organic & biomolecular chemistry》2012,10(11):2307-2317
The reaction of sulfonyl peptides containing L- or D-configured Ser or Thr with bis(succinimidyl) carbonate in the presence of a catalytic amount of a base affords, in solution or in the solid phase, the corresponding peptides with one or two, consecutive or alternate oxazolidin-2-ones (Oxd). The Oxd ring can be regarded to as a pseudo-Pro with an exclusively trans conformation of the preceding peptide bond; homochiral Oxd-containing peptides adopt extended conformations, while the presence of a D-configured Oxd favours folded conformations. 相似文献
85.
Viviana Scognamiglio Italo Pezzotti Gianni Pezzotti Juan Cano Ivano Manfredonia Katia Buonasera Fabiana Arduini Danila Moscone Giuseppe Palleschi Maria Teresa Giardi 《Analytica chimica acta》2012
In this paper we propose the construction and application of a portable multi-purpose biosensor array for the simultaneous detection of a wide range of endocrine disruptor chemicals (EDCs), based on the recognition operated by various enzymes and microorganisms. The developed biosensor combines both electrochemical and optical transduction systems, in order to increase the number of chemical species which can be monitored. Considering to the maximum residue level (MRL) of contaminants established by the European Commission, the biosensor system was able to detect most of the chemicals analysed with very high sensitivity. In particular, atrazine and diuron were detected with a limit of detection of 0.5 nM, with an RSD% less than 5%; paraoxon and chlorpyrifos were revealed with a detection of 5 μM and 4.5 μM, respectively, with an RSD% less than 6%; catechol and bisphenol A were identified with a limit of detection of 1 μM and 35 μM respectively, with an RSD% less than 5%. 相似文献
86.
87.
Wong L Hu C Paradise R Zhu Z Shtukenberg A Kahr B 《Journal of the American Chemical Society》2012,134(29):12245-12251
Many crystalline dyes, when rubbed unidirectionally with cotton on glass slides, can be organized as thin films of highly aligned nanocrystals. Commonly, the linear birefringence and linear dichroism of these films resemble the optical properties of single crystals, indicating precisely oriented particles. Of 186 colored compounds, 122 showed sharp extinction and 50 were distinctly linearly dichroic. Of the latter 50 compounds, 88% were more optically dense when linearly polarized light was aligned with the rubbing axis. The mechanical properties of crystals that underlie the nonstatistical correlation between tribological processes and the direction of electron oscillations in absorption bands are discussed. The features that give rise to the orientation of dye crystallites naturally extend to colorless molecular crystals. 相似文献
88.
Given two positive integers e and s we consider Gorenstein Artinian local rings R whose maximal ideal m satisfies ms≠0=ms+1 and rankR/m(m/m2)=e. We say that R is a compressed Gorenstein local ring when it has maximal length among such rings. It is known that generic Gorenstein Artinian algebras are compressed. If s≠3, we prove that the Poincaré series of all finitely generated modules over a compressed Gorenstein local ring are rational, sharing a common denominator. A formula for the denominator is given. When s is even this formula depends only on the integers e and s . Note that for s=3 examples of compressed Gorenstein local rings with transcendental Poincaré series exist, due to Bøgvad. 相似文献
89.
Liana M. Klivansky Gayane Koshkakaryan Dennis Cao Yi Liu Dr. 《Angewandte Chemie (International ed. in English)》2009,48(23):4185-4189
Cage me! A linear dumbbell‐shaped bipyridinium molecule can template cage formation around itself through sixfold imine bond formation to give an interlocked [2]rotaxane as the single product (see picture). This highly efficient [2+3] clipping occurs despite the symmetry mismatch between the template and the formed macrobicycle.
90.
Koshkakaryan G Jiang P Altoe V Cao D Klivansky LM Zhang Y Chung S Katan A Martin F Salmeron M Ma B Aloni S Liu Y 《Chemical communications (Cambridge, England)》2010,46(45):8579-8581
Symmetrically substituted hexakis(alkoxy)triphenylene (HAT) derivatives were assembled into single molecular thick 2D nanosheets, which stacked further to give multilayered nanofibers through a convenient solution process. Detailed information on molecular arrangement was unraveled by various imaging techniques and diffraction studies. 相似文献