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71.
Herbert Danninger Tayfun Kara Michael Ruhnow Hans -Jürgen Ullrich 《Mikrochimica acta》1990,101(1-6):219-229
Homogenization of Mo, W and Cr in alloyed P/M carbon steels during sintering with a transient liquid phase has been investigated by microscopic and microanalytical means. The reaction was found to start with carburization of the VIa metal, continues with the formation of different carbides, and generation of a liquid phase between the carbide and -Fe. The steady state equilibrium remains stable until all VIa metal has been consumed. Microprobe analysis was found to yield optimum results if selected model samples, in which homogenization should not proceed too fast, are investigated.Dedicated to Professor Günther Tölg on the occasion of his 60th birthday 相似文献
72.
A series of four dichromophoric rigid macrocycles 6a-6d, two with diphenyloligothiophene chromophores, the other two with more electron-rich diphenyl-EDOT or diphenyl-bis-EDOT chromophores, have been synthesized. The absorption spectrum of the diphenyl-bis-EDOT based macrocycle 6d displayed the most pronounced vibronic resolution with a well-resolved 0-0 transition, indicating a fully planarized geometry of the diphenyl-bis-EDOT chromophores. The (1)H NMR spectra of the macrocycles displayed weak to moderate chemical shifts of characteristic signals upon addition of pi-conjugated oligonitro-9-fluorenone acceptors. X-ray single-crystal analysis showed that columnar pi-stacked donor/acceptor complexes are formed with the stacks composed of alternating donor and acceptor molecules. The stoichiometry of the crystalline, dark-colored complexes was found to be 1:1 by elemental analysis and integration of the (1)H NMR peaks. The complex formation is accompanied by remarkably large Stern-Volmer constants of fluorescence quenching. 相似文献
73.
Recent work by Pejova [Mater. Res. Bull. 43, 2887 (2008)] showed that the widely cited classical photocurrent theory of DeVore [Phys. Rev. 102, 86 (1956)] does not necessarily apply for photocurrent experiments carried out on thin-film semiconductors. In this Letter, we theoretically and experimentally justify the successful use of the photocurrent model published by Bouchenaki et al. [J. Opt. Soc. Am. B 8, 691 (1991)]. 相似文献
74.
Gustavo?Garrigós Andreas?SeegerEmail author Tino?Ullrich 《Journal of Fourier Analysis and Applications》2018,24(5):1319-1339
We show that, for suitable enumerations, the Haar system is a Schauder basis in the classical Sobolev spaces in \({\mathbb R}^d\) with integrability \(1<p<\infty \) and smoothness \(1/p-1<s<1/p\). This complements earlier work by the last two authors on the unconditionality of the Haar system and implies that it is a conditional Schauder basis for a nonempty open subset of the (1 / p, s)-diagram. The results extend to (quasi-)Banach spaces of Hardy–Sobolev and Triebel–Lizorkin type in the range of parameters \(\frac{d}{d+1}<p<\infty \) and \(\max \{d(1/p-1),1/p-1\}<s<\min \{1,1/p\}\), which is optimal except perhaps at the end-points. 相似文献
75.
Mario Ullrich 《Random Structures and Algorithms》2013,42(4):520-535
We prove that the spectral gap of the Swendsen‐Wang process for the Potts model on graphs with bounded degree is bounded from below by some constant times the spectral gap of any single‐spin dynamics. This implies rapid mixing for the two‐dimensional Potts model at all temperatures above the critical one, as well as rapid mixing at the critical temperature for the Ising model. After this we introduce a modified version of the Swendsen‐Wang algorithm for planar graphs and prove rapid mixing for the two‐dimensional Potts models at all non‐critical temperatures. © 2012 Wiley Periodicals, Inc. Random Struct. Alg., 42, 520–535, 2013 相似文献
76.
One interesting question is how the good local approximation behavior of the Shannon sampling series for the Paley–Wiener space $\mathcal {PW}_{\pi}^{1}$ is affected if the samples are disturbed by the non-linear threshold operator. This operator, which is important in many applications, sets all samples whose absolute value is smaller than some threshold to zero. In this paper we analyze a generalization of this problem, in which not the Shannon sampling series is disturbed by the threshold operator but a more general system approximation process, were a stable linear time-invariant system is involved. We completely characterize the stable linear time-invariant systems that, for some functions in $\mathcal {PW}_{\pi}^{1}$ , lead to a diverging approximation process as the threshold is decreased to zero. Further, we show that if there exists one such function then the set of functions for which divergence occurs is in fact a residual set. We study the pointwise behavior as well as the behavior of the L ∞-norm of the approximation process. It is known that oversampling does not lead to stable approximation processes in the presence of thresholding. An interesting open problem is the characterization of the systems that can be stably approximated with oversampling. 相似文献
77.
O. O. Versolato M. Schwarz A. Windberger J. Ullrich P. O. Schmidt M. Drewsen J. R. Crespo López-Urrutia 《Hyperfine Interactions》2013,214(1-3):189-194
Narrow optical transitions in highly charged ions (HCIs) are of particular interest for metrology and fundamental physics, exploiting the high sensitivity of HCIs to new physics. The highest sensitivity for a changing fine structure constant ever predicted for a stable atomic system is found in Ir17?+?. However, laser spectroscopy of HCIs is hindered by the large (~ 106 K) temperatures at which they are produced and trapped. An unprecedented improvement in such laser spectroscopy can be obtained when HCIs are cooled down to the mK range in a linear Paul trap. We have developed a cryogenic linear Paul trap in which HCIs will be sympathetically cooled by 9Be?+? ions. Optimized optical access for laser light is provided while maintaining excellent UHV conditions. The Paul trap will be connected to an electron beam ion trap (EBIT) which is able to produce a wide range of HCIs. This EBIT will also provide the first experimental input needed for the determination of the transition energies in Ir17?+?, enabling further laser-spectroscopic investigations of this promising HCI. 相似文献
78.
The exact exchange potential in time-dependent density-functional theory is defined as an orbital functional through the time-dependent optimized effective potential (TDOEP) method. We numerically solve the TDOEP integral equation for the real-time nonlinear intersubband electron dynamics in a semiconductor quantum well with two occupied subbands. It is found that memory effects become significant in the vicinity of intersubband resonances. 相似文献
79.
80.