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181.
182.
183.
This is the fourth article of our series. Here, we study weighted norm inequalities for the Riesz transform of the Laplace–Beltrami
operator on Riemannian manifolds and of subelliptic sum of squares on Lie groups, under the doubling volume property and Gaussian
upper bounds.
相似文献
184.
185.
Aurore Richel Pascal Laurent Bernard Wathelet Michel Paquot 《Tetrahedron letters》2010,51(10):1356-15298
Monomode microwave-assisted coupling of d-glucuronic acid with alcohols, in the presence of various impregnated acid catalysts, was successfully performed, affording in almost quantitative yields the corresponding monosubstituted β-d-glucofuranosidurono-6,3-lactones in less than 10 min at 85 °C. This study evidences the synergy of microwaves and impregnated acid catalysts as a fast and clean strategy in the field of carbohydrate chemistry. 相似文献
186.
As assemblies of graphene sheets, carbon nanotubes, and fullerenes become components of new nanotechnologies, it is important to be able to predict the structures and properties of these systems. A problem has been that the level of quantum mechanics practical for such systems (density functional theory at the PBE level) cannot describe the London dispersion forces responsible for interaction of the graphene planes (thus graphite falls apart into graphene sheets). To provide a basis for describing these London interactions, we derive the quantum mechanics based force field for carbon (QMFF-Cx) by fitting to results from density functional theory calculations at the M06-2X level, which demonstrates accuracies for a broad class of molecules at short and medium range intermolecular distances. We carried out calculations on the dehydrogenated coronene (C24) dimer, emphasizing two geometries: parallel-displaced X (close to the observed structure in graphite crystal) and PD-Y (the lowest energy transition state for sliding graphene sheets with respect to each other). A third, eclipsed geometry is calculated to be much higher in energy. The QMFF-Cx force field leads to accurate predictions of available experimental mechanical and thermodynamics data of graphite (lattice vibrations, elastic constants, Poisson ratios, lattice modes, phonon dispersion curves, specific heat, and thermal expansion). This validates the use of M06-2X as a practical method for development of new first principles based generations of QMFF force fields. 相似文献
187.
Jalal Ghilane Pascal Martin Hyacinthe Randriamahazaka Jean-Christophe Lacroix 《Electrochemistry communications》2010,12(2):246-249
Electrochemical oxidation of primary amine in ionic liquid media has been investigated. The ionic liquid chosen for this study was 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. Two primary amine compounds are used for this study; 4-nitrobenzylamine and 2-aminoethylferrocenylmethylether. The oxidation of the amino compounds in ionic liquid conduces to the modification of the electrode surface. The modified electrodes were characterized by cyclic voltammetry and XPS analysis. Both techniques support the presence of an organic layer strongly attached onto the electrode surface. The surface concentration of the attached group obtained in this media was found to be around 1 to 3 × 10?10 mol cm?2. The use of ionic liquid as media for the grafting leads to decrease of the surface concentration of the grafted layer; and the formation of less dense layer compared with classical solvent such as acetonitrile. 相似文献
188.
Luís Santos Pascal Martin Jalal Ghilane Pierre-Camille Lacaze Hyacinthe Randriamahazaka Luisa Maria Abrantes Jean-Christophe Lacroix 《Electrochemistry communications》2010,12(7):872-875
The electrodeposition of poly(3,4-ethylenedioxythiophene) (PEDOT) films from aqueous surfactant solution through a two-dimensional poly(styrene) (PS) template onto indium tin oxide (ITO) substrate has been investigated. The polymer grows in the interstitial spaces of the self-assembled PS spheres which were subsequently removed by dissolution in tetrahydrofuran (THF). Surface characterization by scanning electron microscopy (SEM) and atomic force microscopy (AFM) reveals that two-dimensional nanoporous honeycomb PEDOT structures can easily be obtained by using PS spheres of different sizes. Gold electrodeposition onto the nanostructured PEDOT electrode was investigated and SEM images show preferential formation of nanoparticles (NP) on the wall and the rim of the PEDOT film but metal clusters inside the pores are also observed. 相似文献
189.
Séverine Derbré Julia Gatto Aude Pelleray Laurie Coulon Denis Séraphin Pascal Richomme 《Analytical and bioanalytical chemistry》2010,398(4):1747-1758
Advanced glycation end-products (AGEs) are involved in the pathogenesis of numerous affections such as diabetes and neurological
diseases. AGEs are also implied in various changes in tissues and organs. Therefore, compounds able to break them or inhibit
their formation may be considered as potential drugs, dietary supplements, or bioactive additives. In this study, we have
developed a rapid and reliable (Z′ factor calculation) anti-AGEs activity screening based on the overall fluorescence of AGEs. This method was successfully
evaluated on known AGEs inhibitors and on a small library of natural compounds, yielding coherent results when compared with
literature data. 相似文献
190.
Gaëlle Semard Valerie Peulon-Agasse Auguste Bruchet Jean-Philippe Bouillon Pascal Cardinaël 《Journal of chromatography. A》2010,1217(33):5449-5454
It is important to develop methods of optimizing the selection of column sets and operating conditions for comprehensive two-dimensional gas chromatography. A new method for the calculation of the percentage of separation space used was developed using Delaunay's triangulation algorithms (convex hull). This approach was compared with an existing method and showed better precision and accuracy. It was successfully applied to the selection of the most convenient column set and the geometrical parameters of second column for the analysis of 49 target compounds in wastewater. 相似文献