Sulphonated macroporous resin catalysts: Studies on the dehydration of 2-butanol

Sulphonated styrene-divinylbenzene resins with various cross-linking have been synthesized and the dehydration of 2-butanol has been studied on these acid catalysts. The pore structure of the resin controls the rate of dehydration. Thecis totrans ratio of the 2-butene formed indicate that the resin catalysts behave like aqueous solution of acids, i.e.dissociated protons are responsible for catalysis.     

Quark masses from qq potentials

Assuming confinement and chiral symmetry breaking, we have calculated constituent quark masses from phenomenological q$\text{q}$ potentials by using a BCS-like gap equation.     

Heterocyclic synthesis using ethyl carboethoxyformimidate

Ethyl carboethoxyformimidate is shown to be a versatile reagent for the synthesis of a variety of mono- and bicyclic heterocyclic systems.     

Separation of lignosulfonate from its aqueous solution using supported liquid membrane

This paper presents an experimental and theoretical study on facilitated transport of lignosulfonate (LS) through a flat sheet supported liquid membrane using trioctylamine (TOA) as carrier and dichloroethane as diluent. The studies were carried out with various support materials and operating conditions (viz. carrier concentration, strip phase concentration, salt concentration, etc.) and their effects on the transport of LS. The results were analyzed to identify a suitable combination of support and operating condition that would yield best performance of the supported liquid membrane (SLM) in terms of fast and efficient transport of LS. The stability of the SLM was assessed in terms of loss of liquid from the pores of membrane support. The SLM is found to be stable till 10 h. Co-transport mechanism has been adopted in this work by using NaOH as the strip phase. It was observed that extraction of LS is increased with increase in concentration of NaOH up to a limiting value of 0.5 M NaOH. Difference of salt concentration between feed and strip phase considerably affect the separation process. The diffusional resistances of organic membrane (Δorg) and aqueous solution (Δaq) calculated from the permeation model, which is again a combination of three unique mechanisms viz., diffusion through a feed aqueous layer, a fast interfacial chemical reaction, and diffusion of carrier–complex through the organic membrane, are found to be 609.9 and 176.6 s cm⁻¹, respectively. The values of the diffusion coefficient in the membrane (D_org) and in the bulk organic phase (D_complex) are 1.67×10⁻⁹ and 6.68 × 10⁻⁸ m²s⁻¹, respectively. The extraction of LS is about 90%. Nearly 43% of LS can be recovered at optimum condition.     

Third Joint ESF–NSF Symposium on ‘Nanoparticles: Applications in Materials Science and Environmental Science and Engineering,’ Dublin,Ireland, September 6, 2000

Journal of Nanoparticle Research -     

Finding the Homology of Submanifolds with High Confidence from Random Samples

Recently there has been a lot of interest in geometrically motivated approaches to data analysis in high-dimensional spaces. We consider the case where data are drawn from sampling a probability distribution that has support on or near a submanifold of Euclidean space. We show how to “learn” the homology of the submanifold with high confidence. We discuss an algorithm to do this and provide learning-theoretic complexity bounds. Our bounds are obtained in terms of a condition number that limits the curvature and nearness to self-intersection of the submanifold. We are also able to treat the situation where the data are “noisy” and lie near rather than on the submanifold in question. The main results of this paper were first presented at a conference in honor of John Franks and Clark Robinson at Northwestern University in April 2003. These results were formally written as Technical Report No. TR-2004-08, Department of Computer Science, University of Chicago.     

Laser induced optoacoustic spectroscopy of benzil: Evaluation of structural volume change upon photoisomerization

The cis-skew to trans-planar photoisomerization of benzil in the photoexcited state was studied by laser-induced optoacoustic spectroscopy (LIOAS) in a series of normal alkane solvents at room temperature. The structural volume change due to the photoisomerization process has been estimated and compared with the same calculated from the optimized skew and trans structures. The magnitude of the structural volume change is estimated to be 22.9 ± 1.2 mL/mol. This study reveals that an expansion in volume occurs during the photoinduced isomerization process. In non-polar alkane solvents, the estimated volume change has been argued to be free from electrostrictional contribution.     

Exploring anionic emission of 2-benzoyl benzimidazole in micellar environments

In this paper, an interesting transformation of the emission of anionic conformer of 2-benzoyl bezimidazole in ionic and non-ionic micelles is reported. Deprotonation is hindered in cationic and non-ionic micelles owing to probe molecule's passage deep inside positive ion-rich Stern-layer in contrast with anionic micelle. The orientation of probe molecule in the two ionic micelles, as determined from the spectral properties is opposite in nature. Micellar environment shields the formation of mono- and di-cationic species at very low pH. Three decay times of the probe in different time domains were attributed to three possible anionic species and they are modified differently in ionic and neutral micelles. Quantum chemical calculations also predict the existence of three different possible anionic species.     

Number-theoretic interpretation and construction of a digital circle

This paper presents a new interpretation of a digital circle in terms of the distribution of square numbers in discrete intervals. The number-theoretic analysis that leads to many important properties of a digital circle succinctly captures the original perspectives of digital calculus and digital geometry for its visualization and characterization. To demonstrate the capability and efficacy of the proposed method, two simple algorithms for the construction of digital circles, based on simple number-theoretic concepts, have been reported. Both the algorithms require only a few primitive operations and are completely devoid of any floating-point computation. To speed up the computation, especially for circular arcs of high radii, a hybridized version of these two algorithms has been given. Experimental results have been furnished to elucidate the analytical power and algorithmic efficiency of the proposed approach. It has been also shown, how and why, for sufficiently high radius, the number-theoretic technique can expedite a circle construction algorithm.     

A tandem mass spectrometric approach to the identification of O‐glycosylated glargine glycoforms in active pharmaceutical ingredient expressed in Pichia pastoris

Glycoforms of glargine expressed in Pichia pastoris were isolated by high‐performance liquid chromatography and analyzed by a series of chemical and mass spectrometric methods for the identification of various glycoforms, glycosylation position, nature and structure of glycans. Reduction and alkylation, peptide mapping techniques were used to decipher the amino acid site at which glycosylation had taken place. Chemical methods were coupled with mass spectrometry techniques such as electrospray ionization and matrix‐assisted laser desorption/ionization for identification of the glycosylation site. Copyright © 2009 John Wiley & Sons, Ltd.