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91.
Tanima Bose Diane Latawiec Partha Pratim Mondal Subhra Mandal 《Journal of nanoparticle research》2014,16(8):1-25
The ever-increasing number of diseases worldwide requires comprehensive, efficient, and cost-effective modes of treatments. Among various strategies, nanomaterials fulfill most of these criteria. The unique physicochemical properties of nanoparticles have made them a premier choice as a drug or a drug delivery system for the purpose of treatment, and as bio-detectors for disease prognosis. However, the main challenge is the proper consideration of the physical properties of these nanomaterials, while developing them as potential tools for therapeutics and/or diagnostics. In this review, we focus mainly on the characteristics of nanoparticles to develop an effective and sensitive system for clinical purposes. This review will present an overview of the important properties of nanoparticles, through their journey from its route of administration until disposal from the human body after accomplishing targeted functionality. We have chosen cancer as our model disease to explain the potentiality of nano-systems for therapeutics and diagnostics in relation to several organs (intestine, lung, brain, etc.). Furthermore, we have discussed their biodegradability and accumulation probability which can cause unfavorable side effects in healthy human subjects. 相似文献
92.
Bar AK Mohapatra S Zangrando E Mukherjee PS 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(31):9571-9579
Three new nanoscopic trigonal prisms, [(tmen)(6) Pd(6) (H(2)L)(3)](NO(3))(12) (1), [(Meen)(6) Pd(6)(H(2) L)(3)](NO(3))(12) (2), and [(2,2'-bipy)(6)Pd(6) (H(2)L)(3)](NO(3))(12) (3), have been synthesized in excellent yields through single-step metal-ligand-coordination-driven self-assembly using 5,10,15,20-tetrakis(3-pyridyl)porphyrin (H(2)L) as a donor and cis-blocked Pd(II) 90° acceptors. These complexes were fully characterized by spectroscopic studies and single-crystal X-ray diffraction. All of these barrels quantitatively bind Zn(II) ions in the N(4) pockets of the porphyrin walls at room temperature. Their corresponding zinc-embedded complexes, [(tmen)(6)Pd(6)(ZnL)(3)](NO(3))(12) (1?a), [(Meen)(6) Pd(6)(ZnL)(3)](NO(3))(12) (2?a), and [(2,2'-bipy)(6)Pd(6)(ZnL)(3)](NO(3))(12) (3?a), were synthesized under ambient conditions by the post-synthetic binding of Zn(II) ions into the H(2)N(4) pockets of the porphyrin walls of these complexes. These zinc-embedded complexes were characterized by electronic absorption, fluorescence emission, (1)H?NMR spectroscopy, as well as elemental analysis. Complexes 1-3 exhibited considerable microporosity in their solid state. Complex 1 was an efficient adsorbent for nitrogen gas and EtOH, MeOH, and water vapors. 相似文献
93.
An amperometric immunosensor for the specific detection of Ricinus communis is reported. Screen printed electrodes (SPEs) were modified with gold nanoparticles (GNPs) loaded multiwalled carbon nanotubes (MWCNTs)-chitosan (Ch) film. The ratio of MWCNT and GNP was optimised to get best electrochemically active electrode. Sandwich immunoassay format was used for the immunosensing of ricin. The revealing antibodies tagged with the enzyme alkaline phosphatase (ALP) converts the substrate 1-naphthyl phosphate into 1-naphthol that was determined with the amperometric technique. The amperometric current obtained was correlated with the concentration of ricin. The prepared GNP-MWCNT-Ch-SPE showed high stability due to the Ch film, short response time with good reproducibility and increased shelf life of the electrodes immobilised with antibodies. The electrochemical activity of the electrode improved because of optimization of composition of CNTs and gold nanoparticles. Under the optimal conditions, the modified electrode showed a wide linear response to the concentration of ricin in the range of 2.5-25 ng mL(-1) with a limit of detection of 2.1 ng mL(-1) and with a relative standard deviation of 5.1% and storage life of 32 days. 相似文献
94.
95.
Partha Guha A. Ghose Choudhury Barun Khanra 《Communications in Nonlinear Science & Numerical Simulation》2012,17(11):4053-4063
We introduce a new transformation (nonlocal) to find the general solutions of some equations belonging to the third and fourth-order time dependent Riccati class of equations. These are in turn related to the Chazy polynomial class and the time dependent F-XVI Bureau symbol PI equations respectively. 相似文献
96.
M. K. PARTHA 《应用数学和力学(英文版)》2010,31(5):565-574
In this paper, the natural convection in a non-Darcy porous medium is studied using a temperature-concentration-dependent density relation. The effect of the two parameters responsible for the nonlinear convection is analyzed for different values of the inertial parameter, dispersion parameters, Rayleigh number, Lewis number, Soret number, and Dufour number. In the aiding buoyancy, the tangential velocity increases steeply with an increase in the nonlinear temperature parameter and the nonlinear concentration parameter when the inertial effect is zero. However, when the inertial effect is non-zero, the effect of the nonlinear temperature parameter and the nonlinear concentration parameter on the tangential velocity is marginal. The concentration distribution varies appreciably and spreads in different ranges for different values of the double dispersion parameters, the inertial effect parameter, and also for the parameters which control the nonlinear temperature and the nonlinear concentration. Heat and mass transfer varies extensively with an increase in the nonlinear temperature parameter and the nonlinear concentration parameter depending on Dacry and non-Darcy porous media. The variation in heat and mass transfer when all the effects, i.e., the inertial effect, double dispersion ef- fects, and Soret and Dufour effects, are simultaneously zero and non-zero. The combined effects of the nonlinear temperature parameter, the nonlinear concentration parameter and buoyancy are analyzed. The effect of the nonlinear temperature parameter and the nonlinear concentration parameter and also the cross diffusion effects on heat and mass transfer are observed to be more in Darcy porous media compared with those in non- Darcy porous media. In the opposing buoyancy, the effect of the temperature parameter is to increase the heat and mass transfer rate, whereas that of the concentration parameter is to decrease. 相似文献
97.
Partha P. Bera Kurt W. Sattelmeyer Martin Saunders Henry F. III Schaefer Paul von Rague Schleyer 《ChemInform》2006,37(30):no-no
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF. 相似文献
98.
Bijnaneswar Mondal Pallab Bhandari Prof. Partha Sarathi Mukherjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(65):15007-15015
Coordination-driven self-assembly of discrete molecular architectures of diverse shapes and sizes has been well studied in the last three decades. Use of dynamic imine bonds for designing analogous metal-free architectures has become a growing challenge recently. This article reports an organic molecular barrel ( OB4R ) as a potential template for nucleation and stabilization of very tiny (<1.5 nm) Ag nanoparticles (AgNPs). Imine bond condensation of a rigid tetra-aldehyde with a flexible diamine followed by imine-bond reduction yielded the discrete tetragonal organic barrel ( OB4R ). The presence of a molecular pocket ornamented with eight diamine moieties gives the potential for encapsulation of silver(I). The organic barrel was finally used as a molecular vessel for the controlled nucleation of silver nanoparticles (AgNPs) with fine size tuning through binding of AgI ions in the confined space of the barrel followed by reduction. Transmission electron microscopy (TEM) analysis of the Ag0@OB4R composite revealed that the mean particle size is 1.44±0.16 nm. The composite material has approximately 52 wt % silver loading. The barrel-supported ultrafine AgNPs [ Ag0@OB4R ] are found to be an efficient photocatalyst for facile Ullmann-type aryl-amination coupling of haloarenes at ambient temperature without using any additives. The catalyst was stable for several cycles of reuse without any agglomeration. The new composite Ag0@OB4R represents the first example of discrete organic barrel-supported AgNPs employed as a photocatalyst in Ullmann-type coupling reactions at room temperature. 相似文献
99.
Here, we refer a new proposal of binary addition as well as subtraction in all-optical domain by exploitation of proper non-linear
material-based switching technique. In this communication, the authors extend this technique for both adder and subtractor
accommodating the spatial input encoding system. 相似文献
100.
Zhao Chun-Liu Yang Xiufeng Lu Chao Ng Jun Hong Guo Xin Partha Roy Chaudhuri Dong Xinyong 《Optics Communications》2004,230(4-6):313-317
A novel and simple Erbium-doped fiber laser by using cascaded fiber Bragg gratings (FBGs) written in high-birefringence fibers for switchable multi-wavelength operation is proposed. Due to two-peak reflection with orthogonal polarizations of the FBG, the polarization hole-burning effect in the cavity is greatly enhanced. Experimental results show that the stable dual- and three-wavelength lasing operation with very narrow wavelength separation (0.39 nm) can be generated at room temperature. The configuration is simple and flexible. Only by adjusting polarization controllers (PCs), the laser can be switched among the stable single-, dual- and three-wavelength lasing operations. 相似文献