Ein neuer Apparat zur Gasanalyse

Ohne Zusammenfassung     

Electric Field Induced Changes of Spin Lattice Relaxation Time T1 in Polar Liquids

T ₁ was found to change linearly with applied electric field for the liquids nitrobenzene, chlorobenzene, ether and dioxane: no change was observed in hexane and cyclohexane. These substantial reductions in T ₁ are explained in terms of quasi-crystalline structures in the liquid.     

Mixing behavior of the biosurfactant, rhamnolipid, with a conventional anionic surfactant, sodium dodecyl benzene sulfonate

The use of small angle neutron scattering, SANS, neutron reflectivity, NR, and surface tension to study the mixing properties of the biosurfactant rhamnolipid with a conventional anionic surfactant, sodium dodecyl 6-benzene sulfonate, LAS, is reported. The monorhamnose rhamnolipid, R1, mixes close to ideally with LAS at the air-water interface, whereas for mixtures of LAS with the dirhamnose rhamnolipid, R2, the LAS strongly partitions to the air-water interface relative to R2, probably because of the steric hindrance of the larger R2 headgroup. These trends in the binary mixtures are also reflected in the ternary R1/R2/LAS mixtures. However, for these ternary mixtures, there is also a pronounced synergy in the total adsorption, which reaches a maximum for a LAS/rhamnolipid mole ratio of about 0.6 and a R1/R2 mol ratio of about 0.5, an effect which is not observed in the binary mixtures. In solution, the R1/LAS mixtures form relatively small globular micelles, L(1), at low surfactant concentrations (<20 mM), more planar structures (lamellar, L(α), unilamellar/multilamellar vesicles, ulv/mlv) are formed at higher surfactant concentrations for R1 and LAS rich compositions, and a large mixed phase (L(α)/L(1) and L(1)/L(α)) region forms at intermediate surfactant compositions. In contrast, for the R2/LAS mixtures, the higher preferred curvature of R2 dominates the phase behavior. The predominant microstructure is in the form of small globular micelles, except for solution compositions rich in LAS (>80 mol % LAS) where more planar structures are formed. For the ternary mixtures, there is an evolution in the resulting phase behavior from one dominated by L(1) (R2 rich) to one dominated by planar structures, L(α), (R1, LAS rich), and which strongly depends upon the LAS/rhamnolipid and R1/R2 mole ratio.     

Group Elastic Symmetries Common to Continuum and Discrete Defective Crystals

The Lie group structure of crystals which have uniform continuous distributions of dislocations allows one to construct associated discrete structures—these are discrete subgroups of the corresponding Lie group, just as the perfect lattices of crystallography are discrete subgroups of $\mathbb{R}^{3}$ , with addition as group operation. We consider whether or not the symmetries of these discrete subgroups extend to symmetries of (particular) ambient Lie groups. It turns out that those symmetries which correspond to automorphisms of the discrete structures do extend to (continuous) symmetries of the ambient Lie group (just as the symmetries of a perfect lattice may be embedded in ‘homogeneous elastic’ deformations). Other types of symmetry must be regarded as ‘inelastic’. We show, following Kamber and Tondeur, that the corresponding continuous automorphisms preserve the Cartan torsion, and we characterize the discrete automorphisms by a commutativity condition, (6.14), that relates (via the matrix exponential) to the dislocation density tensor. This shows that periodicity properties of corresponding energy densities are determined by the dislocation density.