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21.
Ermann M Simkovsky NM Roberts SM Parry DM Baxter AD 《Journal of combinatorial chemistry》2002,4(4):352-358
A solid-phase synthesis of substituted cyclic urea derivatives as potential heterocyclic library scaffolds is described. 2-Amino-3-nitropyridine is attached to Wang resin via a carbamate linkage. Reduction of the nitro group was achieved with SnCl(2).2H(2)O. Reductive alkylation with a range of substituted benzaldehydes followed by cyclative cleavage afforded a small library of 3-substituted imidazo[4,5-b]pyridine-2-ones in 33-45% yield and 59-88% purity. Subsequently, this methodology was applied to the synthesis of 3-substituted imidazo[4,5-f]quinolin-2-ones. 相似文献
22.
Chen M Dong C Penfold J Thomas RK Smyth TJ Perfumo A Marchant R Banat IM Stevenson P Parry A Tucker I Campbell RA 《Langmuir : the ACS journal of surfaces and colloids》2011,27(14):8854-8866
The adsorption of the lactonic (LS) and acidic (AS) forms of sophorolipid and their mixtures with the anionic surfactant sodium dodecyl benzene sulfonate (LAS) has been measured at the air/water interface by neutron reflectivity, NR. The AS and LS sophorolipids adsorb with Langmuir-like adsorption isotherms. The more hydrophobic LS is more surface active than the AS, with a lower critical micellar concentration, CMC, and stronger surface adsorption, with an area/molecule ~70 ?(2) compared with 85 ?(2) for the AS. The acidic sophorolipid shows a maximum in its adsorption at the CMC which appears to be associated with a mixture of different isomeric forms. The binary LS/AS and LS/LAS mixtures show a strong surface partitioning in favor of the more surface active and hydrophobic LS component but are nevertheless consistent with ideal mixing at the interface. In contrast, the surface composition of the AS/LAS mixture is much closer to the solution composition, but the surface mixing is nonideal and can be accounted for by regular solution theory, RST. In the AS/LS/LAS ternary mixtures, the surface adsorption is dominated by the sophorolipid, and especially the LS component, in a way that is not consistent with the observations for the binary mixtures. The extreme partitioning in favor of the sophorolipid for the LAS/LS/AS (1:2) mixtures is attributed to a reduction in the packing constraints at the surface due to the AS component. Measurements of the surface structure reveal a compact monolayer for LS and a narrow solvent region for LS, LS/AS, and LS/LAS mixtures, consistent with the more hydrophobic nature of the LS component. The results highlight the importance of the relative packing constraints on the adsorption of multicomponent mixtures, and the impact of the lactonic form of the sophorolipid on the adsorption of the sophorolipid/LAS mixtures. 相似文献
23.
Phagocytosis is a major component of the animal immune system where apoptotic cellular material, metabolites, and waste are safely processed. Further, efficient phagocytosis by macrophages is key to maintaining healthy vascular systems and preventing atherosclerosis. Single-cell images of macrophage phagocytosis of red blood cells, RBCs, and polystyrene microspheres have been chemically mapped with TOF-SIMS. We demonstrate here cholesterol and phosphocholine localizations as relative to time and activity. 相似文献
24.
25.
G. P. Parry 《Archive for Rational Mechanics and Analysis》1998,145(1):1-22
First I review and adapt some classical and recent formulations of problems relating to the classification of two‐ and three‐dimensional
lattices. Then I use these methods to calculate lattice groups that are of interest in the continuum mechanics of phase transitions
in crystals, and to construct invariant neighbourhoods that are useful in the same context. The paper is designed to provide
a perspective of similar calculations which employ methods of traditional crystallography.
(Accepted February 9, 1998) 相似文献
26.
S. J. Parry 《Journal of Radioanalytical and Nuclear Chemistry》2001,248(1):143-147
Recycling of wastepaper has been shown to increase the concentration of metals in the product. Although it is generally assumed that there is no risk of migration of chemical contaminants from recycled paper and board into food, the UK Food Standards Agency has identified limited evidence of such migration. Therefore, it is important to carry out research to establish the concentration of metals in recycled paper and board in contact with food. A previous study at Imperial College had resulted in the development of a neutron activation analysis method to determine trace metals in plastic packaging. This paper describes an initial study to establish whether the same methodology could be applied to paper and board and to carry out a preliminary investigation into a small range of recycled paper and board products. The study was made on 22 elements in 17 products including pizza boxes, fries boxes, kitchen towel, table napkins, greaseproof paper, tea bags and cake cases. This work has shown elevated levels of some elements including barium (69 mg/kg in pizza bases) and chromium (5 mg/kg in napkins, 50 mg/kg in greaseproof paper, 2 mg/kg in cake cases, 90 mg/kg in baking parchment, 5 mg/kg in fries boxes and 5 mg/kg in pizza bases). 相似文献
27.
William Parry 《Communications in Mathematical Physics》1986,106(2):267-275
Under suitable conditions it is shown how to change the velocity of aC
2 AxiomA attractor so that the Sinai-Ruelle-Bowen measure coincides with the measure of maximal entropy. These measures are obtained as limits of certain closed orbital measures. 相似文献
28.
In the continuum context, a uniform crystal has dislocation density tensor constant in space. A simple iteration procedure generates an infinite set of points which is associated with uniform defective crystals. When certain necessary conditions are satisfied, there is a minimum (non-zero) separation of points in this set, so the set is discrete. We describe the structure of such sets explicitly, and show in particular that any such set is either a simple lattice or a 4-lattice.Paolo Cermelli was partially supported by the Italian MIUR grant ‘Modelli Matematici per la Scienza dei Materiali’. 相似文献
29.
Jönsson-Niedziółka M Lapierre F Coffinier Y Parry SJ Zoueshtiagh F Foat T Thomy V Boukherroub R 《Lab on a chip》2011,11(3):490-496
Environmental air monitoring is of great interest due to the large number of people concerned and exposed to different possible risks. From the most common particles in our environment (e.g. by-products of combustion or pollens) to more specific and dangerous agents (e.g. pathogenic micro-organisms), there are a large range of particles that need to be controlled. In this article we propose an original study on the collection of electrostatically deposited particles using electrowetting droplet displacement. A variety of particles were studied, from synthetic particles (e.g. Polystyrene Latex (PSL) microsphere) to different classes of biological particle (proteins, bacterial spores and a viral simulant). Furthermore, we have compared ElectroWetting-On-Dielectric (EWOD) collecting efficiency using either a hydrophobic or a superhydrophobic counter electrode. We observe different cleaning efficiencies, depending on the hydrophobicity of the substrate (varying from 45% to 99%). Superhydrophobic surfaces show the best cleaning efficiency with water droplets for all investigated particles (MS2 bacteriophage, BG (Bacillus atrophaeus) spores, OA (ovalbumin) proteins, and PSL). 相似文献
30.