全文获取类型
收费全文 | 555篇 |
免费 | 13篇 |
专业分类
化学 | 379篇 |
晶体学 | 6篇 |
力学 | 6篇 |
数学 | 36篇 |
物理学 | 141篇 |
出版年
2023年 | 7篇 |
2022年 | 9篇 |
2021年 | 6篇 |
2020年 | 13篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 10篇 |
2016年 | 11篇 |
2015年 | 11篇 |
2014年 | 17篇 |
2013年 | 58篇 |
2012年 | 31篇 |
2011年 | 32篇 |
2010年 | 20篇 |
2009年 | 14篇 |
2008年 | 20篇 |
2007年 | 22篇 |
2006年 | 17篇 |
2005年 | 16篇 |
2004年 | 14篇 |
2003年 | 10篇 |
2002年 | 6篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 9篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 9篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 9篇 |
1980年 | 12篇 |
1979年 | 9篇 |
1978年 | 16篇 |
1977年 | 7篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1970年 | 3篇 |
1969年 | 3篇 |
排序方式: 共有568条查询结果,搜索用时 281 毫秒
21.
Vadivelu Balasubramanian Naga S. Dixit Chunibhai C. Patel 《Transition Metal Chemistry》1980,5(1):152-154
Summary A series of rhodium(III) complexes of certain hydroxyimino--diketones were synthesised and their structures assigned on the basis of elemental analyses and i.r. and1H n.m.r. spectral studies, The complexes exhibit coordination through carbonyl oxygen and nitrogen of the hydroxy-imino groups in the ligands.1H and13C n.m.r. studies show that the ligands exist in the isonitroso form in CDCl3. 相似文献
22.
Potentiometric investigations on metal complexes of various bivalent metal ions, viz. UO2(II), Cu(II), Ni(II), Co(II), Cd(II), Pb(II), Zn(II) and Mn(II) with benzilmonol(lepidy!)hydrazone (BLH) have been carried
out at different ionic strengths and at different temperatures in order to determine stability constants of the complexes.
Thermodynamic parameters ΔC, ΔH and ΔS have also been evaluated from temperature coefficient data. The effect of varying the
dielectric constant of the medium on the stability constants of complexes has also been investigated at 30±0.5°C and μ = 0.1MNaCl.
Thermodynamic stability constants and thermodynamic stabilization energies for the first transition metals have also been
discussed. 相似文献
23.
Dixit AA Lei Y Lee KW Quiñones E Houston PL 《The journal of physical chemistry. A》2005,109(9):1770-1775
Multiphoton excitation and dissociation of SO(2) have been investigated in the wavelength range from 224 to 232 nm. Strong evidence is found for two-photon excitation to the H Rydberg state, followed by dissociation to SO + O and ionization of the SO product by absorption of a third photon. The two-photon excitation is resonantly enhanced via the C (1)B(2) intermediate state, and the two-photon yield spectrum thus bears a strong resemblance to the spectrum of this intermediate. Imaging of the O((3)P(2)), S((1)D(2)), and SO products suggests that, following dissociation of SO(2) from the H state, SO is produced in the A and B electronic states. S((1)D(2)) is produced both from two-photon dissociation of SO(2) to give S((1)D(2)) + O(2) and by single-photon dissociation of SO(+). In the former process, the O(2) is likely formed in all of its lowest three electronic states. 相似文献
24.
An innovative route for the synthesis of substituted naphtho[2,1-b]furan has been delineated through a ring transformation reaction of suitably functionalized 2H-pyran-2-ones by reaction with 6,7-dihydro-5H-benzofuran-4-one, in good yield. 相似文献
25.
Lambert HM Davis EW Tokel O Dixit AA Houston PL 《The Journal of chemical physics》2005,122(17):174304
The photodissociation of N(2)O at wavelengths near 130 nm has been investigated by velocity-mapped product imaging. In all, five dissociation channels have been detected, leading to the following products: O((1)S)+N(2)(X (1)Sigma), N((2)D)+NO(X (2)Pi), N((2)P)+NO(X (2)Pi), O((3)P) + N(2)(A (3)Sigma(+) (u)), and O((3)P) + N(2)(B (3)Pi(g)). The most significant channel is to the products O((1)S) + N(2)(X(1)Sigma), with strong vibrational excitation in the N(2). The O((3)P) + N(2)(A,B):N((2)D,(2)P) + NO branching ratio is measured to be 1.4 +/- 0.5, while the N(2)(A) + O((3)P(J)):N(2)(B) + O((3)P(J)) branching ratio is determined to be 0.84+/-0.09. The spin-orbit distributions for the O((3)P(J)), N((2)P(J)), and N((2)D(J)) products were also determined. The angular distributions of the products are in qualitative agreement with excitation to the N(2)O(D (1)Sigma(+)) state, with participation as well by the (3)Pi(v) state. 相似文献
26.
Theo Steininger Jait Dixit Philipp Frank Maksim Greiner Sebastian Hutschenreuter Jakob Knollmüller Reimar Leike Natalia Porqueres Daniel Pumpe Martin Reinecke Matev raml Csongor Varady Torsten Enßlin 《Annalen der Physik》2019,531(3)
NIFTy , “Numerical Information Field Theory,” is a software framework designed to ease the development and implementation of field inference algorithms. Field equations are formulated independently of the underlying spatial geometry allowing the user to focus on the algorithmic design. Under the hood, NIFTy ensures that the discretization of the implemented equations is consistent. This enables the user to prototype an algorithm rapidly in 1D and then apply it to high‐dimensional real‐world problems. This paper introduces NIFTy 3, a major upgrade to the original NIFTy framework. NIFTy 3 allows the user to run inference algorithms on massively parallel high performance computing clusters without changing the implementation of the field equations. It supports n‐dimensional Cartesian spaces, spherical spaces, power spaces, and product spaces as well as transforms to their harmonic counterparts. Furthermore, NIFTy 3 is able to handle non‐scalar fields, such as vector or tensor fields. The functionality and performance of the software package is demonstrated with example code, which implements a mock inference inspired by a real‐world algorithm from the realm of information field theory. NIFTy 3 is open‐source software available under the GNU General Public License v3 (GPL‐3) at https://gitlab.mpcdf.mpg.de/ift/NIFTy/tree/NIFTy_3 . 相似文献
27.
Prashant Mishra Kaman Singh Utkarsh Dixit Ankita Agarwal Rayees Ahmad Bhat 《印度化学会志》2022,99(7):100528
The threat of phenol contamination in aquatic ecosystems is significant for the health of the earth's water systems as well as all humans on it. The present study was conducted to synthesize a cost-effective adsorbent (pea shells activated with sulfuric acid, PSASA) from agriculture waste (pea shells) and its use for effective removal of toxic 4-Aminophenol (4-AP). Newly designed PSASA exhibited significant adsorption of 4-AP which was confirmed by SEM, FT-IR, and XRD analysis. Surface topography confirmed high unevenness of the PSASA surface and the macroporous feature of the PSASA was confirmed by BET analysis. . Multiple testing was done to see how various factors affected adsorption such as adsorbent dose, temperature, pH, PZC, the effect of KCl and urea addition and the effect of the initial concentration of 4-AP. A drop in adsorption uptake of 4-AP was observed as the temperature increases from 25 °C to 45 °C. Maximum adsorption uptake (qm) was found to be 106.11 mg/g at an optimum pH of 7.0 and 25 °C. Among various adsorption isotherm models tested, Langmuir Isotherm gave the best explanation with high R2 values of experimental data. The pseudo-first-order model was found to explain the kinetics of adsorption well. The thermodynamic finding confirms the adsorption process was physical and exothermic. The adsorption of 4-AP was primarily governed by electrostatic interaction, hydrogen-bonding and π-π exchange mechanism. Because of the positive outcomes of the present research, we can use the PSASA as a cost-effective adsorbent for removing phenolic compounds. 相似文献
28.
Purnima Dixit J. P. Tandon 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):389-395
Abstract Some organolead(IV) complexes derived from biologically active sulfur and nitrogen donor ligands have been synthesized and characterized by elemental analyses, molecular weight determinations and conductivity measurements. The trigonal bipyramidal and octahedral geometries for these complexes have been proposed on the basis of electronic, infrared and NMR (1H and 13C) spectral evidences. The antifungal activity of some of the ligands and their complexes have also been evaluated against Fursarium oxysporum SCW. ex Frics f. sp. Ciceri (Pedwick) subram. 相似文献
29.
Abstract Macroazoinitiator (MAI) was prepared from hydroxyl‐terminated polybutadiene (HTPB) and 4,4′‐azobis‐4‐cyanopentanoic acid by direct polycondensation in the presence of 1‐methyl‐2‐chloropyridinium iodide at room temperature. This MAI used for block copolymerization of AAm at 60°C gave the best results in chloroform but the formation of a crosslinked product could not be ruled out in dioxane. It was inferred that for production of a linear block copolymer, homogeneous reaction mixture was required. The resulting products were characterized by spectral studies IR and NMR, viscosity measurements. Distinct phase segregation of hydrophobic and hydrophilic blocks was evident through DSC analysis. 相似文献
30.
Polymeric UV absorbers have been prepared by free-radical solution copolymerization at 75°C of methyl methacrylate and 2-hydroxy-4-methacryloyloxybenzophenone monomers at low conversion (around 10%). The composition of the copolymers was determined by UV, IR, and NMR studies. The molecular weight was estimated by GPC. The reactivity ratios were determined by several methods. Viscosity was used to study the effect of copolymer composition and solvents. The copolymers were also analyzed by TGA and DSC, and DSC was used to study the effect of copolymer composition on Tg. 相似文献